全文获取类型
收费全文 | 1160篇 |
免费 | 29篇 |
国内免费 | 2篇 |
专业分类
化学 | 781篇 |
晶体学 | 3篇 |
力学 | 38篇 |
数学 | 165篇 |
物理学 | 204篇 |
出版年
2023年 | 8篇 |
2022年 | 15篇 |
2021年 | 41篇 |
2020年 | 26篇 |
2019年 | 38篇 |
2018年 | 21篇 |
2017年 | 26篇 |
2016年 | 51篇 |
2015年 | 38篇 |
2014年 | 44篇 |
2013年 | 96篇 |
2012年 | 87篇 |
2011年 | 92篇 |
2010年 | 62篇 |
2009年 | 63篇 |
2008年 | 73篇 |
2007年 | 79篇 |
2006年 | 44篇 |
2005年 | 34篇 |
2004年 | 35篇 |
2003年 | 27篇 |
2002年 | 28篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 12篇 |
1998年 | 6篇 |
1997年 | 11篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 10篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1981年 | 3篇 |
1979年 | 5篇 |
1976年 | 7篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1972年 | 6篇 |
1971年 | 6篇 |
1970年 | 2篇 |
1962年 | 2篇 |
排序方式: 共有1191条查询结果,搜索用时 718 毫秒
31.
A test is described for identification and differentiation of n-propyl and isopropyl halides. The halide is reacted with triphenylphosphine to form the phosphoniun salt, and thiocyanate and copper or cobalt solutions are added, Extraction of the colored precipitate into a suitable solvent indicates n-propyl halide whereas isopropyl halides yield unextractable products. The test is applicable to solutions of each halide in the corresponding alcohol as well as to mixtures of both halides. 相似文献
32.
Valderi L Dressler Dirce PozebonÉder L.M Flores José N.G PanizÉrico M.M Flores 《Analytica chimica acta》2002,466(1):117-123
A method for the determination of fluoride in coal, coal fly ash, phosphate rock, limestone, mineral clay, fossilised materials, oyster tissue and vegetation using pyrohydrolysis for sample decomposition is proposed. A specific apparatus was constructed and the influence of vanadium pentoxide (V2O5) as a catalyst for the pyrohydrolysis reaction was investigated. It was verified that V2O5 does not influence the release of fluoride from the vegetation, oyster tissue, coal and coal fly ash matrices analysed. However, the catalyst was necessary for the phosphate rock, fossil bone, mineral clay and limestone samples. Certified and noncertified samples were analysed using an ion selective electrode (ISE) for the analyte detection. Precise (relative standard deviation—R.S.D.<7%) and accurate (recovery in accordance to certified values) results were obtained. The limit of quantification (LOQ) of the method was 5.0 μg g−1 of fluoride using 20 mg of sample and a final dilution to 10 ml. The sample frequency was five samples per hour. 相似文献
33.
Luiz A. F. Coelho Jos V. Oliveira Saul G. D'vila Janete H. Y. Vilegas Fernando M. Lanas 《Journal of separation science》1997,20(8):431-436
The effects of temperature and solvent density on the characteristics of the extracts obtained from supercritical fluid extraction (SFE) of the volatile compounds from Brazilian rosemary (Rosamarinus officianalis L., Labiatae) using carbon dioxide (CO2) as solvent were investigated. The experiments were performed in a semi-batch laboratory scale home-made unit at two temperatures, viz. 310.15 and 320.15 K, over the pressure range of 100-160 bar. This study allowed to determine the crossover point and the maximum solubility of the oil. The products were analyzed by HRGC-MS, and compounds grouped in three different classes according to their molecular mass distribution in order to evaluate the influence of the variables studied on the characteristics of the extracts. The model proposed by Sovová was adopted in an attempt to interpret the mass transfer phenomena in the extraction process. 相似文献
34.
Cristiane P. de Macedo Charles A. B. Negrão Luiz G. M. de Macedo José R. Zamian Geraldo N. da Rocha Filho Carlos E. F. da Costa 《Journal of Thermal Analysis and Calorimetry》2014,115(1):31-36
The Al-MCM-41 molecular sieve with Si/Al = 20 molar ratio was synthesized at room temperature and characterized by X-ray diffractometry, surface area, thermogravimetry, and infrared spectroscopy. The kinetic study was conducted by Vyazovkin and Ozawa method, in order to verify the activation energy during the Hofmann degradation between 130 and 370 °C, in which most of surfactant removal occurs. The results suggest that the activation energy for template removal is close to 80 kJ mol?1 lower in Al-MCM-41 synthesized at room temperature, when compared to results obtained for mesopores Al-MCM-41 and MCM-41 synthesized by hydrothermal method. This lower activation energy may be understood as consequence of textural properties, such as higher pore size. 相似文献
35.
Luiz Carlos Domingos Batista Thiago Izidoro Silva Santos José E. Lima Santos Djalma Ribeiro da Silva Carlos A. Martínez-Huitle 《Electroanalysis》2021,33(1):57-65
MOF-235 is presented as an orange powder, with crystals of the octahedral formation. It was already used as adsorbent to remove different compounds from water; however, no attempts have been published about the exploration of the MOF-235 application as electrochemical sensor for organic compounds yet. MOF-235 was synthetized and after that, it was characterized by SEM, XRD and FTIR. Graphite electrodes (GEs) were modified with different MOF-235 ratio (5 %, 7 %, 10 %, 12 % and 14 %) and these modified GEs were characterized by cyclic voltammetry (CV) measurements in order to determine the effect of MOF-235 concentration on the current response. Results indicated that, a significant improvement on the current response was attained at MOF-235(10 %)/GE respect to unmodified GE. This behavior is related to the pore structure and multiple active sites on the MOF surface. The performance of the MOF-235(10 %)/GE as electrochemical sensor for detecting catechol was assessed by differential pulse voltammetry (DPV). Catechol detection response of MOF-based sensor provided a detection limit of about 12.79 μmol L−1 with a correlation coefficient (R2) of about 0.9928 ranging from 12 to 514 μmol L−1. Finally, MOF-235(10 %)/GE was used to determine catechol in real water matrixes. 相似文献
36.
37.
38.
39.
We study the semiparametric estimation of stochastic differential equations employing methods based on moment conditions, comparing the finite sample and robustness properties of generalized method of moments, empirical likelihood and minimum contrast methods using unconditional and conditional formulations of moment conditions. The results obtained indicate that the estimators proposed, particularly, the estimators based on exponential tilting, obtain better results than those of the generalized methods of moments normally used to estimate stochastic differential equations. This conclusion is mainly derived from the robustness properties of this method in the presence of problems of incorrect specification. 相似文献
40.
One of the key parameters in modeling capital budgeting decisions for investments with embedded options is the project volatility. Most often, however, there is no market or historical data available to provide an accurate estimate for this parameter. A common approach to estimating the project volatility in such instances is to use a Monte Carlo simulation where one or more sources of uncertainty are consolidated into a single stochastic process for the project cash flows, from which the volatility parameter can be determined. Nonetheless, the simulation estimation method originally suggested for this purpose systematically overstates the project volatility, which can result in incorrect option values and non-optimal investment decisions. Examples that illustrate this issue numerically have appeared in several recent papers, along with revised estimation methods that address this problem. In this article, we extend that work by showing analytically the source of the overestimation bias and the adjustment necessary to remove it. We then generalize this development for the cases of levered cash flows and non-constant volatility. In each case, we use an example problem to show how a revised estimation methodology can be applied. 相似文献