Fullerodendrimers with peripheral triethyleneglycol chains

Triethylene glycol terminated poly(aryl ether) dendritic branches with an aldehyde function at the focal point have been prepared and attached to C₆₀ by a 1,3-dipolar cycloaddition.     

Influence of deposition conditions on the optical properties of erbium-doped yttrium oxide films grown by aerosol-UV assisted MOCVD

Erbium-doped Y₂O₃ films were prepared by aerosol-UV assisted metal-organic chemical vapour deposition (MOCVD) at 410 °C. The effects of humidity of carrier gas and UV-assistance on their structure and optical properties were investigated on the as-deposited and thermal annealed films using infrared spectroscopy, X-ray diffraction and transmission electron microscopy. It was found that the as-deposited Er:Y₂O₃ films crystallise in the Y₂O₃ cubic structure and present a very low organic contamination when the deposition takes place under high air humidity and, even better, with UV-assistance. After annealing, two different structural phases are observed corresponding to the cubic and the monoclinic structures of Y₂O₃. The Er³⁺ luminescence analysed in the visible and IR regions, shows the classical green transitions. The best optical properties were obtained with as-deposited and annealed Er:Y₂O₃ films grown under high air humidity with UV-assistance. Under such deposition conditions, ⁴I_13/2 lifetimes was found to be 3.07 and 6.1 ms for films annealed at 800 and 1000 °C, respectively, and up-conversion phenomena were underlined. This indicates that the deposition conditions, in particular air humidity, play an important role in the luminescent properties even after annealing.     

Reaction-Diffusion Equations in Homogeneous Media: Existence,Uniqueness and Stability of Travelling Fronts

The goal of this survey is to describe the construction and some qualitative properties of particular global solutions of certain reaction-diffusion equations. These solutions are known as travelling fronts (or travelling waves) and play an important role in the long-time behaviour of the solutions of the parabolic system. We will mainly focus on the existence of travelling wave solutions and their stability. We will also give some standard tools in elliptic and parabolic theory, which are of general interest.     

ESTIMATION OF PARAMETERS IN A CLOSED PYGMY POPULATION IN CAMEROON

Inspired by Kouakep [16], we consider in this note a wellposed model with differential susceptibility and infectivity adding continuous age structure to an ODE model for a "Baka" pygmy group in the East of Cameroon(Africa).Assuming a very low contribution of carriers to infection compared to acute infection, we estimate a probability p(a)(to develop symptomatic Hepatitis B state at age a) and acute carriers' transmission rate. The value R_0= 2:67 1 of the basic reproduction number estimated from data in the east of Cameroon confirms that HBV is endemic in the Baka pygmy group.     

Construction of invariant whiskered tori by a parameterization method. Part I: Maps and flows in finite dimensions

We present theorems which provide the existence of invariant whiskered tori in finite-dimensional exact symplectic maps and flows. The method is based on the study of a functional equation expressing that there is an invariant torus.We show that, given an approximate solution of the invariance equation which satisfies some non-degeneracy conditions, there is a true solution nearby. We call this an a posteriori approach.The proof of the main theorems is based on an iterative method to solve the functional equation.The theorems do not assume that the system is close to integrable nor that it is written in action-angle variables (hence we can deal in a unified way with primary and secondary tori). It also does not assume that the hyperbolic bundles are trivial and much less that the hyperbolic motion can be reduced to constant linear map.The a posteriori formulation allows us to justify approximate solutions produced by many non-rigorous methods (e.g. formal series expansions, numerical methods). The iterative method is not based on transformation theory, but rather on successive corrections. This makes it possible to adapt the method almost verbatim to several infinite-dimensional situations, which we will discuss in a forthcoming paper. We also note that the method leads to fast and efficient algorithms. We plan to develop these improvements in forthcoming papers.     

A free boundary problem for the Laplacian with a constant Bernoulli-type boundary condition

We study a free boundary problem for the Laplace operator, where we impose a Bernoulli-type boundary condition. We show that there exists a solution to this problem. We use A. Beurling’s technique, by defining two classes of sub- and super-solutions and a Perron argument. We try to generalize here a previous work of A. Henrot and H. Shahgholian. We extend these results in different directions.     

Density functional study of methyl chemisorption on polycyclic aromatic hydrocarbons.

The reactions of methyl radicals with large (up to C(96)H(24)) polycyclic aromatic hydrocarbons (PAHs) are studied by density functional calculations to shed light on the experimentally observed deposition of carbon on highly oriented pyrolytic graphite (HOPG), which occurs when hot HOPG (decorated by nanometre-sized defects) is exposed to methyl radicals. The equilibrium structures of the reaction products, together with transition structures for PAHs up to the size of phenanthroperylene, are determined using the density functionals B3LYP, TPSSh, BP86 and TPSS. The structures are analysed by computing the pi orbital axis vector (POAV) and the altitude of the reactive carbon above the molecular plane of the PAH. The strongest C-CH(3) bonds are found at the edges of the PAHs, where the s character of the C orbital involved in the bond is roughly 25 % (sp(3) hybrid orbital). Carbon atoms inside the PAH form bonds with the methyl radical through atomic orbitals with about 16 % s character in the POAV analysis. These bonds are much weaker than those at the edges of the PAH, while the reactive carbon has moved about 40 pm above the molecular plane. At the edges, the PAH carbon atoms do not leave the molecular plane to this extent. The computed barrier heights and geometrical parameters of the transition structures are in agreement with Hammond's postulate, and the relative energies of all of the equilibrium structures can be rationalized by Hückel molecular orbital (HMO) theory.