全文获取类型
收费全文 | 4350篇 |
免费 | 746篇 |
国内免费 | 622篇 |
专业分类
化学 | 3214篇 |
晶体学 | 70篇 |
力学 | 190篇 |
综合类 | 33篇 |
数学 | 668篇 |
物理学 | 1543篇 |
出版年
2024年 | 18篇 |
2023年 | 124篇 |
2022年 | 187篇 |
2021年 | 194篇 |
2020年 | 226篇 |
2019年 | 234篇 |
2018年 | 202篇 |
2017年 | 160篇 |
2016年 | 232篇 |
2015年 | 240篇 |
2014年 | 261篇 |
2013年 | 351篇 |
2012年 | 384篇 |
2011年 | 346篇 |
2010年 | 241篇 |
2009年 | 268篇 |
2008年 | 283篇 |
2007年 | 243篇 |
2006年 | 199篇 |
2005年 | 175篇 |
2004年 | 124篇 |
2003年 | 108篇 |
2002年 | 112篇 |
2001年 | 96篇 |
2000年 | 94篇 |
1999年 | 62篇 |
1998年 | 43篇 |
1997年 | 36篇 |
1996年 | 56篇 |
1995年 | 46篇 |
1994年 | 41篇 |
1993年 | 39篇 |
1992年 | 34篇 |
1991年 | 40篇 |
1990年 | 32篇 |
1989年 | 21篇 |
1988年 | 22篇 |
1987年 | 23篇 |
1986年 | 20篇 |
1985年 | 15篇 |
1984年 | 16篇 |
1983年 | 9篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 11篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1957年 | 2篇 |
排序方式: 共有5718条查询结果,搜索用时 15 毫秒
81.
Anran Shi Xiumei Song Lei Wei Huiyuan Ma Haijun Pang Weiwei Li Xiaowei Liu Lichao Tan 《Molecules (Basel, Switzerland)》2022,27(23)
High-energy density supercapacitors have attracted extensive attention due to their electrode structure design. A synergistic effect related to core–shell structure can improve the energy storage capacity and power density of electrode materials. The Ni-foam (NF) substrate coupled with polypyrrole (PPy) conductive coating can serve as an internal/external bicontinuous conductive network. In this work, the distinctive PPy@FeNi2S4@NF and PPy@NiCo2S4@NF materials were prepared by a simple two-step hydrothermal synthesis with a subsequent in situ polymerization method. PPy@FeNi2S4@NF and PPy@NiCo2S4@NF could deliver ultrahigh specific capacitances of 3870.3 and 5771.4 F·g−1 at 1 A·g−1 and marvelous cycling capability performances of 81.39% and 93.02% after 5000 cycles. The asymmetric supercapacitors composed of the prepared materials provided a high-energy density of over 47.2 Wh·kg−1 at 699.9 W·kg−1 power density and 67.11 Wh·kg−1 at 800 W·kg−1 power density. Therefore, the self-assembled core–shell structure can effectively improve the electrochemical performance and will have an effective service in advanced energy-storage devices. 相似文献
82.
By using difference schemes, orthogonal partitions and a replacement method, some new methods to construct pure quantum error-correcting codes are provided from orthogonal arrays. As an application of these methods, we construct several infinite series of quantum error-correcting codes including some optimal ones. Compared with the existing binary quantum codes, more new codes can be constructed, which have a lower number of terms (i.e., the number of computational basis states) for each of their basis states. 相似文献
83.
通过纳米二氧化硅的硅烷化改性,使其在高矿化度盐水中可以稳定存在的前提下,研究了改性纳米颗粒与阳离子表面活性剂十二烷基三甲基氯化铵混合体系的溶液稳定性及协同稳定CO2泡沫的效果.研究结果表明,无机盐离子对改性纳米颗粒与阳离子表面活性剂间的静电吸引力具有屏蔽作用,且矿化度越高,屏蔽效果越明显,从而混合溶液更易于在高盐水中稳定;纳米颗粒表面的活性剂吸附层受二者浓度的影响,进而影响了颗粒的亲/疏水性;当混合体系中的表面活性剂浓度低于临界胶束浓度(CMC)时,混合溶液与CO2的界面张力高于单独活性剂溶液,而当活性剂浓度高于CMC时,对CO2-溶液界面张力几乎无影响,最低界面张力可降至6 mN/m左右;改性纳米颗粒的加入可以进一步提高CO2体相泡沫半衰期一倍以上,但受二者浓度比例的影响;纳米颗粒的加入有效提高了多孔介质中泡沫的表观黏度,最大增幅由20 mPa·s增至55 mPa·s左右,泡沫黏度增加接近3倍,增强了CO2泡沫驱的封堵作用. 相似文献
84.
