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71.
Measure-free discrete time stochastic processes in Riesz spaces were formulated and studied by Kuo, Labuschagne and Watson. Aspects relating martingales, stopping times, convergence of these processes as well as various decomposition were considered. Here we formulate and study Markov processes in a measure-free Riesz space setting. 相似文献
72.
In calculating the director configuration in a liquid crystal device, two methods are commonly employed: a vector model and a tensor model. In this paper, we compare and contrast these methods for liquid crystal devices consisting of a layer of liquid crystal sandwiched between two plates. We compare the reliability and accuracy of the results, the speed of computation and the complexity of implementations of each method. 相似文献
73.
Harveen Kaur Amanda M. Heapy Renata Kowalczyk Zaid Amso Maureen Watson Jillian Cornish Margaret A. Brimble 《Tetrahedron》2014
The first synthesis and osteoblast proliferative activity of the naturally occurring cyclic peptides dianthins G and H is described. The greater potency of naturally occurring dianthin G over dianthin H at physiological concentrations mirrored the osteoblast proliferative activity observed for synthetic dianthins G and H. Six alanine-scan analogues of the more potent dianthin G were also synthesised and osteoblast assays revealed that four of the six residues can be further modified for improved activity. We also confirmed by variable temperature 1H NMR spectroscopic analysis that the sets of major and minor signals observed for dianthins G and H in DMSO-d6 are in fact due to cis–trans rotational isomers of the proline ring. 相似文献
74.
Aubert B Barate R Bona M Boutigny D Couderc F Karyotakis Y Lees JP Poireau V Tisserand V Zghiche A Grauges E Palano A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Battaglia M Brown DN Button-Shafer J Cahn RN Charles E Gill MS Groysman Y Jacobsen RG Kadyk JA Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Orimoto TJ Pripstein M Roe NA Ronan MT Wenzel WA del Amo Sanchez P Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE Watson AT Held T Koch H Lewandowski B 《Physical review letters》2007,98(5):051802
We present an observation of B-->eta'K*. The data sample corresponds to 232x10(6) BB[over ] pairs collected with the BABAR detector at the PEP-II asymmetric-energy B factory at the Stanford Linear Accelerator Center. We measure the branching fractions (in units of 10(-6)) B(B(0)-->eta'K*0)=3.8+/-1.1+/-0.5 and B(B+-->eta'K*+)=4.9(1.7)(+1.9)+/-0.8, where the first error is statistical and the second systematic. A simultaneous fit results in the observation of B-->eta'K* with B(B-->eta'K*)=4.1(-0.9)(+1.0)+/-0.5. We also search for B-->eta'rho and eta'f(0)(980)(f(0)-->pi+pi-) with results and 90% confidence level upper limits B(B+-->eta'rho+)=8.7(-2.8-1.3)(+3.1+2.3) (<14), B(B(0)-->eta'rho0)<3.7, and B(B(0)-->eta'f(0)(980)(f(0)-->pi+pi-))<1.5. Charge asymmetries in the channels with significant yields are consistent with zero. 相似文献
75.
Hun Lee Mataz Alcoutlabi Ozan Toprakci Guanjie Xu Jill V. Watson Xiangwu Zhang 《Journal of Solid State Electrochemistry》2014,18(9):2451-2458
Nanofiber-coated membrane separators were prepared by electrospinning polyvinylidene fluoride-co-chlorotrifluoroethylene (PVDF-co-CTFE) nanofibers onto three different microporous membrane substrates. The nanofibers on the membrane substrates showed uniform morphology with average fiber diameters ranging from 129 to 134 nm. Electrolyte uptakes, ionic conductivities, and interfacial resistances were studied by soaking the nanofiber-coated membrane separators with a liquid electrolyte solution of 1 M lithium hexafluorophosphate in ethylene carbonate/dimethylcarbonate/ethylmethyl carbonate (1:1:1 by volume). Compared with uncoated membranes, nanofiber-coated membranes had greater electrolyte uptakes and lower interfacial resistances to the lithium electrode. It was also found that after soaking in the liquid electrolyte solution, nanofiber-coated membranes exhibited higher ionic conductivities than uncoated membranes. In addition, lithium-ion half cells containing nanofiber-coated membranes were evaluated with a LiFePO4 cathode for charge–discharge capacities and cycle performance. The cells containing a nanofiber-coated separator membrane showed high discharge specific capacities and good cycling stability at room temperature. Results demonstrated that coating PVDF-co-CTFE nanofibers onto microporous membrane substrates is a promising approach to obtain new and high-performance separators for rechargeable lithium-ion batteries. 相似文献
76.
Jiang Wang Megan E. Hoerrner Mary P. Watson Daniel J. Weix 《Angewandte Chemie (International ed. in English)》2020,59(32):13484-13489
While ketones are among the most versatile functional groups, their synthesis remains reliant upon reactive and low‐abundance starting materials. In contrast, amide formation is the most‐used bond‐construction method in medicinal chemistry because the chemistry is reliable and draws upon large and diverse substrate pools. A new method for the synthesis of ketones is presented here that draws from the same substrates used for amide bond synthesis: amines and carboxylic acids. A nickel terpyridine catalyst couples N‐alkyl pyridinium salts with in situ formed carboxylic acid fluorides or 2‐pyridyl esters under reducing conditions (Mn metal). The reaction has a broad scope, as demonstrated by the synthesis of 35 different ketones bearing a wide variety of functional groups with an average yield of 60±16 %. This approach is capable of coupling diverse substrates, including pharmaceutical intermediates, to rapidly form complex ketones. 相似文献
77.
Naidong Ye Dan A. Smith J. Gregory Reid David R. Watson Pankaj Daga Stephen E. Gottschling 《合成通讯》2017,47(5):481-485
Incorporation of isotopes has long been used as a research tool to label carbons and elucidate biochemical pathways. More recently, H→D exchange has led to analogs of therapeutic agents with improved metabolic stability and properties. Such compounds also have the potential for an improved drug/drug interaction profile and may even avoid the formation of toxic metabolites. Hence, a clear need for an efficient access to deuterated intermediates on large scale has emerged. In the context of an ongoing drug discovery program, we required large quantities of morpholine-d8. We herein report the successful optimization of a one-pot process allowing a near complete exchange of all methylene hydrogens in morpholine to deuterium atoms using D2O as the sole source of deuterium and Raney Nickel as catalyst. This facile and safe protocol will be used to scale up the synthesis of morpholine-d8 in due course. 相似文献
78.
T. F. Watson D. Belić P. Y. Convers E. J. Boyd S. A. Brown 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2011,61(1):81-85
Thin films produced by depositing tin clusters with sizes between 5 and 10 nm onto silicon nitride substrates were found to
be
highly coalesced resulting in grains with sizes ~30 nm. Exposing the clusters to nitrogen before they were deposited significantly
reduced the coalescence between them and resulted in granular films where the clusters mostly retained their shape. This is
due to a small
amount of tin nitride forming in the clusters. The coalesced and granular films were used to fabricate tin oxide gas sensors.
This was
done by depositing the two types of films onto silicon nitride chips and then oxidising them by baking at 250 °C for 24 h.
It was found that the sensors composed of uncoalesced clusters were much more sensitive to hydrogen. This was attributed to
the smaller grain size and the larger surface area of the granular films. 相似文献
79.
80.
Katherine D. Watson 《Ambix》2017,64(1):104-105