首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   56991篇
  免费   13284篇
  国内免费   5471篇
化学   57544篇
晶体学   731篇
力学   1793篇
综合类   310篇
数学   4551篇
物理学   10817篇
  2024年   57篇
  2023年   543篇
  2022年   726篇
  2021年   1060篇
  2020年   2270篇
  2019年   3559篇
  2018年   1901篇
  2017年   1594篇
  2016年   4451篇
  2015年   4650篇
  2014年   4782篇
  2013年   5735篇
  2012年   4984篇
  2011年   4218篇
  2010年   4354篇
  2009年   4265篇
  2008年   3834篇
  2007年   2937篇
  2006年   2683篇
  2005年   2664篇
  2004年   2261篇
  2003年   2043篇
  2002年   2767篇
  2001年   2062篇
  2000年   1802篇
  1999年   866篇
  1998年   398篇
  1997年   283篇
  1996年   307篇
  1995年   253篇
  1994年   245篇
  1993年   209篇
  1992年   159篇
  1991年   164篇
  1990年   107篇
  1989年   82篇
  1988年   70篇
  1987年   68篇
  1986年   68篇
  1985年   39篇
  1984年   31篇
  1983年   37篇
  1982年   14篇
  1981年   18篇
  1980年   11篇
  1979年   7篇
  1976年   11篇
  1975年   10篇
  1973年   9篇
  1959年   9篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
Let κ be non-negative integer. The unoriented bordism classes, which can be represented as [RP(ξ^κ)] where ξ^κ is a k-plane bundle, form an ideal of the unoriented bordism ring MO.. A group of generators of this ideal expressed by a base of MO. and a necessary and sufficient condition for a bordism class to belong to this ideal are given.  相似文献   
102.
103.
104.
A graph G is N2locally connected if for every vertex ν in G, the edges not incident with ν but having at least one end adjacent to ν in G induce a connected graph. In 1990, Ryjá?ek conjectured that every 3‐connected N2‐locally connected claw‐free graph is Hamiltonian. This conjecture is proved in this note. © 2004 Wiley Periodicals, Inc. J Graph Theory 48: 142–146, 2005  相似文献   
105.
The mixed complex [Ni(L)(L')](ClO4)2 has been synthesized using 2-aminoethyl- bi(3-bi-aminopropyl)amine with phen (1,10-phenanthroline) in the presence of Ni(II) ion, and its structure was determined by X-ray diffraction. The crystal crystallizes in monoclinic, space group P21/c with a = 13.713(2), b = 13.1466(19), c = 14.780(2) (A), β = 97.620(3)°, V = 2640.9(7)(A)3, F(000) = 1272, Z = 4, Dc = 1.540 g/cm3, R = 0.0536 and wR = 0.1207. The Ni2+ ion is six- coordinated to furnish a distorted octahedral geometry.  相似文献   
106.
The irreversibility field (Hirr) of Y-based superconductor is much higher than that of Bi-based superconductor. Y-based superconductor is capable of maintaining stable electrical currents in high magnetic field and electric field, so it is a better suited mate-rial for electric-current applications. Commonly, the Y-based tapes comprise a YBCO thick film deposited on a flexible substrate, typically with an intermediate buffer layer, and an overcoat of noble metal. In this process, the interm…  相似文献   
107.
A Promising MoO_x-based Catalyst for n-Heptane Isomerization   总被引:1,自引:0,他引:1  
The increasing demand for higher-octane gasoline and the regulations limiting the amount of aromatics in the fuel motivate the interest in catalytic isomerization of n-alkanes. In the last ten years, transition metal oxides or oxycarbides based on molybdenum or tungstate have attracted much attention due to their high activity and isomerization selectivity compared to the conventional bifunctional supported platinum catalyst and high resistance to sulphur and nitrogen catalyst poisons1-5. Ma…  相似文献   
108.
Yanmao Shi  Ping Wu  Pan Du  Chenxin Cai 《Acta Physico》2006,22(10):1227-1233
A new electroactive polynuclear inorganic compound of rare earth metal, gadolinium hexacyanoferrate (GdHCF), was prepared and characterized using the techniques of FTIR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectrometry, X-ray photoelectron spectroscopy (XPS), ICP atomic emission spectroscopy, and EDX. The results of ICP atomic emission spectroscopy, EDX, and TGA indicated that the prepared GdHCF sample had a stoichiometry of NaGdFe(CN)6·12H2O (when GdHCF was prepared in NaCl solution). The FTIR spectrum of GdHCF showed that there were two types of water molecules in the structure of GdHCF: one was the interstitial water (5 H2O), which resulted from the association of water due to H-bonding, and the other was water coordinated with Gd (7 H2O). The results obtained using XPS showed that the oxidation state of Fe and Gd in the GdHCF sample was +2 and +3, respectively. GdHCF was immobilized on the surface of spectroscopically pure graphite (SG) electrode forming the GdHCF/SG electrode, and the solid-state electrochemistry of the resultant electrode was studied using cyclic voltammetry. The cyclic voltammetric results indicated that the GdHCF/SG electrode exhibited a pair of well-defined and stable redox peaks with the formal potential of E0′=(197±3) mV. The effects of the concentration of the supporting electrolyte on the electrochemical characteristics of GdHCF were studied, and the results showed that the value of E0′ increased linearly with the activity of the cationic ion of the supporting electrolyte (lgaNa+), with a slope of 54.1 mV, which may become a novel method for determining the activity of Na+ in solution. Further experimental results indicated that GdHCF had electrocatalytic activities toward the oxidation of dopamine (DA) and ascorbic acid (AA), and the electrocatalytic current increased linearly with the concentration of DA (or AA) in the range of 1.0–10.0 mmol·L?1 (for DA) or 0.5–20.0 mmol·L?1 (for AA).  相似文献   
109.
In the title compound, catena‐poly[lithium‐μ3‐ethyl­ene­diphos­phon­ato], [Li(C2H7O6P2)]n, the supra­molecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethyl­ene­diphosphon­ate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand.  相似文献   
110.
The inhomogeneous Dirichlet problems concerning divergence form elliptic equations are studied. Optimal regularity requirements on the coefficients and domains for the W1,p theory, 1 < p < ∞, are obtained. The principal coefficients are supposed to be in the John‐Nirenberg space with small BMO seminorms. The domain is a Reifenberg domain. These conditions for the W1,p theory not only weaken the requirements on the coefficients but also lead to a more general geometric condition on the domains. In fact, these domains might have fractal dimensions. © 2004 Wiley Periodicals, Inc.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号