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排序方式: 共有350条查询结果,搜索用时 312 毫秒
91.
Dennis Chicoma Verónica Carranza Claudia Sayer Reinaldo Giudici 《Macromolecular Symposia》2010,289(1):140-148
Summary: This work deals with the in line and in situ monitoring of the changes in residual monomer concentrations and polymer particle size in the process of emulsion copolymerization of vinyl acetate (VAc) and butyl acrylate (BuA) over the sections of a novel tubular reactor (pulsed sieve plate continuous reactor, PSPC) using NIR spectroscopy. Off-line measurements (gas chromatographic, gravimetric and dynamic light scattering) were used as reference for the development of the multivariate PLS calibration model. All NIR spectra were on-line collected with an IFS 28/N Bruker spectrometer using a probe (transflectance mode) immersed into the reaction medium. The calibration model and validation data were analyzed using the OPUS/QUANT software. The results indicated that there exists a good agreement between values from the NIR calibration models and the off-line reference measured experimental data. Moreover, the on-line NIR can detect efficiently the occurrence of disturbances during the polymerization reaction, a useful tool for the improving the process safety. 相似文献
92.
Moreno D Palopoli C Daier V Shova S Vendier L Sierra MG Tuchagues JP Signorella S 《Dalton transactions (Cambridge, England : 2003)》2006,(43):5156-5166
The diMn(III) complexes [Mn2(5-Me-salpentO)(mu-MeO)(mu-AcO)(H2O)Br] (1) and [Mn2(3-Me-salpentO)(mu-MeO)(mu-AcO)(MeOH)2]Br (2), where salpentOH = 1,5-bis(salicylidenamino)pentan-3-ol, were synthesised and structurally characterized. The two complexes include a bis(micro-alkoxo)(micro-acetato) triply-bridged diMn(III) core with an Mn...Mn separation of 2.93-2.94 A, the structure of which is retained upon dissolution. Complexes 1 and 2 show catalytic activity toward disproportionation of H2O2, with first-order dependence on the catalyst, and saturation kinetics on [H2O2], in methanol and DMF. In DMF, the two complexes are able to disproportionate at least 1500 eq. of H2O2 without significant decomposition, while in methanol, they rapidly lose activity with formation of a non-coupled Mn(II) species. Electrospray ionisation mass spectrometry, EPR and UV/vis spectroscopy used to monitor the reaction suggest that the major active form of the catalyst occurs in the Mn2(III) oxidation state during cycling. The correlation between log(k(cat)) and the redox potentials of 1, 2 and analogous complexes of other X-salpentOH derivatives indicates that, in this series, the oxidation of the catalyst is probably the rate-limiting step in the catalytic cycle. It is also noted that formation of the catalyst-peroxide adduct is more sensitive to steric effects in DMF than in methanol. Overall, kinetics and spectroscopic studies of H2O2 dismutation by these complexes converge at a catalytic cycle that involves the Mn2(III) and Mn2(IV) oxidation states. 相似文献
93.
Alfonso Carriazo Verónica Martín-Molina Luc Vrancken 《Annals of Global Analysis and Geometry》2018,54(2):173-185
We present classifications of totally geodesic and totally umbilical Legendrian submanifolds of \((\kappa ,\mu )\)-spaces with Boeckx invariant \(I \le -1\). In particular, we prove that such submanifolds must be, up to local isometries, among the examples that we explicitly construct. 相似文献
94.
Verónica A. Jiménez 《Structural chemistry》2009,20(4):677-684
Computational calculations at B3LYP/6-311++G(d,p) and MP2/6-311++G(d,p) levels were employed to analyze the structure and
conformation of 1,3-bis(4-bromophenyl)azulene (1), 1,3-bis(2-thienyl)azulene (2), and 1,3-bis(2-pyrrollyl)azulene (3) in order to rationalize the out-of-plane deformation found in the azulene cores of 1 and 2 in the crystalline state, whereas compound 3 shows a totally planar azulene moiety. Our results indicate that 1,3-disubstituted azulenes possess two almost equally stable
and easily convertible minimum energy conformers, which differ in the relative orientation of the substituent groups and in
the planarity degree of the azulene core. An absolute planarity index (P) is introduced to quantify the out-of-plane distortion found in the azulenes under study. The aromaticity of minimum energy
conformers was evaluated by means of geometric (HOMA), magnetic (NICS), and energetic (the frequency of the lowest out-of-plane
vibration, νmin) aromaticity indicators, which suggest that compound 3 possesses the most aromatic azulene core within the group. Calculated molecular dipole moments suggest that the conformation
of 1,3-disubstituted azulenes in the crystalline state can be explained in terms of electrostatic intermolecular interactions
rather than relative stability of planar and non-planar conformers. 相似文献
95.
