全文获取类型
收费全文 | 180篇 |
免费 | 4篇 |
专业分类
化学 | 67篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 66篇 |
物理学 | 48篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 8篇 |
2020年 | 4篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 9篇 |
2013年 | 11篇 |
2012年 | 15篇 |
2011年 | 12篇 |
2010年 | 20篇 |
2009年 | 4篇 |
2008年 | 9篇 |
2007年 | 10篇 |
2006年 | 10篇 |
2005年 | 7篇 |
2004年 | 2篇 |
2003年 | 2篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1985年 | 2篇 |
1983年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有184条查询结果,搜索用时 0 毫秒
101.
Volodymyr SvitlykTyler Russell Taras KolodiazhnyiYurij Mozharivskyj 《Journal of magnetism and magnetic materials》2012,324(7):1419-1424
Small single crystals of the Fe1.14(7)Cr1.86(8)Se4.0(2) ferrimagnet were grown using chemical vapor transport. Fe1.14Cr1.86Se4 adopts the Cr3S4 structure with two metal sites. The magnetic behavior of Fe1.14Cr1.86Se4 can be described by two magnetic sublattices with different magnetization values and different temperature dependencies. Depending on the experimental conditions, such as the strength and direction of the cooling field, magnetization reversal, large negative magnetization and high-temperature compensation point may result. If the cooling field exceeds 1.5 Oe, magnetization reversal occurs at low temperatures. If the cooling and applied fields are opposite, a large negative magnetization and high-temperature compensation point are observed. 相似文献
102.
We apply the 2D Jordan-Wigner fermionization to examine the ground state and thermodynamic properties of the square-lattice s=1/2 anisotropic XY model. We compare our findings with the results of different analytical and numerical approaches. 相似文献
103.
Piotr Błaszczyk Alexandre Borovik Vladimir Kanovei Mikhail G. Katz Taras Kudryk Semen S. Kutateladze David Sherry 《Logica Universalis》2016,10(4):393-405
We examine Paul Halmos’ comments on category theory, Dedekind cuts, devil worship, logic, and Robinson’s infinitesimals. Halmos’ scepticism about category theory derives from his philosophical position of naive set-theoretic realism. In the words of an MAA biography, Halmos thought that mathematics is “certainty” and “architecture” yet 20th century logic teaches us is that mathematics is full of uncertainty or more precisely incompleteness. If the term architecture meant to imply that mathematics is one great solid castle, then modern logic tends to teach us the opposite lesson, namely that the castle is floating in midair. Halmos’ realism tends to color his judgment of purely scientific aspects of logic and the way it is practiced and applied. He often expressed distaste for nonstandard models, and made a sustained effort to eliminate first-order logic, the logicians’ concept of interpretation, and the syntactic vs semantic distinction. He felt that these were vague, and sought to replace them all by his polyadic algebra. Halmos claimed that Robinson’s framework is “unnecessary” but Henson and Keisler argue that Robinson’s framework allows one to dig deeper into set-theoretic resources than is common in Archimedean mathematics. This can potentially prove theorems not accessible by standard methods, undermining Halmos’ criticisms. 相似文献
104.
Taras K. Antal Wayne Lo William H. Armstrong Esa Tyystjärvi 《Photochemistry and photobiology》2009,85(3):663-668
We measured the photosensitivity of an artificial tetranuclear oxo–Mn(IV) complex, [Mn4 O6 (bpea)4 ]Br4 , which has an adamantane-shaped {Mn4 O6 }4+ core. Illumination caused changes in the absorption spectrum of the compound consistent with a one-electron reduction in the compound. Bromide appears to be the most probable electron donor in the reaction system. Chemical modification of the cluster appears to destabilize it, predisposing it to reductive degradation. UV light was more efficient than visible light in causing the changes. The data support the suggestion that the natural oxygen-evolving Mn complex is photosensitive and can oxidize components of the oxygen-evolving complex in its excited state causing photoinhibition, and that photostability is an important issue in designing Mn complexes for artificial photosynthesis. Furthermore, light-induced oxidation of bromide by [Mn4 O6 (bpea)4 ]4+ may suggest that oxidation of chloride is involved in natural water splitting or has been involved during the evolution of the water-splitting enzyme. 相似文献
105.
