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111.
Robin D. Rogers Philip D. Richards 《Journal of inclusion phenomena and macrocyclic chemistry》1987,5(5):631-638
The title complex was crystallized from a saturated solution of 18-crown-6 in nitromethane at 5°C and cooled to –150°C prior to X-ray diffraction data collection. At –150° C 18-crown-6·2(CH3NO2) is monoclinic,P21/n witha=9.290(2),b=7.864(6),c=13.627(8) Å, =1000.84(4)° andD
calc=1.31 g cm–3 for Z=2. Leastsquares refinement using 1521 independent observed reflections [F
o5(F
o)] led to a final conventionalR value of 0.041. The complex at –150°C is isostructural with its room temperature structure with the exception of the orientation of the methyl hydrogen atoms and their crown ether oxygen interactions. The methyl group hydrogen atoms were fully refined isotropically. The crown ether resides around a center of inversion and hasD
3d symmetry. There is one methyl hydrogen...crown interaction at 2.35(3) Å, one apparently bifurcated hydrogen bond utilizing a second methyl hydrogen atom (2.55(3), 2.65(3) Å) and the third hydrogen atom is actually directed away from the crown ring (closest H...O contact=2.67(3) Å).
Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82048 (5 pages).For part 2, see reference [24]. 相似文献
112.
Robin D. Clark 《Journal of heterocyclic chemistry》1983,20(5):1393-1395
N-substituted 4-(2-morpholinyl)indoles were prepared from 1-(t-butoxycarbonyl)-4-acetylindole (7) which was itself prepared from 4-cyanoindole. Bromination of ketone 7, followed by reaction with amines and subsequent sodium borohydride reduction, gave amino alcohols. These were converted to α-chloro amides that were cyclized to lactams. Lithium aluminum hydride reduction served both to remove the t-BOC protecting group and to reduce the lactams to the 4-(2-morpholinyl) indoles. 相似文献
113.
Krishnakumar V Xavier RJ Chithambarathanu T 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):931-939
This work deals with the vibrational spectroscopy of succinimide and N-bromosuccinimide. The mid and far FTIR and FT-Raman spectra were measured in the condensed state. The fundamental vibrational frequencies and intensity of vibrational bands were evaluated using density functional theory (DFT) using standard B3LYP/6-31G(*) and B3LYP/6-311+G(**) methods and basis set combinations. The vibrational spectra were interpreted, with the aid of normal coordinate analysis based on a scaled quantum mechanical force field. The infrared and Raman spectra were also predicted from the calculated intensities. Comparison of simulated spectra with the experimental spectra provides important information about the ability of the computational method to describe the vibrational modes. Unambiguous vibrational assignment of all the fundamentals were made using the total energy distribution (TED). 相似文献
114.
By the use of stochastic theory it is clearly shown that two types of emission should to fluctuations such as would occur during interactions with their environment are resonantly driven by light. In our approach the electromagnetic field is treated in a classical manner and decay is introduced by a Wigner-Weisskopfansatz. The two types of emission should occur for a three-level system and relaxation to other levels is not involved in the mechanism. Also included is a discussion of operational definitions of fluorescence (and other spontaneous emissions) and of the relationship between absorption and scattering in terms of dephasing or T2 processes, especially as this relates to conventional emission phenomena. 相似文献
115.
A new approach is developed for estimating the limit of detection in second-order bilinear calibration with the generalized rank annihilation method (GRAM). The proposed estimator is based on recently derived expressions for prediction variance and bias. It follows the latest IUPAC recommendations in the sense that it concisely accounts for the probabilities of committing both types I and II errors, i.e. false positive and false negative declarations, respectively. The estimator has been extensively validated with simulated data, yielding promising results. 相似文献
116.
Haplotypic variation within and among the Ascaris populations representing six provinces in China was investigated. Mitochondrial DNA regions in the cytochrome c oxidase subunit 1 (cox1) and NADH dehydrogenase subunit 1 (nad1) genes were amplified by PCR from total genomic DNA samples (n > 720) from Ascaris individuals from humans and pigs, and subjected to mutation scanning and subsequent selective sequencing. For the cox1, ten different electrophoretic profiles were recorded for human Ascaris, and the same number for pig Ascaris, one of them being common to both host species. For the nad1, 11 different profiles were detected for human Ascaris, and 15 for pig Ascaris. Having defined all haplotypes (20 for pcox1 and 26 for pnad1) by sequencing, their frequencies were estimated in each of the two host species and each of the six provinces. For each mitochondrial region, the frequency of the different haplotypes varied considerably, depending on host species and geographical origin. Analysis of the sequence data (representing all haplotypes for each mitochondrial locus) by F-statistics indicated restricted gene flow between human Ascaris and pig Ascaris, and supported the conclusions from previous molecular epidemiological investigations that pigs are not a significant source of Ascaris infection in humans in endemic regions. 相似文献
117.
