全文获取类型
收费全文 | 75241篇 |
免费 | 11445篇 |
国内免费 | 4016篇 |
专业分类
化学 | 64248篇 |
晶体学 | 705篇 |
力学 | 3213篇 |
综合类 | 248篇 |
数学 | 6742篇 |
物理学 | 15546篇 |
出版年
2023年 | 456篇 |
2022年 | 877篇 |
2021年 | 1157篇 |
2020年 | 2202篇 |
2019年 | 3537篇 |
2018年 | 2015篇 |
2017年 | 1687篇 |
2016年 | 4661篇 |
2015年 | 4603篇 |
2014年 | 4808篇 |
2013年 | 5984篇 |
2012年 | 5116篇 |
2011年 | 4485篇 |
2010年 | 4520篇 |
2009年 | 4426篇 |
2008年 | 4130篇 |
2007年 | 3486篇 |
2006年 | 2938篇 |
2005年 | 2808篇 |
2004年 | 2464篇 |
2003年 | 2323篇 |
2002年 | 3100篇 |
2001年 | 2293篇 |
2000年 | 2024篇 |
1999年 | 1129篇 |
1998年 | 685篇 |
1997年 | 673篇 |
1996年 | 685篇 |
1995年 | 575篇 |
1994年 | 572篇 |
1993年 | 508篇 |
1992年 | 493篇 |
1991年 | 478篇 |
1990年 | 431篇 |
1989年 | 388篇 |
1988年 | 323篇 |
1987年 | 333篇 |
1986年 | 323篇 |
1985年 | 357篇 |
1984年 | 341篇 |
1979年 | 318篇 |
1978年 | 339篇 |
1977年 | 328篇 |
1976年 | 409篇 |
1975年 | 366篇 |
1974年 | 394篇 |
1973年 | 402篇 |
1972年 | 373篇 |
1971年 | 331篇 |
1970年 | 315篇 |
排序方式: 共有10000条查询结果,搜索用时 21 毫秒
81.
P. Ya. Malits 《Journal of Mathematical Sciences》1991,57(5):3417-3420
We consider the pressure of a plate on a half-space with a round cylindrical cavity. The surface of the cavity is reinforced by elastic elements that are modeled by very general operators. The problem is reduced to a Fredholm integral equation of second kind. A detailed study is made of the case of reinforcement described by the Winkler law. An approximate solution is obtained in the form of the asymptotics with respect to the radii of the plate and the cavity.Translated fromDinamicheskie Sistemy, No. 6, 1987, pp. 80–85. 相似文献
82.
Wei‐Ling Wang Jian‐Wei Xu Yee‐Hing Lai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4154-4164
Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and 1H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu2+, Co2+, Ni2+, Zn2+, Mn2+, and Ag+ ions. In contrast, only Cu2+, Co2+, and Ni2+ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu2+, Co2+, and Ni2+ ions toward P7 are of the order of 106 M?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006 相似文献
83.
The prediction of the peak width at half height is an important aspect in the optimization of the chromatographic operating conditions. In this paper, a linear relationship, between the peak widths at half height and the retention values with various isocratic elution is observed. In gradient elution, however, the relationship between the peak widths at half height and the so-called invented retention values that correspond to the mobile phase composition by eluting the solute from the column end is developed. We believe that there is almost the same band width at half height inside the column (in unit of length) for different solutes. The peak width at half height in the chromatogram (in unit of time) is mainly determined by the capacity factor of the solute when it is eluted from the column end. The larger the capacity factor of a solute eluted from the column end, the more slowly will be the solute eluted from the column end and the wider will be the peak width at half height. It is possible to predict the peak width at half height in various isocratic and gradient elutions by using this linear relationship. 相似文献
84.
An approach is proposed to solving multipoint boundary-value problems for linear differential equation of w-th order, based on reduction to two-point boundary-value problems. The two-point problems are solved by the stable discrete orthogonalization method. Some numerical examples are considered.Translated from Vychislitel'naya i Prikladnaya Matematika, No. 58, pp. 36–45, 1986. 相似文献
85.
