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991.
A novolac phenol-formaldehyde resin was investigated via the thermally stimulated depolarization current, using integral and partial measurements in the temperature range from 137 to 270 K. Tow broadened peaks, assigned as Β1, and Β2, appeared at about 160 and 190 K. The influence of water and ¯Mn was investigated. The activation energy Ea vs. T relationship was analysed, and a search was made for compensation phenomena. The distribution of the relaxing dipolesN vs. Ea was approximated. Three different relaxation ranges were distinguished. All the motions were attributed to the rotation of the phenyl rings. The differences found are due to the heterogeneity in the resin. Contamination with water increases the polarizability, decreases the structure differences and relieves the motions in the resin. A resin with a smaller ¯Mn exhibits a higher polarizability and a decreases in structure variety. 相似文献
992.
A. Vertačnik D. Barišić Lj Musani E. Prohić M. Juračić 《Journal of Radioanalytical and Nuclear Chemistry》1997,218(1):45-52
Concentrations of Ag, Ba, Cd, Ce, Cs, Co, Cr, Eu, Fe, Rb, Sc, Sr, Th, and Zn exchangeable fractions were determined in alluvial sediments at waste disposal site area in the vicinity of water-well field. Samples have been leached with 0.5M NH4Cl at a sample/solution ratio of 120 during 24 hours without shaking. INAA of dry NH4Cl residues show that the concentrations of exchangeable elements determined in the most of the sediments below the wastes have natural levels. Ag, Ba and Sr are readily exchangeable; Rb, Cs and Zn have lower exchangeability, while Cd, Ce, Th, Sc, Eu, Cr, Fe and Co are rather immobile. Extremely high total and exchangeable silver concentration was found at 6.5–6.8 meters below waste in the aerated layer occasionally under the water table. Exchangeable concentrations in deeper water-bearing sediment layers are not elevated. Due to this, one can presume that the upper sediment layers act as chemical filter generally preventing the infiltration from overlying wastes into water-bearing layers. 相似文献
993.
Considering mixed-norm sequence spaces lp,q, p, q 1, C. N. Kellogg proved the following theorem: if 1 < p 2 then
lp,2 and lp,2
, where 1/p + 1/p = 1. This result extends the Hausdorff-Young Theorem.We introduce here multiple mixed-norm sequence spaces
, examine their properties and characterize the multipliers of spaces of the form lp,[s;n],q, with the index s repeated n times. By an interpolation-type argument we prove that
(l,[2;n],2, lp,[1;n],1) for 1 < p 2. Using these results we obtain a further generalization of the Hausdorff-Young Theorem: if 1 < p 2 then
lp,[2;n] and lp,[2;n]
for each n = 0, 1, 2, ¨. The spaces lp,[2;n] decrease and lp,[2;n] increase properly with n for 1 < p < 2 and 1/p + 1/p = 1. We also extend a theorem of J. H. Hedlund on multiplers of Hardy spaces
and deduce other results. 相似文献
994.
Sanja Tomić Razif R. Gabdoulline Biserka Kojić-Prodić Rebecca C. Wade 《Journal of computer-aided molecular design》1998,12(1):63-79
Although auxins were the first type of plant hormone to be identified, little is known about the molecular mechanism of this important class of plant hormones. We present a classification of a set of about 50 compounds with measured auxin activities, according to their interaction properties. Four classes of compounds were defined: strongly active, weakly active with weak antiauxin behaviour, inactive and inhibitory. All compounds were modeled in two low-energy conformations, P and T, so as to obtain the best match to the planar and tilted conformations, respectively, of indole 3-acetic acid. Each set of conformers was superimposed separately using several different alignment schemes. Molecular interaction energy fields were computed for each molecule with five different chemical probes and then compared by computing similarity indices. Similarity analysis showed that the classes are on average distinguishable, with better differentiation achieved for the T conformers than the P conformers. This indicates that the T conformation might be the active one. Further, a screening was developed which could distinguish compounds with auxin activity from inactive compounds and most antiauxins using the T conformers. The classifications rationalize ambiguities in activity data found in the literature and should be of value in predicting the activities of new plant growth substances and herbicides. 相似文献
995.
We prove boundedness of the Lusin's area operatorS
T
on the space BMO(R
n
). 相似文献
996.
By generalizing some well-known results, we first obtain an inequality involving the volume and product of s-contents of s-faces of an n-simplex. Using this we generalize two inequalities maximizing the volume of one or two simplices in terms of their edge lengths. 相似文献
997.
998.
999.
Marijana Gavranić Branko Kaitner Ernest Meštrović 《Journal of chemical crystallography》1996,26(1):23-28
The structures of N-(-naphthyl)-2-oxy-1-naphthaldimine1 and N-(-naphthyl)-2-oxy-1-naphthaldimine2 have been investigated by X-ray analysis and by spectroscopic methods. Crystals of1 are monoclinic, space groupPn, with cell dimensionsa=10.823(3),b=5.826(2),c=11.899 (3) Å, and =99.66(3)°. Compound2 crystallizes in the orthorhombic space groupPca21 witha=17.564(3),b=6.314(2), andc=13.663(4) Å. The IR spectra exhibited neither N–H nor O–H stretching frequencies. The existence of theintramolecular hydrogen bonding of N–H...O type was predicted by spectroscopic experiment but unequivocally established by diffraction experiment in both cases1 and2. The molecules1 and2 are significantly planar with considerable quinoid effect at the 2-oxy-naphthaldimine moiety. Although essentially planar, both molecules1 and2 show the delocalization of -electrons only in the central part of the molecules including C=N imino group with pendent ring carbon atoms.Intermolecular attractions in the crystals belong to weak van der Waals interactions-between discrete planar molecules spatially arranged into the expectedherringbone motif in the solid state. 相似文献
1000.
A new heterogeneous catalyst composed of copper and nickel oxide particles supported within charcoal has been developed. It catalyzes cross-couplings that traditionally use palladium, nickel, or copper, including Suzuki-Miyaura reactions, Buchwald-Hartwig aminations, vinylalane alkylations, etherifications of aryl halides, aryl halide reductions, asymmetric conjugate reductions of activated olefins, and azide-alkyne "click" reactions. 相似文献