Two new nickel(II) end-to-end azido-bridged compounds, cis-catena-[NiL(2)(&mgr;-N(3))](n)()(ClO(4))(n)().nH(2)O (1) and [Ni(2)L(4)(&mgr;-N(3))(2)](PF(6))(2) (2), were synthesized and characterized; L is 2-(aminoethyl)pyridine. The crystal structures of 1 and 2 were solved. Complex 1: monoclinic system, space group P2(1)/a, a = 8.637(2) ?, b = 18.9995(7) ?, c = 12.3093(7) ?, beta = 105.92(2) degrees, Z = 4. Complex 2: triclinic system, space group P&onemacr;, a = 9.139(7) ?, b = 10.124(3) ?, c = 12.024(2) ?, alpha = 70.407(14) degrees, beta = 84.19(2) degrees, gamma = 67.67(4) degrees, Z = 1. In the two complexes the nickel atom is situated in a similarly distorted octahedral environment. The two complexes are different; 1 is a one-dimensional helicoidal complex with the two L ligands and the two end-to-end azido bridges in a cis arrangement while complex 2 is a dinuclear system with two end-to-end azido bridges, indicating the extreme importance of the counteranion present (ClO(4)(-) for 1 and PF(6)(-) for 2). The magnetic properties of the two compounds were studied by susceptibility measurements vs temperature. The chi(M) vs T plot for 1 shows the shape for a weakly antiferromagnetically coupled nickel(II) one-dimensional complex without a maximum until 4 K. In contrast, for complex 2 the shape of the chi(M) vs T curve shows a maximum near 40 K, indicating medium antiferromagnetic coupling. From the spin Hamiltonian -J(ij)()S(i)()S(j)(), J values for 1 and 2 were less than -1 and -29.1 cm(-)(1), respectively. The magnetic behavior for 1 and 2 may be explained in terms of the overlap between magnetic orbitals, taking into account the torsion of the Ni(II) atoms and azido-bridging ligands in the two structures. 相似文献
118.
The synthesis and full characterization of a number of amino acid and dipeptide derivatives with sulfur-containing side chains derived from ferrocene carboxylic acid and ferrocene-1,1′-dicarboxylic acid is presented. In particular, compounds Fc-CO-(Aaa)n-OMe (4) and Fe[C5H4-CO-(Aaa)n-OMe]2 (3) with (Aaa)n = Cys(Bzl) (a), Cys(Bzl)-Cys(Bzl) (b), Cys(p-OMe-Bzl) (c), Cys(p-OMe-Bzl)-Cys(p-OMe-Bzl) (d), Met (e), and Met-Met (f) were prepared. Also, the free acid derivatives Fe[C5H4-CO-Met-OH]2 (6e) and Fc-CO-Met-OH (7e) were prepared and characterized. The solid state structures of 3a, 4b, and 4e were determined by single crystal X-ray diffraction. Compound 3a shows a 1,3′ substitution pattern on the Cp rings in the solid state. Structures in solution were determined by NMR, IR and CD spectroscopy, with particular emphasis on the question of hydrogen bonding and helical chirality of the metallocene. As an example, the full assignment for the Cp signals in the disubstituted derivative 3a was achieved by simulation of the 1H NMR signals from the cyclopentadienyl ring in combination with 2D-NOESY spectra. In solution, 3a has the known 1,2′ substitution pattern, which is stabilized by intramolecular hydrogen bonds. 相似文献
119.
Sylvie BertinJean-Jacques Robin 《European Polymer Journal》2002,38(11):2255-2264
Recycling of mixed plastic wastes composed of low-density polyethylene (LDPE) matrix and polypropylene (PP) was carried out by compounding using single-screw or twin-screw extruders. Blends of virgin polymers have been prepared to compare mechanical properties of both virgin and regenerated materials. First, a model composition of virgin LDPE/PP blend was prepared to study the effect of process parameters and that of different types of compatibilizers. Second, the results were applied to plastic wastes coming from industrial post-consumer plastic wastes. By adding compatibilizing agents such as ethylene-propylene-diene monomer, ethylene-propylene monomer, or PE-g-(2-methyl-1,3-butadiene) graft copolymer, elongation at break and impact strength were improved for all blends. The effect of these various copolymers is quite different and is in relation with their chemical structure. The recycled blends exhibit suitable properties leading to applications that require good mechanical properties. 相似文献
120.
Lou Y Horikawa M Kloster RA Hawryluk NA Corey EJ 《Journal of the American Chemical Society》2004,126(29):8916-8918
A novel chiral Rh(II) catalyst (1) is introduced for the [2 + 1]-cycloaddition of ethyl diazoacetate to terminal acetylenes and olefins with high enantioselectivity. The catalyst 1 consists of one acetate bridging group and three mono-N-triflyldiphenylimidazoline-2-one bidentate ligands (DPTI) spanning the Rh(II)-Rh(II) metallic center in a structure that was determined by single-crystal X-ray diffraction analysis. A rational mechanism is advanced that provides a straightforward explanation for the enantioselectivity and absolute stereochemical course of the [2 + 1]-cycloaddition reactions. A key element in this explanation is the cleavage of one of the Rh-O bonds of the bridging acetate group in the intermediate Rh-carbene complex to form a new pentacoordinate Rh carbene complex (formally 1.5 valent Rh) that can undergo [2 + 2]-cycloaddition with the C-C pi-bond of the acetylenic or olefinic substrate. Reductive elimination of the resulting adduct affords the cyclopropene or cyclopropane product. The C2-symmetry of the two DPTI ligands orthogonal to the bridging acetate also contributes to the high observed enantioselectivity and mechanistic clarity. The catalyst 1, which functions effectively at 0.5 mol %, can be recovered efficiently for reuse. Its ready availability, robustness, and effectiveness suggest it as a useful addition to the list of practical chiral Rh(II) catalysts for synthesis. 相似文献