Bojan Verček Božidar Ogorevc Branko Stanovnik Miha Tišler 《Monatshefte für Chemie / Chemical Monthly》1983,114(6-7):789-798
Transformations of some heterocyclic cyanoamino compounds leading to various heterocyclic systems are described.s-Triazolo (1,5-α)azines are obtained either in a direct synthetic approach or via the substituted aminotetrazoles, substituted 3-amino-5-oxo-1,2,4-oxadiazolines, and fromN-ethoxycarbonylN′-heteroaryl thioureas orN-heteroarylN′-hydroxyguanidine. The cyanoamino group reacts also witho-difunctional benzenes to give the corresponding substituted derivatives of benzimidazole, benzoxazole or benzothiazole. 相似文献
96.
J. T. Gerard C. C. Swanson L. J. Ver Weire J. L. Pietruszewski 《Journal of Radioanalytical and Nuclear Chemistry》1979,54(1-2):59-68
A nondestructive neutron activation technique for the simultaneous direct determination of chlorine, bromine, and iodine in
silver halide mixtures is described using a252Cf neutron multiplier (CFX). About 5–50 mg of sample are used. The analysis is semiroutine, without the need for a monitor
included with each sample since the flux stability and reproducibility are within ±1%, decaying only with the 2.65 year half-life
of252Cf. The precision and accuracy are counting-statistics controlled and are generally ±1% RSD or better. The method offers an
attractive alternative to existing chemical and instrumental methods for these determinations in silver halide mixtures because
it has the potential for providing reasonably rapid analyses with good precision and accuracy. 相似文献
97.
Brázdová V Ganduglia-Pirovano MV Sauer J 《The journal of physical chemistry. B》2005,109(49):23532-23542
The structure, stability, and vibrational properties of isolated V2O5 clusters on the Al2O3(0001) surface have been studied by density functional theory and statistical thermodynamics. The most stable structure does not possess vanadyl oxygen atoms. The positions of the oxygen atoms are in registry with those of the alumina support, and both vanadium atoms occupy octahedral sites. Another structure with one vanadyl oxygen atom is only 0.12 eV less stable. Infrared spectra are calculated for the two structures. The highest frequency at 922 cm(-1) belongs to a V-O stretch in the V-O-Al interface bonds, which supports the assignment of such a mode to the band observed around 941 cm(-1) for vanadia particles on alumina. Removal of a bridging oxygen atom from the most stable cluster at the V-O-Al interface bond costs 2.79 eV. Removal of a (vanadyl) oxygen atom from a thin vanadia film on alpha-Al2O3 costs 1.3 eV more, but removal from a V2O5(001) single-crystal surface costs 0.9 eV less. Similar to the V2O5(001) surface, the facile reduction is due to substantial structure relaxations that involve formation of an additional V-O-V bond and yield a pair of V(IV)(d1) sites instead of a V(III)(d2)/V(V)(d0) pair. 相似文献
98.
We have studied the interaction of atomic hydrogen with (5,5) and (10,0) single-walled carbon nanotubes (SWNT) using density functional theory. These calculations use Gaussian orbitals and periodic boundary conditions. We compare results from the local spin density approximation, generalized gradient approximation (GGA), and hybrid density functionals. We have first kept the SWNT geometric structure fixed while a single H atom approaches the tube on top of a carbon atom. In that case, a weakly bound state with binding energies from -0.8 to -0.4 eV was found. Full geometry relaxation leads to a strong SWNT deformation, weakening the nearest C-C bonds and increasing the binding energy by about 1 eV. Full hydrogen coverage of the (5,5) SWNT converts this metallic nanotube into an insulator with a band gap of 3.4 eV for the GGA functional and 4.8 eV for the hybrid functional. Hybrid functionals perform similar to pure density functional theory functionals for the calculation of binding energies while band gaps critically depend on the functional choice. 相似文献
99.
100.
Gonzalez VD Gugliotta LM Vega JR Meira GR 《Journal of colloid and interface science》2005,285(2):581-589
Multiangle dynamic light scattering (MDLS) and turbidimetry (T) were applied (both individually and combined) for determining the contamination by larger particles of two almost-uniform polystyrene (PS) latices. Latex 1 was synthesized in our laboratories, and it contained a main population diameter of 340 nm together with a small fraction of larger particles. This latex was used as the base material for producing an immunoassay kit. Latex 2 was obtained by a simple blend of two uniform PS standards. The proposed data treatment calculates the diameter and number fraction of the large particles contamination assuming that the PSDs are bimodal. The calculation involves minimizing the errors between the measurements and their theoretical predictions. When analyzed by combined MDLS-T, the contamination of Latex 1 involved number fraction 0.6% and particle diameter 865 nm. The T average diameter is a function of the measurement wavelength, and the highest deviations of this average to an increasing contamination by large particles were always observed at the higher wavelengths. The DLS average diameter is a function of the measurement angle, but in this case it is impossible to determine a priori the angle of observation that provides the largest deviation of this average diameter to an increasing contamination. 相似文献