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991.
992.
Dong Han Kim 《Journal of heterocyclic chemistry》1981,18(4):855-856
The treatment of N-(2-hydroxyphenyl)anthranilic acids with cyanogen bromide in the presence of triethylamine gave dibenz[b,e][1,4]oxazepin-11-(5H)ones in good yields. 相似文献
993.
Jack Gelfand Muhammad Zughul Herschel Rabitz C.J. Han 《Journal of Quantitative Spectroscopy & Radiative Transfer》1981,26(4):303-305
We have measured the absorption intesities for a number of rotation-vibration lines in the 4-0 through 7-0 overtone bands of HCl utilizing a Fourier transform spectrometer and a 409.6 m path length White cell. Individual line strengths, band strengths, dipole matrix elements, and Herman-Wallis factors are presented. 相似文献
994.
Starting from simple topological arguments due to Dirac on the classical rotational properties of extended rigid bodies, we abstract the concept of a finite-size spinor (FSS). The FSS is a concept distinct from both point spinors (e.g., electrons) and composite spinors (e.g., nuclei), and suggests a new model for baryons. The FSS offers a natural explanation of threeness for the quarks, excludes the existence of free quarks, denies the operational definition of quark spin statistics, and, moreover, leads to the dual model of hadronic interactions.Research supported in part by the National Science Foundation, the Army Research Office (Durham), and the U.S. Atomic Energy Commission. 相似文献
995.
Chien-Pai Han 《Annals of the Institute of Statistical Mathematics》1973,25(1):335-344
Summary In estimating the mean μ
y
of one variable in a bivariate normal distribution, the experimenter can use the other variable,x, as an auxiliary variable to increase precision. In particular, if μ
x
is known, he can use the regression estimator. When μ
x
is unknown, a preliminary test can be performed and the estimator will be made to depend on the result of the preliminary
test. The bias and mean square error of the preliminary test estimator are obtained and the relative efficiency is are discussed. 相似文献
996.
997.
998.
Wang H Ciobanu L Webb A 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,173(1):134-139
A new hardware-based approach is presented to reduce data acquisition times in multi-dimensional NMR spectroscopy using a multiple-coil probe. Using a four-coil setup, two-dimensional COSY and TOCSY spectra were acquired in one-quarter the time of conventional spectra by simultaneous acquisition of different effective t1 evolution times for each coil. Data processing consists of simple phase-shifting and intensity normalization of the individual data sets, and results in spectra almost identical to those acquired in a conventional manner. This method can potentially be integrated with other new data acquisition and processing schemes for further increases in data acquisition speed. 相似文献
999.
Sonocatalytic degradation of methyl orange in the presence of TiO2 catalysts and catalytic activity comparison of rutile and anatase 总被引:5,自引:0,他引:5
Rutile and anatase titanium dioxide (TiO(2)) powders were used as sonocatalysts for the degradation of methyl orange which was used as a model compound. Ultrasound was used as an irradiation source. It was found that the sonocatalytic degradation ratios of methyl orange in the presence of TiO(2) powder were much better than ones without any TiO(2), but the sonocatalytic activity of rutile TiO(2) particles was obviously higher than that of anatase TiO(2) particles. Although there are many factors influencing sonocatalytic degradation of methyl orange, the experimental results show that the best degradation ratio of methyl orange can be obtained when the experimental conditions of the initial methyl orange concentration of 10 mg/l, rutile TiO(2) added amount of 500 mg/l, ultrasonic frequency of 40 kHz, output power of 50 W, pH=3.0 and 40 degrees C within 150 min were adopted. In addition, the catalytic activity of reused rutile TiO(2) catalyst was also studied and found to be better than new rutile TiO(2) catalyst sometimes. All experimental results indicated that the method of the sonocatalytic degradation of organic pollutants in the presence of TiO(2) powder was an advisable choice for treating non- or low-transparent organic wastewaters. 相似文献
1000.
Li H Chen DL Zhong S Xu B Han BS Hu KS 《The journal of physical chemistry. B》2005,109(22):11273-11278
Bacteriorhodopsin (bR) trimers naturally form two-dimensional hexagonal crystals in purple membrane (PM), which make it very stable. However, the dnaturation of bR was found to occur during a very narrow pH range when the pH was increased above 12.0, as indicated by inactivation of the photochemical cycle observed by flash photolysis kinetic spectra. Here, atomic force microscopy was used to study the surface structural changes of PM during the denaturation process induced by high pH. Together with the absorption and fluorescence spectra, it was found that the structural changes could be divided into three steps. First, some hydrophobic amino acids of bR become exposed to the aqueous environment and PM loses its 2D crystalline structure, transforming into the so-called "nonisland" structure. Second, bR molecules are extracted out of membrane and form protrusions on the surface like islands in the sea; therefore, the "nonisland" structure transforms into the "island" structure. Finally, most bRs break off from the membrane and form large depositions. 相似文献