A New Triterpene from the Orchid Pholidota yunnanensis

A new triterpene, 25-methylenecyclopholidonyl p-hydroxy-trans-cinnamate, was isolated from a orchid Pholidota yunnanensis. The structure elucidation and ^1H, ^13C-NMR assignments were achieved by spectral and chemical method.     

统一混沌系统的控制

对统一混沌系统建立了自反馈控制、错位反馈控制和自适应控制方法，在理论上给予严格证明，数值仿真表明这些方法是很有效的.还纠正了文献［１０］的某些不足. 关键词： 统一混沌系统 反馈 自适应 控制 Routh-Hurwitz定理     

全景图像几何畸变校正的算法研究及其软件实现

对于360°视场的全景图像,本文提出了分别对其进行切向和径向畸变校正的处理算法,并用插值处理提高处理精度。达到了将全景图像恢复为常规视场平面像的目的。它是进一步图像分析的前期工作。     

Mean curvature flows and isotopy of maps between spheres

Let f be a smooth map between unit spheres of possibly different dimensions. We prove the global existence and convergence of the mean curvature flow of the graph of f under various conditions. A corollary is that any area‐decreasing map between unit spheres (of possibly different dimensions) is isotopic to a constant map. © 2004 Wiley Periodicals, Inc.     

高压下聚苯胺的结构和电性能研究

 以金刚石压腔高压装置为工具，用Ⅱ型金刚石作压砧兼红外窗口，对本征态聚苯胺进行了高压（0~8.4 GPa）就位红外光谱测试。结果表明：在4.8~5.2 GPa压力区间，代表醌环振动的吸收峰相对代表苯环振动的吸收峰变小，表明聚苯胺在此压力区间结构上发生了显著变化，且这种变化是不可逆的。聚苯胺的高压（0~14.5 GPa）电阻测量结果表明：当压力小于7.5 GPa时，电阻随压力升高而显著降低，据此认为聚苯胺为电子性导电物质；在7.5 GPa处电阻出现极小值，然后又缓慢升高，至10 GPa后基本不变。推测聚苯胺电阻极小值是由结构变化引起的。至于红外光谱与电阻测量结果反映聚苯胺结构变化的压力值不一致，可能是由于测试条件不同所致。     

N_2和O_2纯转动拉曼光谱(PRRS)的温度特性

计算了N2 和O2 的PRRS ,讨论了其温度特性。提出通过测量N2 和O2 的PRRS计算大气温度的方法。     

Structure and magnetic properties of nanocrystalline ferromagnets (II)

The role of magnetoelastic coupling effects in nanocrystalline ferromagnets is investigated by means of high-field magnetization and Doppler-broadening spectrum measurements. For the nanocrystalline Fe_{73 5}Cu₁Nb₃Si_13.5B₉ alloy, the results show that the pinning effects resulting from the quasidislocation dipole intensely influence the movement of domain wall; by coupling with the magnetostriction the defects-induced stress fields determine the magnetic properties at the early stage of crystallization. In view of the effective anisotropy and magnetoelastic coupling energy the optimal annealing conditions of alloys are discussed.     

四氢β—咔啉类化合物的~(13)C NMR研究

测定了四对新合成的四氢β-咔啉化合物的~13C NMR谱,通过APT,HETCOR和HETCOLOC谱指认了所有碳的归属.所确定的化学位移规律可以用来确定它们的构型.     

H2S·HOH or H2O·HSH, which is more stable in the water-hydrogen sulfide complex?

High-level ab initio calculations are carried out to study the relative stability of the two hydrogen bonded structures of water-hydrogen sulfide complex, one with water as the proton donor (A) and the other with hydrogen sulfide as the proton donor (B). The results show that structure A is considerably more stable than B at the correlated level, which is in contrast with previous results obtained from Hartree-Fock calculations.     

罗尔定理证明一类存在性问题

提出罗尔定理证明一类存在性问题的方法,采用拉格朗日中值定理或柯西中值定理来证明这类问题往往需要构造精巧的辅助函数,我们还指出了这种方法的一般性.