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61.
This study presents an experimental investigation of the large plastic deformation of poly(ethylene terephthalate) (PET) submitted to plane strain compression. PET samples, obtained by injection moulding, annealed and non-annealed, were deformed using a specific compression device developed for this purpose. The obtained stress–strain curves at different temperatures and strain rates are useful for engineering applications and show a significant temperature dependence and a minor dependence on the strain rate. A softening temperature as a minimum temperature necessary to initiate deformation when a minimum, almost zero, stress is applied is introduced. This temperature, at the zero stress and strain limit, we denominate “Stress–Strain independent softening Temperature (T
SOF)”. The T
SOF values, 104 and 113°C for non-annealed and annealed PET, respectively, have been obtained using three different strain rates, indicating that the property is sensitive to the thermal history of the material. 相似文献
62.
Sandip N.Gavade Ravi S.Balaskar Madhav S.Mane Pramod N.Pabrekar Murlidhar S.Shingare Dhananjay V.Mane 《中国化学快报》2011,22(6):675-678
The coupling reaction of phenylurea with different functionalized aryl halides in the presence of air stable CuI,N,N-dimethylethylenediamine as a ligand,and K3PO4 as a base gives symmetrical and unsymmetrical diarylureas in relatively high yields.This method is milder than the palladium catalyzed arylation and avoids the use of toxic phosphine ligands. 相似文献
63.
64.
Using an off resonance ac technique in ultrahigh vacuum we have directly measured the force-gradient interaction characteristics of a gold tip and sample and demonstrated a new atomic force microscope imaging mode with the tip located very close to the surface. The method involves the application of a small sinusoidal oscillating force to the tip via a magnetic field created by a conducting coil which interacts with a magnetic particle glued on the backside of the cantilever. By measuring the change in amplitude during the approach and retraction of the sample we have a continuous and accurate measure of the force gradient. The interaction potential is thus found without the need for complex analysis as is necessary in the case of the commonly used technique of measuring frequency shifts. 相似文献
65.
L. Brossard R. Clerac C. Coulon M. Tokumoto T. Ziman D.K. Petrov V.N. Laukhin M.J. Naughton A. Audouard F. Goze A. Kobayashi H. Kobayashi P. Cassoux 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,1(4):439-452
In order to understand the magnetic field-induced restoration of a highly conductive state in , static (SQUID) and dynamic (ESR and AFR) magnetization measurements were performed on polycrystalline samples and single
crystals, respectively. In addition, cantilever and resistivity measurements under steady fields were performed. While the
metal-insulator transition curve of the () phase diagram exhibits a first order character, a “spin-flop” transition line divides the insulating state when the magnetic
field is applied along the easy axis of magnetization. The effects of a RKKY-type indirect exchange and of applied magnetic
field are described within the framework of a generalized Kondo lattice, namely two chains of localised spins coupled through the itinerant spins of the 2D sheets of BETS. The calculations, which can incorporate intramolecular
electron correlations within a mean field theory, are in qualitative agreement with the field induced transition from the
antiferromagnetic insulating ground state to a canted one, i.e. a not fully oriented paramagnetic, but metallic state.
Received: 6 August 1997 / Received: 5 November 1997 / Accepted: 10 November 1997 相似文献
66.
M.E. Kozlov M. Tokumoto K. Yakushi 《Applied Physics A: Materials Science & Processing》1997,64(3):241-245
60 are reported. The material associated with the mixture of rhombohedral and tetragonal phases was synthesized under pressure
of when treatment temperature was only a little lower than the high-temperature limit of C60 stability. The substance exhibits very rich infrared and Raman spectra as well as luminescence spectra of an unusual shape.
They show that vibrational transitions in the prepared carbon architecture substantially deviate from icosahedral symmetry
of buckyballs and exhibit a similarity with lattice phonons in graphite. It may originate from mixing of C60 modes and vibrations of a layer structure on deformed and weakly bound fullerene molecules. The luminescence spectra reveal
three distinct electronic states located below . One of them responsible for the emission peak at is very characteristic for the pressure modified fullerene. The data should be useful for the accurate determination of structural
changes in C60 induced by pressure.
Received: 6 September 1996/Accepted: 10 October 1996 相似文献
67.
Harrison N Mielke CH Christianson AD Brooks JS Tokumoto M 《Physical review letters》2001,86(8):1586-1589
ac susceptibility measurements of the charge-density-wave (CDW) compound alpha-(BEDT-TTF)(2)-KHg(SCN)(4) at magnetic fields, mu0H >23 T, above its Pauli paramagnetic limit, reveal unambiguously that the magnetic hysteresis observed previously within this CDW phase is diamagnetic and can only be explained by induced currents. It is argued that the ensemble of experimental techniques amounts to a strong case for dissipationless conductivity within this phase. 相似文献
68.
