全文获取类型
收费全文 | 238148篇 |
免费 | 8399篇 |
国内免费 | 4875篇 |
专业分类
化学 | 126366篇 |
晶体学 | 3190篇 |
力学 | 11654篇 |
综合类 | 290篇 |
数学 | 26814篇 |
物理学 | 83108篇 |
出版年
2021年 | 2808篇 |
2020年 | 3254篇 |
2019年 | 3362篇 |
2018年 | 3918篇 |
2017年 | 3728篇 |
2016年 | 5460篇 |
2015年 | 3973篇 |
2014年 | 5654篇 |
2013年 | 11653篇 |
2012年 | 10373篇 |
2011年 | 12035篇 |
2010年 | 8308篇 |
2009年 | 8145篇 |
2008年 | 10334篇 |
2007年 | 10266篇 |
2006年 | 9791篇 |
2005年 | 8486篇 |
2004年 | 7711篇 |
2003年 | 6730篇 |
2002年 | 6494篇 |
2001年 | 7209篇 |
2000年 | 5753篇 |
1999年 | 4595篇 |
1998年 | 3753篇 |
1997年 | 3713篇 |
1996年 | 3219篇 |
1995年 | 3157篇 |
1994年 | 2929篇 |
1993年 | 2680篇 |
1992年 | 3034篇 |
1991年 | 2897篇 |
1990年 | 2816篇 |
1989年 | 2554篇 |
1988年 | 2587篇 |
1987年 | 2553篇 |
1986年 | 2372篇 |
1985年 | 3063篇 |
1984年 | 3281篇 |
1983年 | 2659篇 |
1982年 | 2814篇 |
1981年 | 2751篇 |
1980年 | 2608篇 |
1979年 | 2705篇 |
1978年 | 2787篇 |
1977年 | 2805篇 |
1976年 | 2864篇 |
1975年 | 2649篇 |
1974年 | 2625篇 |
1973年 | 2755篇 |
1972年 | 1743篇 |
排序方式: 共有10000条查询结果,搜索用时 326 毫秒
981.
After carefull analysis in a turbulent zero-pressure gradient flow, various simple algebraic turbulence models were applied to the almost separated flow on the upperside of an airfoil at incidence. The Johnson-King and Horton non-equilibrium (or rate equation) models give clearly improved results. 相似文献
982.
This Review discusses the synthesis and characterization by our Group of new antibiotics belonging to the class of penicillins, cephalosporins and rifamycins with ferrocenyl and 1, 1′-ferrocenilene residues in the molecule. As reactants for 6-aminopenicillanic acid (6-APA) and 7-aminocephalosporanic acid (7-ACA) the following were used: 1, 1-bis(chlorocarbonyl)ferrocene, ferrocenyl sulfochloride, 1, 1′-ferrocenylenedisulfochloride and thioglycolic acids S-modified with ferrocene. In the synthesis of rifamycins, the hydrazides of the thioglycolic acids, S-modified with ferrocene, were employed as nucleophilic agents. The synthesized intermediates were characterized by elemental analysis, TLC, IR, UV and 1H NMR spectra. The characterization of new antibiotics was made by TLC, IR and UV spectral analysis. Biological activity was tested on Gram-negative and Gram-positive bacteria. Good activity is reported towards Gram-positive bacteria in the case of derivatives containing residues of thioglycolic acid S-modified with ferrocene, the antibacterial activity being similar to that of amoxicillin, carbenicillin and cephalothin. All compounds are inactive towards Gram-negative bacteria. 相似文献
983.
The gravitational interaction between grooves machined in a hollow cylindrical mass of uniform density, and an external point mass, is derived in terms of the Associated Legendre functions, and the parametric form of the coupling coefficients is presented. The cross-sections of the grooves, which are regularly spaced in azimuth, are in the form of truncated sectors of the cylinder's end-faces. This theory is applied to the test-masses for the Satellite Test of the Equivalence Principle (STEP) experiment, for which four grooves have been assumed, and an expression for the axialforce is derived which is more than 104 times faster to compute than a Monte-Carlo integration of similar accuracy. Following this analysis it is suggested that the STEP test-masses should carry at least 6 grooves. This theory has wider application to gravitational problems involving general sectored cylindrical bodies. 相似文献
984.
We study the stochastic dynamics of deposition-evaporation cooperative processes of dimers, trimers, etc., in two- and higher-dimensional lattices. The dimer system in bipartite lattices allows for an exact solution of dynamic correlations and scaling functions by means of a quantum spin equivalence. Autocorrelations exhibit a diffusive asymptotic kinetics and crossovers of different dynamic regimes in highly anisotropic lattices. Monte Carlo simulations combined with finite-size scaling arguments support the validity of the diffusive picture in more general situations. Steady-state coverages and diffusion constants are obtained using mean-field approaches, spin wave calculations, and random walk analyses in nearly jammed configurations. 相似文献
985.
