首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   896篇
  免费   10篇
  国内免费   5篇
化学   435篇
晶体学   20篇
力学   31篇
数学   118篇
物理学   307篇
  2023年   5篇
  2019年   6篇
  2016年   7篇
  2015年   9篇
  2014年   14篇
  2013年   44篇
  2012年   30篇
  2011年   31篇
  2010年   14篇
  2009年   9篇
  2008年   27篇
  2007年   31篇
  2006年   40篇
  2005年   27篇
  2004年   28篇
  2003年   29篇
  2002年   25篇
  2001年   20篇
  2000年   29篇
  1999年   18篇
  1998年   12篇
  1997年   11篇
  1996年   12篇
  1995年   10篇
  1994年   10篇
  1993年   15篇
  1992年   18篇
  1991年   20篇
  1990年   11篇
  1989年   12篇
  1988年   9篇
  1987年   13篇
  1986年   13篇
  1985年   16篇
  1984年   11篇
  1983年   13篇
  1982年   20篇
  1981年   26篇
  1980年   17篇
  1979年   23篇
  1978年   15篇
  1977年   23篇
  1976年   20篇
  1975年   15篇
  1974年   9篇
  1973年   22篇
  1972年   12篇
  1971年   8篇
  1970年   5篇
  1968年   5篇
排序方式: 共有911条查询结果,搜索用时 375 毫秒
81.
Gauge theories in two dimensions generate masses for the gauge bosons via the Schwinger mechanism. This mechanism is studied in two models based on a direct product group gauge invariance. The gauge boson mass spectrum is determined in each case.  相似文献   
82.
Mature radula pieces from the chitonAcanthopleura hirtosa were studied using Mössbauer spectroscopy. The magnetite present in the radulae was found to have a distribution of Verwey transition temperatures in the range 85–100K. It was deduced that the magnetite was non-stoichiometric with an average formula Fe2.98O3. About 10% of the Fe in the radulae was in the form of maghemite and about 19% was in the form of paramagnetic or superparamagnetic phases.  相似文献   
83.
Hyperfine Interactions - Horse spleen apoferritin was reconstituted with varying numbers of iron atoms per protein shell at 25 and 50°C. Samples with mean particle sizes ranging from...  相似文献   
84.
A highly efficient frequency-controlled sound source based on a tunable high-Q underwater acoustic resonator is described. The required spectrum width was achieved by transmitting a linear frequency-modulated signal and simultaneously tuning the resonance frequency, keeping the sound source in resonance at the instantaneous frequency of the signal transmitted. Such sound sources have applications in ocean-acoustic tomography and deep-penetration seismic tomography. Mathematical analysis and numerical simulation show the Helmholtz resonator's ability for instant resonant frequency switching and quick adjustment of its resonant frequency to the instantaneous frequency signal. The concept of a quick frequency adjustment filter is considered. The discussion includes the simplest lumped resonant source as well as the complicated distributed system of a tunable organ pipe. A numerical model of the tunable organ pipe is shown to have a form similar to a transmission line segment. This provides a general form for the principal results, which can be applied to tunable resonators of a different physical nature. The numerical simulation shows that the "state-switched" concept also works in the high-Q tunable organ pipe, and the speed of frequency sweeping in a high-Q tunable organ pipe is analyzed. The simulation results were applied to a projector design for ocean-acoustic tomography.  相似文献   
85.
Effects of oxidation and surface roughness on contact angle   总被引:1,自引:0,他引:1  
Contact angle is known to be a parameter that effects boiling. This study was undertaken to measure contact angle of high and low surface tension fluids on copper and aluminum surfaces.Data were taken for polished, oxidized, and rough surfaces. A simple, yet fairly accurate method of measuring the static equilibrium contact angle of a solid/liquid interface is presented. The principles of a line light source and tilting plate were modified and then combined in the design of this apparatus. The angles obtained and their variation with the solid surface properties were in good agreement with previously published data. The contact angle of distilled water o of the organic fluids and refrigerants tested were in the range of 2–5°. Roughness and oxidation reduce the contact angle. If the depth of the roughness is less than 0.5 μm contact angle. The apparatus is fairly simple in construction, is inexpensive, and has good reproductibity. The measured angles were then compared to those measured with the sessile drop method.  相似文献   
86.
