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91.
92.
Zusammenfassung Es wird die Struktur der beiden möglichen isomeren Bis-(p-nitrobenzolazo)-resorcinverbindungen1 und4 mittels gezielter Azokupplung geeigneter Modellsubstanzen und durch NMR-spektroskopische Messungen festgelegt.
The structures of the two possible isomeric bis(p-nitrophenylazo)-resorcinol derivatives1 and4 have been determined by diazo coupling of suitable model compounds and by n.m.r. spectroscopic studies.相似文献
93.
The diastereoselective synthesis of ornithine lactams 6-9 via photoinduced -hydrogen abstraction followed by cyclization of the corresponding 1,6-biradicals is described. A highly asymmetric 1,4-induction is observed. 相似文献
94.
95.
Schweiggert U Kammerer DR Carle R Schieber A 《Rapid communications in mass spectrometry : RCM》2005,19(18):2617-2628
Carotenoids and carotenoid esters were extracted from red pepper pods (Capsicum annuum L.) without saponification. Among the 42 compounds detected, 4 non-esterified, 11 mono- and 17 diesters were characterized based on their retention times, UV/Vis spectra and their fragmentation patterns in collision-induced dissociation experiments in atmospheric pressure chemical ionization mass spectrometry (APCI-MS). Positive and negative ion mode measurements were used for the characterization of major and minor carotenoids and their esters. Capsanthin esterified with lauric, palmitic and myristic acids represented the predominant compounds in the red pepper extracts. Additionally, three beta-cryptoxanthin and one zeaxanthin monoester were tentatively identified in red pepper pods for the first time. Furthermore, the specific fragmentation patterns of capsanthin-laurate-myristate and capsanthin-myristate-palmitate were used for the distinction of both regioisomers. The results obtained from LC-DAD-APCI-MSn experiments demonstrated that the carotenoid profile of red pepper pods is considerably more complex than considered hitherto. 相似文献
96.
A previously investigated model of a two band superconductor with hybrid pairing and molecular fields is enlarged by exchange interactions generating those fields. The fields are calculated selfconsistently in molecular field approximation at zero temperature. They turn out to stabilise the previously found new state of gapless superconductivity and non vanishing spin polarization for a wide range of exchange couplings, in particular for zero external field.Dedicated to B. Mühlschlegel on the occasion of his 60th birthdayWork performed within the research program of Sonderforschungsbereich 125 Aachen-Jülich-Köln 相似文献
97.
98.
Wienkoop S Larrainzar E Niemann M Gonzalez EM Lehmann U Weckwerth W 《Journal of separation science》2006,29(18):2793-2801
Mass spectrometry (MS) has become a powerful tool for the quantitative analysis of complex protein samples. A high-throughput strategy for the comparative analysis of multiple protein samples with high complexity becomes more and more important. Two strategies, spectral count and peak intensity, for label-free MS analysis of prefractionated complex mixtures have been described recently to be useful for quantitation. Here we compare both strategies for rapid and quantitative 1-D shotgun LC/MS/MS analyses of highly complex protein mixtures using silica-based monolithic columns. First, we validated linearity and sensitivity of these methods by spiking varying amounts of an internal standard protein in a complex plant protein extract. Secondly, quantitative data of proteins of Medicago truncatula nodules were visualized with independent components analysis using data either obtained from spectral count or peak integration performed with commercial software. Spectral count showed apparent advantages over peak integration because several peptides per protein are automatically averaged, the linear dynamic range of quantitation increases in complex matrices and the number of quantified proteins surpasses the number of proteins using peak integration. Thus, for the need of rapid comparative analysis of highly complex protein samples, spectral count enables sample pattern recognition and identification of biomarkers in nongel based proteomic studies. 相似文献
99.
Homogeneous hydrogenations of unsaturated substrates with parahydrogen yield strong NMR signal enhancements of the transferred 1H nuclei if the symmetry of H2 is broken in the resulting hydrogenated products. This chemically induced hyperpolarization known as Parahydrogen-induced polarization (PHIP) is also transferred to other protons and heteronuclei (2H, 13C, 29Si, 31P) when the hydrogenation is initiated at low magnetic fields. Hydrogenating various fluorinated styrenes and phenylacetylenes, we show that PHIP-derived hyperpolarization is transferred to 19F not only in the Earth's magnetic field (ALTADENA condition) but also in a strong magnetic field, e.g., when carrying out the reaction in the NMR spectrometer (PASADENA condition). Upon conducting a systematic analysis of the observed PHIP transfer to 1H, 13C, and 19F in the hydrogenation products to elucidate the mechanisms that govern this parahydrogen-aided resonance transfer (PART), we conclude that high- and low-field PHIP transfer mechanisms differ in detail depending on either through-bond or through-space interactions. Substrates with high hydrogenation rates and long spin-lattice relaxation times (T1) yield the highest degree of heteronuclear hyperpolarization. Possible medical applications for hyperpolarized 19F-containing molecules as "active" contrast agents for magnetic resonance imaging (MRI) are outlined. 相似文献
100.
A water-soluble hexa-peri-hexabenzocoronene was prepared and shown to undergo ordered columnar self-assembly either in water solution or bulk and therefore served as template for the fabrication of porous silica with aligned nanochannels. 相似文献