Conversion of Methane to Ethylene with BaCe_(0.9)Y_(0.1)Co_xO_(3-δ) Hydrogen Permeation Membrane

Dehydrogenation coupling of methane (DCM),which can be effectively used to produce low carbon alkenes,has the advantages of rich raw materials,simple reaction device,low energy consumption,etc.Herein,we report a series of Co doped perovskite porous-dense Ba Ce_(0.9)Y_(0.1)Co_xO_(3-δ)(BCYCx) membrane for DCM.After treatment in a reduced atmosphere,a large number of Co nanoparticles will exsolute on the surface of BCY.The metal-oxide interface is helpful to activate the C–H bonds,inhibit the carbon deposition,and so on.The XRD,SEM and XPS prove that Co nanoparticles homogeneously distributed on the BCYCx porous layers,which will create a large quantity of catalytic active sites.At 1100℃,the highest concentration of C_2 product was 5.66%(5.25%ethane+0.41%ethylene)in output gas when methane conversion reaches a maximum value of 24.8%,and the C_2 selectivity gets to 45.6%.We further demonstrate the catalytic performance of high-temperature DCM without obvious decrease after running for 30hours.     

TD-DFT Study on the Electronic Spectrum Properties of 2,7＇-（Ethylene）- bis-8-hydroxyquinoline and Its Derivatives

The structures of 2,7＇-（ethylene）-bis-8-hydroxyquinoline and its derivatives were optimized at the ground states using ab initio HF and B3LYP methods. At the same time, the molecular structures of the first singlet excited state for 2,7＇-（ethylene）-bis-8-hydroxyqulnoline and its derivatives were optimized by CIS/6-31G（d）. The absorption and emission spectra based on the above structures were obtained by the time-dependent density functional theory （TD-DFT） by the B3LYP method with the 6-31G（d） basis set. The calculated results of luminescence originate from the electronic transition from the hydroxphenol ring of 8-hydroxyquinoline A to the pyridine ring of 8-hydroxyquinoline B. Their luminescence wave bands can be tuned by different substituents on the ligand of 8-hydroxyquinoline.     

磁性碱木素胺稳定的Ru纳米粒子催化α-蒎烯加氢反应

通过Mannich反应在碱木素结构中引入胺源,再结合共沉淀法制备了包裹Fe₃O₄磁核的稳定金属粒子的碱木素胺载体,并进一步构建了催化可再生资源α-蒎烯加氢反应的Ru纳米粒子催化剂.通过元素分析、粉末X射线衍射、傅里叶变换红外光谱、电感耦合等离子体原子发射光谱、透射电子显微镜、热重分析和X射线光电子能谱等方法对该催化剂进行表征.结果表明,碱木素中的苯环和含氧基团均对金属粒子有稳定作用,但胺源的引入可更加有效地稳定金属粒子.经过对催化剂制备工艺、木质素类型、胺源类型和胺源含量的筛选,得到活性最优的催化剂Fe₃O₄@0.8ALN₁-Ru, Ru负载量为1.92 mmol/g, Ru粒子粒径为(2.1±0.5)nm.该催化剂在n(α-蒎烯)/n(Ru)=65.8, 1 MPa H₂条件下70℃催化1 mLα-蒎烯加氢反应2 h,可获得99.64%的α-蒎烯转化率和96.52%的顺式蒎烷选择性,并表现出良好的重复使用稳定性.     

Advanced Nanomaterials for Multimodal Molecular Imaging

The development of multimodal molecular imaging contrast agents based on versatile nanomaterials has recently attracted much attention in disease diagnosis and therapeutic delivery. Contrast agents made from nanoparticles and used for multimodal imaging in vivo provide a multidimensional pathophysiological overview of diseases. This review summarizes recently developed advanced nanomaterials for multimodal molecular imaging. We comprehensively discuss these nanoparticle contrast agents in terms of their targeting modalities, limitations in clinical translation and future directions.     

Stochastic and upscaled analytical modeling of fines migration in porous media induced by low-salinity water injection

Fines migration induced by injection of low-salinity water(LSW) into porous media can lead to severe pore plugging and consequent permeability reduction. The deepbed filtration(DBF) theory is used to model the aforementioned phenomenon, which allows us to predict the effluent concentration history and the distribution profile of entrapped particles. However, the previous models fail to consider the movement of the waterflood front. In this study, we derive a stochastic model for fines migration ...     

HL-2M偏滤器结构动力学分析

用有限元软件分析了动载荷作用下的偏滤器结构动力学响应。通过对动力学和静力学计算结果的对比,确定载荷的动态放大因子。计算结果表明,所设计的偏滤器结构在瞬态电磁力载荷作用下能满足设计准则的要求。     

基于大变形分析的动不定体系的求解

动不定体系由于内部存在机构位移,其求解过程不同于动定体系。为了全面了解动不定体系的受力性能,本文对其相容及非相容平衡方程的求解进行了详细的分析和推导;同时,由于动不定体系求解过程涉及大位移,本文对通常建立在小变形假定下的变形协调方程进行了重新推导,采用建立在大变形基础上的变形协调方程对有限机构进行求解,并由此编制了相应的计算程序。算例分析表明本文计算方法是精确和有效的,可用于确定动不定体系的平衡状态和内力。     

血管内光声图像的建模与仿真

为了给血管内光声(intravascular photoacoustic,IVPA)成像的图像重建算法和图像后处理算法提供数据源,为培训医师提供图像库,提出一种二维IVPA图像的建模与仿真方法。建立包含斑块的血管横截面模型,并对成像导管发射激光脉冲照射血管壁组织、血管壁组织产生光声信号、利用得到的一组光声信号重建IVPA图像整个过程进行仿真,得到血管横截面模型的二维IVPA灰阶图像,同时根据冠状动脉血管随心脏搏动的规律,实现序列图像的仿真。利用仿真模型得到的IVPA图像与原电磁吸收分布图接近程度较高。仿真模型的物理意义清晰,可得到质量稳定的IVPA图像。     

双城记——星系并合和星系对

在重子世界中,星系是宇宙构成的砖块,但是星系在宇宙中的分布却不是随机的。在大尺度上,星系的分布是网状的;在小尺度上,星系往往也会成对存在,比如本地星系群中的银河系和仙女座大星云。星系对最终会发生并合,而这个并合过程是星系增长的主要途径之一。对星系对进行的观测研究能够帮助人们理解星系的相互作用和增长过程。文章重点介绍了现代星系巡天中对星系对进行的观测,特别是中国的重大科学工程郭守敬望远镜在其中所发挥的作用。     

虚拟时间反转镜啁啾率键控的水声多用户通信

针对频率选择性衰落严重的浅海信道多用户通信问题,提出了一种虚拟时间反转镜(VTRM,Virtual Time Reversal Mirror)啁啾率键控(CRK,Chirp-Rate Keying)的水声多用户通信方式。该算法采用啁啾信号作为载波,接收端利用啁啾信号中心频率与分数阶傅里叶变换域的关系还原出原始信息,并使用虚拟时间反转镜技术减少了多径环境对系统的影响,采用啁啾调频率分集作为多址接入方式。在10 kHz的带宽内,可支持4个用户进行可靠通信,每用户通信速率425 bps。水池及海洋实验结果表明:该算法能够有效地传输数据,并且误码率在10^-3数量级以下。