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71.
Basak R Mukhopadhyay N Bandyopadhyay R 《The European physical journal. E, Soft matter》2011,34(9):103
Photon correlation spectroscopy and rheological measurements are performed to investigate the microscopic dynamics and mechanical
responses of aqueous solutions of triblock copolymers and aqueous mixtures of triblock copolymers and anionic surfactants.
Increasing the concentration of triblock copolymers results in a sharp increase in the magnitude of the complex moduli characterising
the samples. This is understood in terms of the changes in the aggregation and packing behaviours of the copolymers and the
constraints imposed upon their dynamics due to increased close packing. The addition of suitable quantities of an anionic
surfactant to a strongly elastic copolymer solution results in a decrease in the complex moduli of the samples by several
decades. It is argued that the shape anisotropy and size polydispersity of the micelles comprising mixtures cause dramatic
changes in the packing behaviour, resulting in sample unjamming and the observed decrease in complex moduli. Finally, a phase
diagram is constructed in the temperature-surfactant concentration plane to summarise the jamming-unjamming behaviour of aggregates
constituting triblock copolymer-anionic surfactant mixtures. 相似文献
72.
Sukanta Kumar DashAmar Nath Samanta Syamalendu S. Bandyopadhyay 《Fluid Phase Equilibria》2011,307(2):166-174
In this work, new experimental results of the vapour-liquid equilibrium (VLE) of CO2 in aqueous 2-amino-2-methyl-1-propanol (AMP) and piperazine (PZ) have been presented in the temperature range of 298-328 K and PZ concentration range of 2-8 mass%, keeping the total amine concentration in the solution at 30 mass%. The partial pressures of CO2 were in the range of 0.1-1450 kPa. A thermodynamic model was developed to correlate and predict the VLE of CO2 in aqueous AMP + PZ. The electrolyte nonrandom two liquid (ENRTL) theory has been used to develop the VLE model for the quaternary system (CO2 + AMP + PZ + H2O) to describe the equilibrium behaviour of the solution. The experimental data from this work and data available in the literature were used to regress the ENRTL interaction parameters. The model predictions are in good agreement with the experimental data of CO2 solubility in aqueous blends of this work as well as those reported in the literature. The current model can also predict speciation, heat of absorption, pH of the CO2 loaded solution, and amine volatility. 相似文献
73.
74.
Bahni Ray P. Dinesh Sankar Reddy Dipankar Bandyopadhyay Sang Woo Joo Ashutosh Sharma Shizhi Qian Gautam Biswas 《Theoretical and Computational Fluid Dynamics》2012,26(1-4):311-318
Instability of a thin electrolyte film undergoing a direct current electroosmotic flow has been investigated. The film with a compliant electrolyte–air interface is flowing over a rigid charged substrate. Unlike previous studies, inclusion of the Maxwell stresses in the formulation shows the presence of a new finite wavenumber shear-flow mode of instability, alongside the more frequently observed long-wave interfacial mode. The shear mode is found to be the dominant mode of instability when the electrolyte–solid and electrolyte–air interfaces are of opposite charge or of same charge but have very large zeta-potential at the electrolyte–air interface. The conditions for mode-switch (interfacial to shear) and the direction of the travelling waves are discussed through stability diagrams. Interestingly, the analysis shows that when the interfaces are of nearly same zeta potential, the ‘free’ electrolyte–air interface behaves more like a ‘stationary’ wall because of the ion transport in the reverse direction of the flow. 相似文献
75.
76.
Mrinal Kanti Roychowdhury 《Journal of Mathematical Analysis and Applications》2011,383(2):499-505
The quantization dimension function for a probability measure induced by a set of infinite contractive similarity mappings and a given probability vector is determined. A relationship between the quantization dimension function and the temperature function of the thermodynamic formalism arising in multifractal analysis is established. The result in this paper is an infinite extension of Graf and Luschgy [S. Graf, H. Luschgy, The quantization dimension of self-similar probabilities, Math. Nachr. 241 (2002) 103-109]. 相似文献
77.
Rajoshree Bandyopadhyay 《Journal of organometallic chemistry》2010,695(7):1012-10984
The treatment of tin(II) trifluoromethanesulfonate with three differently-sized crown ethers [12]crown-4, [15]crown-5 and [18]crown-6 results in the formation of tin complexes that exhibit dramatically different structural features. The compounds are investigated using experimental techniques and density functional theory calculations. 相似文献
78.
We report here high-pressure x-ray diffraction (XRD) studies on tellurium (Te) at room temperature up to 40 GPa in the diamond
anvil cell (DAC). The XRD measurements clearly indicate a sequence of pressure-induced phase transitions with increasing pressure.
The data obtained in the pressure range 1 bar to 40 GPa fit five different crystalline phases out of Te: hexagonal Te (I)
→ monoclinic Te(II) → orthorhombic Te (III) → Β-Po-type Te(IV) → body-centered-cubic Te(V) at 4, 6.2, 11 and 27 GPa, respectively. The volume changes across these transitions
are 10%, 1.5%, 0.3% and 0.5%, respectively.
Self consistent electronic band structure calculations both for ambient and high pressure phases have been carried out using
the tight binding linear muffin tin orbital (TB-LMTO) method within the atomic-sphere approximation (ASA). Reported here apart
from the energy band calculations are the density of states (DOS), Fermi energy (E
f) at various high-pressure phases. Our calculations show that the ambient pressure hexagonal phase has a band gap of 0.42
eV whereas high-pressure phases are found to be metallic. We also found that the pressure induced semiconducting to metallic
transition occurs at about 4 GPa which corresponds to the hexagonal phase to monoclinic phase transition. Equation of state
and bulk modulus of different high-pressure phases have also been discussed. 相似文献
79.
A series of unexpected cycloadducts along with normal cycloadducts have been isolated from the 1,3-dipolar cycloaddition of 3,4-dehydromorpholine N-oxide to piperidides of cinnamic acid and para-substituted cinnamic acids and these were analyzed by X-ray crystallography to reveal novel solid-state structures. At first, 1:1 cycloadducts were formed which underwent in situ nucleophilic attack by another reduced nitrone moiety. A plausible iminium-oxonium ion mechanism has been proposed. 相似文献
80.
The breakdown of statistical homogeneity and isotropy of cosmic perturbations is a generic feature of ultra-large scale structure
of the cosmos, in particular, of non-trivial cosmic topology. The statistical isotropy (SI) of the cosmic microwave background
temperature fluctuations (CMB anisotropy) is sensitive to this breakdown on the largest scales comparable to, and even beyond
the cosmic horizon. We propose a set of measures,K
l
(l = 1, 2,3,...) which for non-zero values indicate and quantify statistical isotropy violations in a CMB map. We numerically
compute the predictedK
l
spectra for CMB anisotropy in flat torus universe models. Characteristic signatures of different models in theK
l
spectrum are noted. 相似文献