Helane?MS?Costa Augusto?CV?Freitas Júnior Ian?PG?Amaral Izaura?Y?Hirata Patrícia?MG?Paiva Luiz?B?CarvalhoJr Vitor?Oliveira Ranilson?S?BezerraEmail author 《Chemistry Central journal》2013,7(1):166
Background
Over the past decades, the economic development and world population growth has led to increased for food demand. Increasing the fish production is considered one of the alternatives to meet the increased food demand, but the processing of fish leads to by-products such as skin, bones and viscera, a source of environmental contamination. Fish viscera have been reported as an important source of digestive proteases with interesting characteristics for biotechnological processes. Thus, the aim of this study was to purify and to characterize a trypsin from the processing by-products of crevalle jack (Caranx hippos) fish.Results
A 27.5 kDa trypsin with N-terminal amino acid sequence IVGGFECTPHVFAYQ was easily purified from the pyloric caeca of the crevalle jack. Its physicochemical and kinetic properties were evaluated using N-α-benzoyl-DL-arginine-p-nitroanilide (BApNA) as substrate. In addition, the effects of various metal ions and specific protease inhibitors on trypsin activity were determined. Optimum pH and temperature were 8.0 and 50°C, respectively. After incubation at 50°C for 30 min the enzyme lost only 20% of its activity. K m , kcat, and k cat /K m values using BApNA as substrate were 0.689 mM, 6.9 s-1, and 10 s-1 mM-1, respectively. High inhibition of trypsin activity was observed after incubation with Cd2+, Al3+, Zn2+, Cu2+, Pb2+, and Hg2+ at 1 mM, revealing high sensitivity of the enzyme to metal ions.Conclusions
Extraction of a thermostable trypsin from by-products of the fishery industry confirms the potential of these materials as an alternative source of these biomolecules. Furthermore, the results suggest that this trypsin-like enzyme presents interesting biotechnological properties for industrial applications.69.
DE Blumling T Tokumoto S McGill KL Knappenberger 《Physical chemistry chemical physics : PCCP》2012,14(31):11053-11059
The influence of temperature and applied magnetic fields on photoluminescence (PL) emission and electronic energy transfer (ET) of both isolated and aggregated CdSe nanocrystals was investigated. Following 400-nm excitation, temperature-dependent, intensity-integrated and energy-resolved PL measurements were used to quantify the emission wavelength and amplitude of isolated CdSe nanocrystals. The results indicated an approximately three-fold increase in PL intensity upon decreasing the temperature from 300 K to 6 K; this was attributed to a reduction of charge carrier access to nanocrystal surface trap states and suppression of thermal loss channels. Temperature-dependent PL measurements of aggregated CdSe nanocrystals, which included both energy-donating and -accepting particles, were analyzed using a modified version of F?rster theory. Temperature-dependent ET efficiency increased from 0.55 to 0.75 upon decreasing the sample temperature from 225 K to 6 K, and the ET data contained the same trend observed for the PL of isolated nanoclusters. The application of magnetic fields to increase nanocrystal ET efficiency was studied using magneto-photoluminescence measurements recorded at a sample temperature of 1.6 K. We demonstrated that the exciton fine structure population of the donor was varied using applied magnetic fields, which in turn dictated the PL yield and the resultant ET efficiency of the CdSe nanocrystal aggregate system. The experimental data indicated an ET efficiency enhancement of approximately 7%, which was limited by the random orientation of the spherical nanocrystals in the thin film. 相似文献
70.
Yamada K Tokumoto Y Nagata T Mafuné F 《The journal of physical chemistry. B》2006,110(24):11751-11756
Gold nanoparticles with an average diameter of approximately 8 nm (Au approximately 15,000) were irradiated with a tightly focused pulse laser at 355 nm in an aqueous solution of sodium dodecyl sulfate (SDS). Transient absorption spectra of the solution were measured at 25-100 ns after the laser irradiation. The observed transient absorption around 720 nm is assignable to the 2p <-- 1s transition of solvated electrons produced via multiple ionization of the gold nanoparticles. The nascent charge state of the gold nanoparticles was estimated from the transient absorbance. The dependence of the charge state on the SDS concentration shows a gradual increase from approximately +60 to approximately +70 in the 2 x 10(-4) to 3 x 10(-4) M range and an abrupt increase up to approximately +710 at the critical micelle concentration (CMC) of SDS, 8 x 10(-3) M. TEM measurements after laser irradiation reveal that the gold nanoparticles fragment into Au(approximately 1000) at a SDS concentration of 3 x 10(-4) M, whereas they are significantly dissociated into Au(approximately 100) above the CMC. The observed correlation between the nascent charge states and the extent of size reduction of the gold nanoparticles after the laser treatment indicates that the size reduction is caused by the Coulomb explosion of the highly charged gold nanoparticles. The mechanism of laser-induced size reduction is quantitatively discussed based on the liquid drop model. 相似文献