86.
87.
L. A. Kurdanchenko B. V. Petrenko I. Ya. Subbotin 《Ukrainian Mathematical Journal》1997,49(11):1742-1746
We prove that, in an Artinian module, the upper FC-hypercenter over an infinite FC-hypercentral locally solvable group has a direct complement. Thus, we obtain a generalization of one of Zaitsev’s theorems and one of Duan’s theorems. 相似文献
88.
Xiao Huang Bishwa Ranjan Nayak Tao Lu Lowe 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5054-5066
A series of novel multifunctional hydrogels that combined the merits of both thermoresponsive and biodegradable polymeric materials were designed, synthesized, and characterized. The hydrogels were copolymeric networks composed of N‐isopropylacrylamide (NIPAAM) as a thermoresponsive component, poly(L‐lactic acid) (PLLA) as a hydrolytically degradable and hydrophobic component, and dextran as an enzymatically degradable and hydrophilic component. The chemical structures of the hydrogels were characterized by an attenuated total reflection–Fourier transform infrared spectroscopy (ATR–FTIR) technique. The hydrogels were thermoresponsive, showing a lower critical solution temperature (LCST) at approximately 32 °C, and their swelling properties strongly depended on temperature changes, the balance of the hydrophilic/hydrophobic components, and the degradation of the PLLA component. The degradation of the hydrogels caused by hydrolytic cleavage of ester bonds in the PLLA component was faster at 25 °C below the LCST than at 37 °C above the LCST, determined by the ATR–FTIR technique. Due to their multifunctional properties, the designed hydrogels show great potential for biomedical applications, including drug delivery and tissue engineering. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5054–5066, 2004 相似文献
89.
Marie‐France Llauro Julien Loiseau Fernande Boisson Frdric Delolme Catherine Ladavire J. Claverie 《Journal of polymer science. Part A, Polymer chemistry》2004,42(21):5439-5462
Low‐molecular‐weight poly(acrylic acid) (PAA) was synthesized by reversible addition fragmentation chain transfer polymerization with a trithiocarbonate as chain‐transfer agent (CTA). With a combination of NMR spectroscopy and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry, the PAA end‐groups of the polymer were analyzed before and after neutralization by sodium hydroxide. The polymer prior to neutralization is made up of the expected trithiocarbonate chain‐ends and of the H‐terminated chains issued from a reaction of transfer to solvent. After neutralization, the trithiocarbonates are transformed into thiols, disulfides, thiolactones, and additional H‐terminated chains. By quantifying the different end‐groups, it was possible to demonstrate that fragmentation is the rate limiting step in the transfer reaction. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5439–5462, 2004 相似文献
90.
John Boyle Ica Manas‐Zloczower DonaldL. Feke 《Particle & Particle Systems Characterization》2004,21(3):205-212
The dispersion behavior of agglomerates of several grades of fumed silica in poly(dimethyl siloxane) liquids has been studied as a function of particle morphology and applied flow conditions. The effects of primary particle size and aggregate density and structure on cohesivity were probed through tensile and shear strength tests on particle compacts. These cohesivity tests indicated that the shear strength of particle compacts was two orders of magnitude higher than the tensile strength at the same overall packing density. Experiments carried out in both steady and time‐varying simple‐shear flows indicate that dispersion occurs through tensile failure. In the steady‐shear experiments,enhanced dispersion was obtained at higher levels of applied stress and, at comparable levels of applied stress, dispersion was found to proceed faster at higher shear rates. Experiments conducted in time‐varying flows further corroborated the results obtained in tensile cohesivity tests. Experiments in which the mean and maximum stresses in the time‐varying flows were matched to the stresses produced in steady shear flows highlight the influence of flow dynamics on dispersion behavior. 相似文献