Collapse of square and rectangular tubes in transverse loading

Summary Analysis of the in plane lateral collapse of square and rectangular cross-section tubes is presented by considering the out-of-straightness of horizontal and vertical arms, corner radius, friction between the platens and the deforming specimen and instability of vertical arms. Results of collapse load for tubes of aluminium and mild steel, thus computed, are presented for some typical tube geometrics, and influence thereon of various parameters considered is discussed. Experiments were conducted wherein tubes of square and rectangular cross-sections of both the materials were laterally compressed between two parallel platens in an Instron machine. The observed collapse loads compare very well with the corresponding computed values.

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Kollaps von vertikal belasteten Rohren mit quadratischem und rechteckigem Querschmitt

Übersicht Der Kollaps von Rohren mit quadratischem und rechteckigem Querschnitt, welche senkrecht zur Achse belastet werden, wird untersucht, wobei schiefe Vertikal- und Horizontalstege, gerundete Profilecken, Reibung zwischen Belastungsplatten und Rohr sowie die Stabilität der Vertikalstege brücksichtigt werden. Die Kollapslast wird für Aluminium und Weichstahl und einige typische Rohrgeometrien ermittelt und der Einfluß verschiedener Parameter wird untersucht. Die Experimente wurden auf einer Instron-Maschine durchgeführt, wobei Rohre mit quadratischem und rechteckigem Querschnitt aus beiden Werkstoffen zwischen zwei parallelen Platten quer zur Achse komprimiert wurden. Es konnte eine gute Übereinstimmung zwischen den Resultaten aus Experiment und Rechnung festgestellt werden.

     

Kinetics and mechanism of the oxidation of acetaldehyde by chromic acid in perchloric acid

Summary The oxidation of MeCHO by chromium(VI) has been studied in HClO₄ medium over a wide range of experimental conditions and has been found to obey the rate law;v=k[MeCHO][HCrO ₄ ^– ][H⁺]. The calculated H and-S values for the reaction are 30±2kJ mol^–1 and 171±7J mol^–1deg^–1, respectively. The mechanism is discussed in terms of carbon-hydrogen bond cleavage.     

Chromatographic separation of some metal ions on NTA-impregnated thin-layer plates

Summary NTA (nitrilo triacetic acid) has been used as an impregnating agent for an efficient TLC separation of twelve metal ions, using a mixture of 5% aq ammonia, ethanol acetone and acetic acid as the solvent system and dithizone (0.5% in chloroform) for visualization.     

Enzymatic polymerizations using surfactant microstructures and the preparation of polymer-ferrite composites

Applied Biochemistry and Biotechnology - Horseradish peroxidase has been used as a biocatalyst to synthesize a polymeric material from alkyl-substituted phenols. The synthesis is carried out in a...