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51.
A method for the determination of total selenium in wheat and wheat flour using graphite furnace atomic absorption spectrometry (GFAAS) with palladium/ascorbic acid as a chemical modifier was studied. The effects of nickel nitrate, palladium/ascorbic acid, and palladium/magnesium nitrate as chemical modifiers on the sensitivity in the determination of selenite, selenate and selenomethionine by GFAAS were compared. The palladium/ascorbic acid modifier was used for the determination of total selenium in wheat and wheat flour, because the oxidation states of the selenium ion are not important in the determination. The detection limit was estimated to be 1 microg L(-1) (calculated as 3sigma of the blank); the calibration curve was linear for the concentration range 5 - 50 microg L(-1) and the recovery range was 96.66 - 101.80%. The optimal ashing and atomizing temperatures were 1300 degrees C and 2250 degrees C, respectively. The proposed method was successfully applied to the determination of total selenium in wheat and wheat flour. 相似文献
52.
53.
Nicusor Fifere Anton Airinei Constantin Gaina Viorica Gaina Mircea Grigoras 《Journal of fluorescence》2014,24(2):345-353
A fluorophore-photochrome system incorporating an aryleneimine type fluorophore and an azobismaleimide photochrome was developed and the photochemical properties of this system were investigated. The photoisomerization of trans-azoaromatic chromophore leads to the increase of the fluorescence intensity of fluorophore. The cis azobismaleimide isomers revert photochemically to the trans form and the emission intensity decreases. The fluorescence intensity of the imine fluorophore can be modulated under irradiation with UV and visible (436 nm) light due to reversible trans-cis-trans photoisomerization of azobismaleimide partner. The photoisomerization kinetics was obeyed a first-order relationship with a rate constant of 1.95?×?10?2 s?1 for azobismaleimide/imine fluorophore system and for polyazothioetherimide/imine derivative the kinetics was described by a biexponential equation. 相似文献
54.
55.
H. L. Luo Viorica Spânu Guan-mian Chen S. Y. Dai X. C. Huang G. Filoti 《Hyperfine Interactions》1990,54(1-4):599-602
The 0.05 (wt%) Co-coated hematite having cigar-shaped particles was investigated by means of Mössbauer effect at temperatures between 77 K and 300 K by ascending and descending temperatures, respectively. The Mössbauer spectra indicated the coexistence of two distinct magnetic phases below 223 K or 232 K, depending on the starting point. The angle between the spin direction and the crystallographic trigonal axis was calculated taking into account the quadrupole splitting values. 相似文献
56.
S. P. Feofilov A. A. Kaplyanskii A. B. Kulinkin R. S. Meltzer T. N. Vasilevskaya 《Journal of luminescence》2002,100(1-4):155-161
We report optical studies of the new material – Cr3+-doped lithium–germanate glass, containing Li2Ge7O15 (LGO) nanocrystalline particles. While only broadband 4T2–4A2 fluorescence from the low-field octahedral Cr3+ sites was observed from Cr3+ ions in the glass, in LGO nanocrystals high-field Cr3+ centers emit 2E–4A2 (R–lines) fluorescence. The process of crystallization in the course of isothermal annealing of glasses was monitored spectroscopically and the nucleation of LGO crystallites was observed starting from the smallest clusters. Using the 2E–4A2 fluorescence spectra it is possible to detect the ferroelectric phase transition in LGO:Cr3+ nanocrystals, whose critical temperature was found to be similar to that of the bulk crystals. Long-lived spectral holes were burned in the inhomogeneously broadened R-lines of Cr3+ in LGO nanocrystals at low temperatures. The linear temperature dependence of hole widths shows that the homogeneous broadening of 4A2–2E transitions of Cr3+ in nanocrystals is due to interaction of Cr3+ electronic levels with the two-level systems (TLS) of the surrounding glass. The range of the Cr3+-TLS elastic dipole–dipole interaction is estimated. 相似文献
57.
58.
