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41.
P. Villemoes A. Wännström A. Arnesen R. Hallin F. Heijkenskjöld A. Kastberg C. Nordling O. Vogel 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,18(3):235-238
We report the first measurements of the hyperfine splitting of the fine structure levels 3d 5'4s a 5 S 2 and 3d 5 4p z 5 P 1,2,3 0 in singly ionised manganese in a collinear fast ion beam-laser experiment. The ions are excited by the intracavity frequency doubled output of a ring dye laser. The observed linewidth is sufficiently narrow to identify all hyperfine components of each fine structure level. 相似文献
42.
Vogel R Meredith P Harvey MD Rubinsztein-Dunlop H 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(1-2):245-249
A comparison has been made between the spectroscopic properties of the laser dye rhodamine 6G (R6G) in mesostructured titanium dioxide (TiO(2)) and in ethanol. Steady-state excitation and emission techniques have been used to probe the dye-matrix interactions. We show that the TiO(2)-nanocomposite studied is a good host for R6G, as it allows high dye concentrations, while keeping dye molecules isolated, and preventing aggregation. Our findings have important implications in the context of solid state dye-lasers and microphotonic device applications. 相似文献
43.
The face selectivity (endo-face vs. exo-face attack onto the exocyclic s-cis-butadiene moiety) of the [4+2]cycloadditions of 5,6-bis((D)methylidene)-2-bicyclo-[2.2.2]octene ( 11 ) to strong dienophiles has been determined in benzene at 25°. It is ca. 95/5, 75/5, 70/30, 60/40 and 50/50 for N-phenyltriazolinedione (NPTAD), tetracyanoethylene (TCE), dimethyl acetylenedicarboxylate (DMAD), maleic anhydride (MA) and singlet oxygen (1O2), respectively. The endo-face preference is probably due to a participation of the homoconjugated double bond at C(2), C(3) which makes the etheno bridge more polarizable than the ethano bridge in 11. The absence of face selectivity with 1O2 is consistent with an entropy-controlled mechanism involving the intermediacy of an exciplex. 相似文献
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Summary In a simply connected planar domainD the expected lifetime of conditioned Brownian motion may be viewed as a function on the set of hyperbolic geodesics for the domain. We show that each hyperbolic geodesic induces a decomposition ofD into disjoint subregions
and that the subregions are obtained in a natural way using Euclidean geometric quantities relating toD. The lifetime associated with on each
j
is then shown to be bounded by the product of the diameter of the smallest ball containing
j
and the diameter of the largest ball in
j
. Because this quantity is never larger than, and in general is much smaller than, the area of the largest ball in
j
it leads to finite lifetime estimates in a variety of domains of infinite area.Research of the first author was supported in part by NSF Grant DMS-9100811Research of the second author was supported in part by NSF Grant DMS-9105407 相似文献
49.
Nitrobenzoxadiazole (NBD) derivatives are determined with limits of detection ranging down to 20 nmol l(-1) using liquid chromatography-mass spectrometry (LC-MS) with electron capture (EC) ionisation. An atmospheric pressure chemical ionisation (APCI) interface operated in the negative ion mode is used as ionisation source. Amine derivatives of 4-chloro-7-nitro-2,1,3-benzoxadiazole (NBDCl) as well as the isocyanate derivatives of 4-nitro-7-piperazino-2,1,3-nitrobenzoxadiazole (NBDPZ) have been analysed using this technique. The parameters favouring electron capture mechanisms have been investigated thoroughly under consideration of the competing mechanism of deprotonation to allow a better understanding of the electron capture process and to improve selectivity of the analysis. 相似文献
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