Active control of high Reynolds number and high-speed jets has been hampered due to the lack of suitable actuators. Some of the attributes that would make an actuator suitable for such flows are: high amplitude and bandwidth; small size for distribution around the jet; phase-locking ability for jet azimuthal mode forcing; and sufficient ruggedness for hot jets. We have been developing a class of actuators termed localized arc filament plasma actuators, which possess such characteristics. In this paper, we present the development and characterization of these actuators as well as preliminary results on their applications in high Reynolds number Mach 0.9 and ideally expanded Mach 1.3 jets.Patent pending  相似文献   
87.
A family of arylspiroborates has been prepared by the addition of either 4‐tert‐butylcatechol or 3,5‐di‐tert‐butylcatechol to boric acid and an alkali metal hydroxide. All compounds were characterized fully using multinuclear NMR spectroscopy and by elemental analyses. A single crystal X‐ray diffraction was carried out on potassium (bis‐(3,5‐di‐tertbutyl[1,2‐benzenediolato(2‐)‐O,O′]borate)) ( 8 ). All compounds displayed appreciable anti‐microbial activities.  相似文献   
88.
Means for effecting dipolar direct current collision-induced dissociation (DDC CID) on a quadrupole/time-of-flight in a mass spectrometer have been implemented for the broadband dissociation of a wide range of analyte ions. The DDC fragmentation method in electrodynamic storage and transmission devices provides a means for inducing fragmentation of ions over a large mass-to-charge range simultaneously. It can be effected within an ion storage step in a quadrupole collision cell that is operated as a linear ion trap or as ions are continuously transmitted through the collision cell. A DDC potential is applied across one pair of rods in the quadrupole collision cell of a QqTOF hybrid mass spectrometer to effect fragmentation. In this study, ions derived from a small drug molecule, a model peptide, a small protein, and an oligonucleotide were subjected to the DDC CID method in either an ion trapping or an ion transmission mode (or both). Several key experimental parameters that affect DDC CID results, such as time, voltage, low mass cutoff, and bath gas pressure, are illustrated with protonated leucine enkephalin. The DDC CID dissociation method gives a readily tunable, broadband tool for probing the primary structures of a wide range of analyte ions. The method provides an alternative to the narrow resonance conditions of conventional ion trap CID and it can access more extensive sequential fragmentation, depending upon conditions. The DDC CID approach constitutes a collision analog to infrared multiphoton dissociation (IRMPD).  相似文献   
89.
90.
We report the appearance of anomalous water diffusion in hydrophilic Sephadex gels observed using pulse field gradient (PFG) nuclear magnetic resonance (NMR). The NMR diffusion data was collected using a Varian 14.1 Tesla imaging system with a home-built RF saddle coil. A fractional order analysis of the data was used to characterize heterogeneity in the gels for the dynamics of water diffusion in this restricted environment. Several recent studies of anomalous diffusion have used the stretched exponential function to model the decay of the NMR signal, i.e., exp[-(bD)(α)], where D is the apparent diffusion constant, b is determined the experimental conditions (gradient pulse separation, durations and strength), and α is a measure of structural complexity. In this work, we consider a different case where the spatial Laplacian in the Bloch-Torrey equation is generalized to a fractional order model of diffusivity via a complexity parameter, β, a space constant, μ, and a diffusion coefficient, D. This treatment reverts to the classical result for the integer order case. The fractional order decay model was fit to the diffusion-weighted signal attenuation for a range of b-values (0 < b < 4,000 s-mm(-2)). Throughout this range of b values, the parameters β, μ and D, were found to correlate with the porosity and tortuosity of the gel structure.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号