Lucica Viorica Ababei Angela Kriza Cristian Andronescu Adina Magdalena Musuc 《Journal of Thermal Analysis and Calorimetry》2012,107(2):573-584
Ten new mononuclear complexes having general formulae [ML2](ClO4)2, M = Cu(II), Co(II), Ni(II), Mn(II) and Zn(II), [ML2](SO4), M = Co(II), Ni(II) and [ML2(H2O)2](SO4), M = Cu(II), Mn(II) and Zn(II), L = 2-acetyl-pyridyl-isonicotinoylhydrazone have been synthesized and characterized based
on elemental analyses, IR spectroscopy, UV–Vis–NIR, EPR, as well as thermal analysis and determination of molar conductivity
and magnetic moments. The structures of [CoL2](ClO4)2 are accomplished by single crystal X-ray diffraction. The coordination sphere is formed by two N, N, O tridentates 2-acetyl-pyridyl-isonicotinoylhydrazone
ligands, or by two N, O bidentate 2-acetyl-pyridyl-isonicotinoylhydrazone and two water molecules. Biological activity studies
reveal a moderate activity of complexes against gram-negative and gram-positive bacteria. 相似文献
59.
G. I. Rusu A. Airinei Viorica Hamciuc G. G. Rusu Petronela Râmbu Mihaela Diciu 《Journal of Macromolecular Science: Physics》2013,52(2):238-253
Polysulfone (PSF)-polydimethylsiloxane (PDMS) block copolymers (PSF-b-PDMS) with various compositions were prepared by condensing chloro-terminated polysulfone oligomers with α, ω -dihydrogensilyl-polydimethylsiloxane in refluxing chlorobenzene solution in the presence of urea as a hydrogen chloride acceptor. The temperature dependences of the electrical conductivity and thermoelectric power (Seebeck coefficient) of copolymers were studied using thin films deposited from a dimethylformamide solution (spin coating method) onto glass substrates. It was established that the various copolymers showed typical semiconducting properties. Some correlations between these properties (activation energy, ratio of carrier mobilities, etc) and molecular structure of the copolymers were found. A model based on band gap representation was found to be suitable for explanation of the electronic transport mechanism through the studied copolymers in thin films. The study of the transmission and absorption spectra (in the spectral range from 300 nm to 1400 nm) evidenced that the indirect allowed optical transitions were predominant. The values of the optical energy band gap (ranged between 1.50 eV and 1.70 eV) are in agreement with values of width of the forbidden band calculated from the temperature dependence of the electrical conductivity. 相似文献
60.
A new monomer bearing N-trityl-l-serine methyl ester in structure, methacryloyloxyethyl carbamoyloxy–N-trityl methyl serine (MTS), was prepared to be further polymerized by atom transfer radical polymerization (ATRP) with pyrene-endcapped poly(methyl methacrylate) (Py–PMMA–Br) or poly(N-isopropylacrylamide) (Py–PNIPA–Br). The resulting block copolymers, poly(methyl methacrylate–block–methacryloyloxyethyl carbamoyloxy–N-trityl methyl serine) (Py–PMMA–b–PMTS) and poly(N-isopropylacrylamide–block–methacryloyloxyethyl carbamoyloxy–N-trityl methyl serine (Py–PNIPA–b–PMTS) were characterized by 1H (13C) NMR, ultraviolet, FTIR and fluorescence spectroscopy, thermal analysis, differential scanning calorimetry (DSC), atomic force microscopy (AFM), scanning electron microscopy (SEM), and gel permeation chromatography (GPC) measurements. The chemical composition in Py–PMMA–b–PMTS was estimated from the 1H NMR analysis that indicated a ratio of the repeating units of 46:19 (MMA:MTS). For the Py–PNIPA–b–PMTS the composition rate in the copolymer was 61:25 (NIPA:MTS). Quenching of the pyrene species with N,N-diethylaniline, nitrobenzene, nitrophenol, potassium iodide, p-nitrotoluene and tetracyanoquinodimethane (TCNQ) in DMF solution excited at 348 nm was evidenced, more efficiently being nitrophenol and TCNQ. In this case, the monomer emission at 388–409 nm underwent a significant decrease caused of an electron transfer from the electron-reach photoexcited pyrene molecule to the electron-deficient quenchers. 相似文献