Iyor Yu. Sagalianov Taras M. Radchenko Yuriy I. Prylutskyy Valentyn A. Tatarenko Pawel Szroeder 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(6):112
The study deals with electronic properties of uniaxially stressed mono- and multi-layer graphene sheets with various kinds of imperfection: point defects modelled as resonant (neutral) adsorbed atoms or molecules, vacancies, charged impurities, and local distortions. The presence of randomly distributed defects in a strained graphene counteract the band-gap opening and even can suppress the gap occurs when they are absent. However, impurity ordering contributes to the band gap appearance and thereby re-opens the gap being suppressed by random dopants in graphene stretched along zigzag-edge direction. The band gap is found to be non-monotonic with strain in case of mutual action of defect ordering and zigzag deformation. Herewith, the minimal tensile strain required for the band-gap opening (≈12.5%) is smaller than that for defect-free graphene (≈23%), and band gap energy reaches the value predicted for maximal nondestructive strains in the pristine graphene. Effective manipulating the band gap in graphene requires balanced content of ordered dopants: their concentration should be sufficient for a significant sublattice asymmetry effect, but not so much that they may suppress the band gap or transform it into the “quasi- (or pseudo-) gap”. 相似文献
106.
Despite the availability of a spin Hamiltonian for the Gd(3)Ga(5)O(12) garnet (GGG) for over 25 years, there has so far been little theoretical insight regarding the many unusual low temperature properties of GGG. Here we investigate GGG in zero magnetic field using mean-field theory. We reproduce the spin liquid-like correlations and, most importantly, explain the positions of the sharp peaks seen in powder neutron diffraction experiments. We show that it is crucial to treat accurately the long-range nature of the magnetic dipolar interactions to allow for a determination of the small exchange energy scales involved in the selection of the experimental ordering wave vector. Our results show that the incommensurate order in GGG is classical in nature, intrinsic to the microscopic spin Hamiltonian and not caused by weak disorder. 相似文献
107.
A map f:X→Y between topological spaces is defined to be scatteredly continuous if for each subspace AX the restriction f|A has a point of continuity. We show that for a function f:X→Y from a perfectly paracompact hereditarily Baire Preiss–Simon space X into a regular space Y the scattered continuity of f is equivalent to (i) the weak discontinuity (for each subset AX the set D(f|A) of discontinuity points of f|A is nowhere dense in A), (ii) the piecewise continuity (X can be written as a countable union of closed subsets on which f is continuous), (iii) the Gδ-measurability (the preimage of each open set is of type Gδ). Also under Martin Axiom, we construct a Gδ-measurable map f:X→Y between metrizable separable spaces, which is not piecewise continuous. This answers an old question of V. Vinokurov. 相似文献
108.
Dy2Ti2O7 is a geometrically frustrated magnetic material with a strongly correlated spin ice regime that extends from 1 K down to as low as 60 mK. The diffuse elastic neutron scattering intensities in the spin ice regime can be remarkably well described by a phenomenological model of weakly interacting hexagonal spin clusters, as invoked in other geometrically frustrated magnets. We present a highly refined microscopic theory of Dy2Ti2O7 that includes long-range dipolar and exchange interactions to third nearest neighbors and which demonstrates that the clusters are purely fictitious in this material. The seeming emergence of composite spin clusters and their associated scattering pattern is instead an indicator of fine-tuning of ancillary correlations within a strongly correlated state. 相似文献
109.
We study the asymptotic behavior of eigenvalues and eigenfunctions of the Laplacian in a 2D thick cascade junction with heavy concentrated masses. We present two-term asymptotic approximations, as ε→0, for the eigenelements in the case of “slightly heavy”, “moderate heavy”, and “super heavy” concentrated masses. Asymptotics of high-frequency cell-vibrations are found as well. 相似文献
110.
Taras Gula Carolyn Hoessler 《International Journal of Mathematical Education in Science & Technology》2013,44(8):1130-1148
Many students enter the Canadian college system with insufficient mathematical ability and leave the system with little improvement. Those students who enter with poor mathematics ability typically take a developmental mathematics course as their first and possibly only mathematics course. The educational experiences that comprise a developmental mathematics course vary widely and are, too often, ineffective at improving students’ ability. This trend is concerning, since low mathematics ability is known to be related to lower rates of success in subsequent courses. To date, little attention has been paid to the selection of an instructional approach to consistently apply across developmental mathematics courses. Prior research suggests that an appropriate instructional method would involve explicit instruction and practising mathematical procedures linked to a mathematical concept. This study reports on a randomized field trial of a developmental mathematics approach at a college in Ontario, Canada. The new approach is an adaptation of the JUMP Math program, an explicit instruction method designed for primary and secondary school curriculae, to the college learning environment. In this study, a subset of courses was assigned to JUMP Math and the remainder was taught in the same style as in the previous years. We found consistent, modest improvement in the JUMP Math sections compared to the non-JUMP sections, after accounting for potential covariates. The findings from this randomized field trial, along with prior research on effective education for developmental mathematics students, suggest that JUMP Math is a promising way to improve college student outcomes. 相似文献