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991.
The theoretical basis of a Gaussian-like approximate solution was applied to a chromatographic impulse response technique with curve fitting for measuring binary diffusion coefficients and retention factors using a polymer-coated capillary column. The formulae were derived for evaluating both the accuracy of the approximate solution and the sensitivity of the parameters. The validity of the solution also was confirmed experimentally for pulse injection of phenol in acetone into supercritical carbon dioxide flowing at 313.15 K and 11.6-28.6 MPa. Potential sources for experimental errors of the method are discussed. 相似文献
992.
[reaction: see text] The title technique is a convenient and powerful method for directly monitoring or assaying any reaction mixture or reagent solution. Examples of some common processes (Fischer esterification, lithiation, butyllithium/THF compatibility, olefin metathesis, and a quantification assay), each interrogated in its native solvent, are presented. The spectral data are easy to acquire, and the information content makes a compelling case for routine use of No-D NMR spectroscopy. 相似文献
993.
Yao D Vlessidis AG Gou Y Zhou X Zhou Y Evmiridis NP 《Analytical and bioanalytical chemistry》2004,379(1):171-177
A novel flow-injection chemiluminescence-based method has been developed for determination of superoxide dismutase (SOD) activity. An in-vitro superoxide anion generation xanthine/xanthine oxidase stable source was established on line with FIA/CL-detection apparatus, for measuring SOD activity. This method can detect SOD in the linear range of 0.002–2.00 U mL–1 with a detection limit of 0.001 U mL–1. Another method for detection of superoxide anion is based on the luminol–FeCl3 chemiluminescence (CL) reaction. This method was used to evaluate superoxide release and SOD activity in rats treated with the traditional Chinese herb Pulsatilla chinensis, which resulted in high clearance of hepatitis B virus (HBV) after treatment of a hepatitis B patient. Interestingly, we found that treatment with Pulsatilla chinensis can specifically increase superoxide release by liver tissues and, at the same time, slightly increase extracellular SOD (ECSOD) activity in plasma; in particular it can markedly increase MnSOD activity in mitochondria in liver tissue. This work revealed a possible mechanism whereby Pulsatilla chinensis prevents possible infection (for example HBV) by specifically increasing superoxide release in the liver and increasing MnSOD activity to minimize superoxide-mediated toxicity. 相似文献
994.
Guowu Yao 《Proceedings of the American Mathematical Society》2004,132(8):2483-2493
Let be a sequence of locally quasiconformal harmonic maps on the unit disk with respect to the Poincaré metric. Suppose that the energy densities of are uniformly bounded from below by a positive constant and locally uniformly bounded from above. Then there is a subsequence of that locally uniformly converges on , and the limit function is either a locally quasiconformal harmonic map of the Poincaré disk or a constant. Especially, if the limit function is not a constant, the subsequence can be chosen to satisfy some stronger conditions. As an application, it is proved that every point of the space , a subspace of the universal Teichmüller space, can be represented by a quasiconformal harmonic map that is an asymptotic hyperbolic isometry.
995.
Braunisch H Habashy TM Sinha BK Pabon J Kong JA 《The Journal of the Acoustical Society of America》2004,115(1):269-279
The problem of inferring unknown geometry and material parameters of a waveguide model from noisy samples of the associated modal dispersion curves is considered. In a significant reduction of the complexity of a common inversion methodology, the inner of two nested iterations is eliminated: The approach described does not employ explicit fitting of the data to computed dispersion curves. Instead, the unknown parameters are adjusted to minimize a cost function derived directly from the determinant of the boundary condition system matrix. This results in an efficient inversion scheme that, in the case of noise-free data, yields exact results. Multimode data can be simultaneously processed without extra complications. Furthermore, the inversion scheme can accommodate an arbitrary number of unknown parameters, provided that the data have sufficient sensitivity to these parameters. As an important application, we consider the sonic guidance condition for a fluid-filled borehole in an elastic, homogeneous, and isotropic rock formation for numerical forward and inverse dispersion analysis. We investigate numerically the parametric inversion with errors in the model parameters and the influence of bandwidth and noise, and examine the cases of multifrequency and multimode data, using simulated flexural and Stoneley dispersion data. 相似文献
996.
Yao Y Kleinman L MacDonald AH Sinova J Jungwirth T Wang DS Wang E Niu Q 《Physical review letters》2004,92(3):037204
We perform a first principles calculation of the anomalous Hall effect in ferromagnetic bcc Fe. Our theory identifies an intrinsic contribution to the anomalous Hall conductivity and relates it to the k-space Berry phase of occupied Bloch states. This dc conductivity has the same origin as the well-known magneto-optical effect, and our result accounts for experimental measurement on Fe crystals with no adjustable parameters. 相似文献
997.
C.H. Song J. Ma Y.Y. Yao X.M. Lu Y.N. Wang C.L. Choy 《Solid State Communications》2004,129(12):775-780
Bi4Ti3O12 (BiT), Bi3.25La0.75Ti3O12 (BLT), Bi4−x/3Ti3−xNbxO12 (BTN) and Bi3.25−x/3La0.75Ti3−xNbxO12 (BLTN) thin films have been prepared by pulsed laser deposition. BTN and BLTN films exhibit a maximum in the remanent polarization Pr at a Nb content x=0.018. At this Nb content, the BLTN film has a Pr value (25 μC/cm2) that is much higher than that of BiT and a coercive field similar to that of BiT. The polarization of this BLTN film is fatigue-free up to 109 switching cycles. The high fatigue resistance is mainly due to the substitution of Bi3+ ions by La3+ ions at the A site and the enhanced Pr arises largely from the replacement of Ti4+ ions by Nb5+ ions at the B site. The mechanisms behind the effects of the substitution at the two sites are discussed. 相似文献
998.
The spectral properties of a diode-pumped Yb:Y2O3 ceramic laser are reported. We show experimentally that the instantaneous emission wavelengths of the laser change randomly with time, whereas its emission has fixed well-defined transverse modes. The central wavelength of the laser emission also shifts prominently with the increase of intracavity light intensity. It is found that the spectral properties of the laser can be explained well based on the strong reabsorption of light in the gain medium. 相似文献
999.
We have developed a new technique for rapid microfabrication that uses electrophoretically delivered particles and an optical trap. The material particles, micrometer- and nanometer-sized polystyrene beads in aqueous solution, are continuously delivered to an optical trap by means of the electrophoretic effect inside glass capillaries or similar microstructures. The optical trap is used to manipulate and deposit the polystyrene beads onto a substrate. The continuous, on-demand delivery of particles allows for microfabrication in two and three dimensions with high speed and high efficiency and without material waste. This new technique has many potential applications in microelectronics and biotechnology. 相似文献
1000.
Multi-line laser transitions from one metastable triplet state to another at wavelengths of 2.92, 3.01, 2.69 and 2.60 μm have
been obtained through high pulse repetition frequency longitudinal discharge in a mixed gas of strontium vapor and helium
buffer gas. The intensity ratio of these laser lines was 5:4:4:1. As far as we know, these laser lines have never been reported
except for 3.01 μm. Some mechanisms for forming a population inversion are initially discussed on the basis of analyzing features
of corresponding energy-level structure and experimental phenomena. It is reasonable to name this kind of laser as an M–M
transition laser according to the feature of the lasing process.
Received: 15 October 2002 / Published online: 9 April 2003
RID="*"
ID="*"Corresponding author. Fax: +86-0571/8795-1328, E-mail: pbl66@zju.edu.cn 相似文献