磁流变弹性体(magnetorheological elastomer,MRE)因其独特的场相关性能在工程应用领域引起了广泛关注.论文介绍了MRE的最新发展,重点介绍导电性MRE在材料设计、力学行为和实际应用等方面的研究现状.论文从高性能导电性MRE的研制开始,讨论了材料与结构设计中涉及的关键问题;介绍了导电性MRE材料在磁场作用下的磁、力、电学行为的耦合作用机理和相关物理模型;之后对导电性MRE器件的研究现状进行了总结;最后展望了导电性MRE的发展潜力和面临的挑战. 相似文献
85.
将幂函数引入Eringen非局部线粘弹性本构,导出Riesz势形式的应力-应变关系.利用该关系,构造非局部弹簧和非局部阻尼器两类元件;利用元件的串联和并联,建立非局部Kelvin和非局部Maxwell粘弹性模型,推导模型的松弛模量和蠕变柔量.进一步,给出非局部粘弹性模型在生物组织超声波耗散建模中的应用. 相似文献
86.
Metasurface-based vectorial holography manifests itself as an advanced platform for large-capacity information storage, holographic display, and cryptography. However, a convenient and effective reconfigurable vectorial hologram generation mechanism still remains a challenge. Here, a rotation-driven reconfigurable vectorial holography scheme is developed via a dual-layer hybrid metasurface device, in which radiation-type and birefringent metasurfaces are cascaded hybridly. Thus, reconfigurable and highly customizable intensity and polarization response of holograms in the 3D space is achieved. Rotatable radiation-type metasurface (RTM) serves as an incidence-wavefront modulator to excite the non-rotatable birefringent metasurface (BM). The gradient descent optimization inverse design method is introduced to achieve the high-efficiency reconstruction of the Jones vector and Jones matrix distribution on both RTM and BM. On this basis, numerical analysis and experimental verification of 3-D reconfigurable vectorial holography are demonstrated in the microwave region. This scheme implies a new paradigm for 3-D reconfigurable vectorial holography and can lead to advances in high-capacity optical display, switchable meta-devices, and cryptography. 相似文献
87.
Xuan Shi Yu Sun Junhui Liu Wencai Liu Yan Xing Zhilong Xiu Yuesheng Dong 《Molecules (Basel, Switzerland)》2023,28(1)
Chemical epigenetic regulation (CER) is an effective method to activate the silent pathway of fungal secondary metabolite synthesis. However, conventional methods for CER study are laborious and time-consuming. In the meantime, the overall profile of the secondary metabolites in the fungi treated by the CER reagent is not well characterized. In this study, suberohydroxamic acid (SBHA), a histone deacetylase inhibitor, was added to a culture of Aspergillus aculeatus DL1011 and a new strategy based on LC-MS/MS analysis integrated with various metabolomic tools (MetaboAnalyst, MS-DIAL, SIRIUS and GNPS) was developed to characterize the profile of induced metabolites. As a result, 13.6%, 29.5% and 27.2% of metabolites were identified as newly biosynthesized, increasing and decreasing in abundance by CER, respectively. The structures of the 18 newly induced secondary metabolites were further identified by the new strategy to demonstrate that 72.2% of them (1 novel compound and 12 known compounds) were first discovered in A. aculeatus upon SBHA treatment. The accuracy of the new approach was confirmed by purification and NMR data analysis of major newly biosynthesized secondary metabolites. The bioassay showed that the newly biosynthesized compounds, roseopurpurin analogues, showed selective activities against DPPH scavenging, cytotoxicity and SHP1 inhibition. Our research demonstrated that CER was beneficial for changing the secondary metabolic profile of fungi and was an effective means of increasing the diversity of active metabolites. Our work also supplied a metabolomic strategy to characterize the profile changes and determine the newly induced compounds in the secondary metabolites of fungi treated with the chemical epigenetic regulator. 相似文献
88.
:根据Stevenson等效电路法设计了两个X波段低副瓣波导缝隙阵列天线。通过建立多个缝隙时的谐振长度提取模型,计算了存在缝隙间互耦时的谐振长度。两个阵列天线测试结果和仿真结果吻合良好,线阵中心频率实测增益为17.83 dB,其仿真结果为18.2 dB,实测副瓣为-28.12 dB,其仿真结果为-29.97 dB;平面阵列中心频率实测增益为27 dB,其仿真结果为27.9 dB, 实测H面副瓣为-27.2 dB,其仿真结果为-29.9 dB,实测E面副瓣为-22 dB,其仿真结果为-22 dB。 相似文献
89.
90.
正向成像技术是正向计算与反演相结合的密度重建技术的基础。为了正确获取闪光照相面光源下复杂客体的正向计算数值图像,提出了面光源点源化的思想,并用窗口化的探测系统模糊、径迹法等技术得到了更加准确的、含系统模糊的正向投影矩阵以及方程。利用含系统模糊的正向投影方程计算实验客体的正向投影,获得了与实验结果一致的边界信息。含系统模糊的正向投影方程和逆问题求解的约束共轭梯度法合成了整体密度重建方法。整体密度重建方法应用于FTO客体的模拟图像和实验图像,都能够将模糊控制在1~2个像素。 相似文献