The origin of the high performance of tungsten carbides/carbon nanotubes supported Pt catalysts for methanol electrooxidation

The Pt supported on WC modified MWCNT catalysts (PtWC/MWCNT) were synthesized by the combination of organic colloidal and intermittent microwave heating (IMH) methods for the first. The results proved the better performance of the PtWC/MWCNT catalyst than that of Pt/C for methanol oxidation in terms of the onset potential and peak current density. The synergistic effect between Pt nanoparticles and WC and the structure effect of the MWCNTs could be the reasons to result in the high activity. The CO stripping test provided the evidence that the onset potential shift for methanol oxidation is consistent with the reduction in the overpotential for the CO oxidation on PtWC/MWCNT catalyst. Therefore, the mechanism of the high performance for methanol oxidation on PtWC/MWCNT catalyst is probably the easier oxidation of CO-like species which cause high overpotential for further oxidation of methanol.     

A new alkaloid from Lycoris aurea

A new alkaloid was isolated from the bulbs of Lycoris aurea(L'Herit.) Herb.Its structure was established as 3-o-ethyltazettinol through chemical and spectroscopic studies including 2D NMR.     

On the resolution and optimization of a system of fuzzy relational equations with sup-T composition

This paper provides a thorough investigation on the resolution of a finite system of fuzzy relational equations with sup-T composition, where T is a continuous triangular norm. When such a system is consistent, although we know that the solution set can be characterized by a maximum solution and finitely many minimal solutions, it is still a challenging task to find all minimal solutions in an efficient manner. Using the representation theorem of continuous triangular norms, we show that the systems of sup-T equations can be divided into two categories depending on the involved triangular norm. When the triangular norm is Archimedean, the minimal solutions correspond one-to-one to the irredundant coverings of a set covering problem. When it is non-Archimedean, they only correspond to a subset of constrained irredundant coverings of a set covering problem. We then show that the problem of minimizing a linear objective function subject to a system of sup-T equations can be reduced into a 0–1 integer programming problem in polynomial time. This work generalizes most, if not all, known results and provides a unified framework to deal with the problem of resolution and optimization of a system of sup-T equations. Further generalizations and related issues are also included for discussion.     

Synthesis,Crystal Structure and Magnetic Behaviour of {[Co(dimb)2(H2O)2]·(NO3)2·(H2O)2}n

The title complex {[Co(dimb)₂(H₂O)₂]·(NO₃)₂·(H₂O)₂}_n ( 1 ) (dimb = 1,3‐di(imidazol‐1‐ylmethyl)‐5‐methylbenzene) has been hydrothermally synthesized by the reaction of dimb with Co(NO₃)₂·6H₂O in aqueous solution. The cobalt(II) atoms are linked by bridging dimb ligands to form 2D corrugated and wavy networks containing Co₄(dimb)₄ macrocyclic motifs. Two neighboring independent layers interlinked each other in a parallel fashion to construct three‐dimensional structure by O–H···O, N–H···O and C–H···O hydrogen bonds. Magnetic measurement shows the weak antiferromagnetic interaction with a one‐dimensional chain model in the range of 5–300 K, with J of –0.68 cm⁻¹.     

拟共形映射和John域

本文研究了(R)∫ΩBn中的John域与一致域和线性局部连通域的关系.利用平面中John域和拟圆的关系,获得了(R)∫ΩBn中的John域成为一致域和线性局部连通域的几个充分条件,它们是(R)2的推广.     

A covalent attraction between two molecular cation TTF·+

The optimized structure of the tetrathiafulvalence radical-cation dimer (TTF·⁺-TTF·⁺) with all-real frequencies is obtained at MP2/6-311G level, which exhibits the attraction between two molecular cation TTF·⁺. The new attraction interaction is a 20-center-2-electron intermolecular covalent π/π bonding with a telescope shape. The covalent π/π bonding has the bonding energy of about ?21 kcal·mol^?1 and is concealed by the Coulombic repulsion between two TTF·⁺ cations. This intermolecular covalent attraction also influences the structure of the TTF·⁺ subunit, i.e., its molecular plane is bent by an angle θ = 5.6°. This work provides new knowledge on intermolecular interaction.