A number of biphenyl, terphenyl analogues and ethynes which contain a pyrazine ring have been made and their liquid crystal transition temperatures, together with examples of birefringence measurements, are reported. All the 2,5-disubstituted pyrazine systems are liquid crystalline showing high birefringence values for the biphenyl and terphenyl analogues, whereas the 1,5-disubstituted systems are not liquid crystalline. The pyrazine ethyne systems exhibit very high birefringence values. X-ray diffraction has been used to identify the liquid crystal phases of 2-n-nonyloxy-5-(4'-propylbiphenyl-4-yl)pyrazine. 相似文献
986.
Ch. M. Hardalov K. D. Stefanov D. Sueva 《Applied Physics A: Materials Science & Processing》1995,61(2):107-109
Deep-Level Transient Spectroscopy (DLTS) measurements were carried out on silicon p+nn+ diodes before and after irradiation with fast neutrons at room temperature with fluences 5.5×1011 and 1.0×1012 n/cm2. It was found out, that all preexisting defects decreased their amplitudes during irradiation, while only one defect, identified as a single-charged divacancy, increased in amplitude. An interpretation is proposed in terms of the cluster model, and the applicability of the DLTS is discussed. 相似文献
987.
D. Hugh Powell Andr E. Merbach Gabriel Gonzlez Ern Brücher Kroly Micskei M. Francesca Ottaviani Klaus Khler Alex Von Zelewsky Oleg Ya. Grinberg Yakob S. Lebedev 《Helvetica chimica acta》1993,76(5):2129-2146
EPR Spectra have been measured for aqueous solutions of a series of Gd3+ complexes at variable temperature and a range of magnetic fields; S-band (0.14 T), X-band (0.34 T), Q-band (1.2 T), and 2-mm-band (5.0 T). The major contribution to the observed line widths is magnetic-field-dependent and is interpreted as being due to the modulation of the zero-field splitting produced by distortion of the complexes from perfect symmetry. The transverse and longitudinal relaxation matrices for an 8S ion with such an interaction have been calculated using Redfield theory with vector-coupling methods, and diagonalised numerically to obtain relaxation rates and intensities for the degenerate transitions which contribute to the multiplet. The observed line width, which is inversely proportional to the magnetic field at low temperatures, is best described by the intensity-weighted mean transverse relaxation time for the four transitions with non-zero intensity. A least-squares fit of the data yields the square of the zero-field splitting tensor, Δ2, and a correlation time, τv, with activation energy, Ev. The physical significance of these parameters and the extent of validity of the theoretical approach are considered. The parameters are used to predict the magnetic-field dependence of the longitudinal and transverse electronic relaxation times, which are discussed in the context of their relevance to 1H-NMR relaxivity. 相似文献
988.
V. D. Fedotov N. P. Obuchov R. A. Zadikhanov J. Spěváček J. Straka 《Applied magnetic resonance》1993,4(4):491-511
The combined analysis of1H and13C NMR relaxation data in solid lysozyme and some typical homopolypeptides was carried out by using “model-free” approach. Three types of relaxation transitions (γ’, γ and β) were revealed in the temperature range investigated. The microdynamical parameters of these motions were determined. From the comparison of these parameters with those of selected synthetic polymers it follows that the molecular motions in proteins and synthetic polymers are of the same nature. All these motions show pronounced anisotropic character. In the investigated temperature range no molecular motions corresponding to α-relaxation (liquid-like) transition were revealed. The hydration effects on parameters of the motions in proteins were considered. The most pronounced effect takes place for β-transition. The effect of Brownian rotation of protein molecule in solution on measured correlation function of local motions was also discussed. 相似文献
989.
用漫反射红外光谱和光声红外光谱研究了金属羰基化合物(CpFe(CO)2)2Cp=η^5-C5H5与酸性,中性和碱性Al2O3及TiO2的相互作用,结果表明,在Al2O3表面生成的洗生物种类及浓度与Al2O3的酸碱度明显相关,在酸性Al2O3表面,主要存在衍生物(CpFe(CO)2Fe-H-Fe(CO2Cp)^+及少量的CpFe(CO)2(-O-);在中性Al2O3表面存在的CpFe(CO)2(-O 相似文献
990.
D. A. Rakhimov M. Kh. Malikova A. A. Vakhabov I. O. Ruziev T. R. Abdurakhmanov 《Chemistry of Natural Compounds》1995,31(2):260-261
Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89 14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 313–314, March–April, 1995. Original article submitted November 7, 1994. 相似文献