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41.
Morse theory is a powerful tool in its applications to computational topology, computer graphics and geometric modeling. It was originally formulated for smooth manifolds. Recently, Robin Forman formulated a version of this theory for discrete structures such as cell complexes. It opens up several categories of interesting objects (particularly meshes) to applications of Morse theory. Once a Morse function has been defined on a manifold, then information about its topology can be deduced from its critical elements. The main objective of this paper is to introduce a linear algorithm to define optimal discrete Morse functions on discrete 2-manifolds, where optimality entails having the least number of critical elements. The algorithm presented is also extended to general finite cell complexes of dimension at most 2, with no guarantee of optimality. 相似文献
42.
L. Valadares Tavares 《Stochastic Processes and their Applications》1977,5(2):151-156
The exact distribution of extremes of a non-gaussian stationary discrete process is obtained and their crossing intervals are studied in terms of the autocorrelation coefficients for any level of crossing. This process is an important model for some physical magnitudes. 相似文献
43.
We study removable sets of solutions of locally solvable partial differential operators with smooth coefficients and characterize
them in terms of capacity in the sense of Harvey and Polking. For operators of order one we are able to give a geometric characterization
of removable sets in terms of orbits in the sense of Sussmann.
Oblatum 2-IX-1995 & 14-V-1996 相似文献
44.
In this work the separation of eighteen flavonoids was attempted using reduced-flow micellar elektrokinetic chromatography (RF-MEKC) electrolytes modified by selected solvents with differing properties: methanol (MeOH), acetonitrile (ACN) and tetrahydrofuran (THF). Structural aspects such as unsaturation of the C ring, number and position of OH groups, methylation and glycosylation as well as solvent effects and their impact on the electrophoretic behavior of flavonoids were addressed. By evaluating the electropherograms obtained from mixture-designed electrolytes and searching for changes in the critical pairs, a favorable separation condition was achieved using 20 mmol/L phosphate buffer at pH 2.5 containing 50 mmol/L sodium dodecyl sulfate (SDS), 15% ACN and 5% THF (one critical pair) in less than 12 min with 1.5% coefficient of variation (CV) for retention factor and 3% CV for peak area (n = 5). The applicability of the proposed separation condition was demonstrated by the inspection of flavonoids in herbal extracts of Neem. 相似文献
45.
O. A. P. Tavares E. L. Medeiros 《The European Physical Journal A - Hadrons and Nuclei》2010,45(1):57-60
The partial proton emission half-life for 53mCo unstable isomer is re-examined in the framework of a semiempirical model based on tunneling through a Coulomb-plus-centrifugal-plus-overlapping
potential barrier within the spherical nucleus approximation. It is shown that the known measured half-life value of 17s is
compatible with a large prolate shape for 53mCo proton emitter and a high angular momentum ℓ = 11 assigned to the proton transition to the ground state of 52Fe . 相似文献
46.
Boström M Tavares FW Ninham BW Prausnitz JM 《The journal of physical chemistry. B》2006,110(48):24757-24760
Monte Carlo simulations are used to establish the potential of mean force between two globular proteins in an aqueous electrolyte solution. This potential includes nonelectrostatic contributions arising from dispersion forces first, between the globular proteins, and second, between ions in solution and between each ion and the globular protein. These latter contributions are missing from standard models. The potential of mean force, obtained from simulation, is fitted to an analytic equation. Using our analytic potential of mean force and Barker-Henderson perturbation theory, we obtain phase diagrams for lysozyme solutions that include stable and metastable fluid-fluid and solid-fluid phases when the electrolyte is 0.2 M NaSCN or NaI or NaCl. The nature of the electrolyte has a significant effect on the phase diagram. 相似文献
47.
48.
49.
L. C. R. Andrade M. J. M. de Almeida F. M. Fernandes Roleira C. L. Varela E. J. Tavares da Silva 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(9):o508-o510
The title compound, C19H29NO, is a C17‐oxime derivative of a potent aromatase inhibitor, which surprisingly has been found to have no inhibitory power. It crystallizes with two independent molecules in the asymmetric unit. C=N—O—H...N hydrogen bonds link pairs of molecules to form dimers almost parallel to the bc plane. Cohesion of the structure is also due to another three C—H...O hydrogen bonds directed along the a axis. This hydrogen‐bonding scheme can be correlated to the almost complete loss of inhibitory power of the title compound. 相似文献
50.
Lima ER Horinek D Netz RR Biscaia EC Tavares FW Kunz W Boström M 《The journal of physical chemistry. B》2008,112(6):1580-1585
Mean-field theories that include nonelectrostatic interactions acting on ions near interfaces have been found to accommodate many experimentally observed ion specific effects. However, it is clear that this approach does not fully account for the liquid molecular structure and hydration effects. This is now improved by using parametrized ionic potentials deduced from recent nonprimitive model molecular dynamics (MD) simulations in a generalized Poisson-Boltzmann equation. We investigate how ion distributions and double layer forces depend on the choice of background salt. There is a strong ion specific double layer force set up due to unequal ion specific short-range potentials acting between ions and surfaces. 相似文献