Effect of Ce<Superscript>3+</Superscript> on spectral characteristic of D1/D2/Cytb559 complex from spinach

It was studied by spectroscopy that PSII reaction center complex consisting of three polypeptides, D₁, D₂ and Cytb559, were purified from PSII particle of CeCl₃ treated spinach. The results of the experiment show that Ce³⁺ could improve the growth of spinach, and accelerate electron transport of PSII particles. Of chl-a of UV-Vis spectrum of D1/D2/Cytb559 complex, Soret band was blue-shifted by 3 nm and Q band by 2 nm, respectively, and the fluorescence emission peak was blue-shifted by 5 nm in CeCl₃-treated spinach compared with the one in control. By the extended X-ray absorption fine structure (EXAFS) spectroscopy methods, it has been found that Ce³⁺ is coordinated with 8 nitrogen atoms in the first coordination shell with Ce-N bond length of 0.253 nm, and Ce³⁺ with 6 oxygen atoms in the second coordination shell with Ce-O bond length of 0.32 nm. However, the secondary structure of D1/D2/Cytb559 complex by circular dichroism (CD) spectroscopy has no significant change after CeCl₃ treated. It might be that Ce³⁺ binds to porphyrin rings of chlorophyll and oxygen of amino acid residue of polypeptide in D1/D2/Cytb559 complex, and then accelerates the primary reaction of PSII, intensifies function of P680⁺ primary electron donor of D1/D2/Cytb559, but there is little change in conformation of PSII reaction center complex.     

Experimental study of natural convection heat transfer between an outer horizontal cylindrical envelope and an inner concentric heated square cylinder with two slots

This paper presents the results of an experimental study of natural convection heat transfer between a horizontal cylindrical envelope and an internal concentric heated square cylinder with two slots. The internal cylinder was a hollow one with horizontal slots on its top and bottom surfaces. The ratio of slot widthS to the side heightH was 0.0612 and 0.3878. The ratio of the envelope inner diameterD _o to the side heightH was 2.653. Air was used as the working fluid. The range of Ray-leigh number was 1.77×10²8.72×10⁶ forS/H=0.0612 and 1.32×10²6.25×10⁶ forS/H=0.3878. The results show that there are three different heat transfer regimes in different Ray-leigh number regions, i.e. pure conduction regime, transition regime and convection regime. The average heat transfer results were correlated into two empirical equations. Comparison was made with the non-slotted case. It is found that slots of the internal cylinder can significantly enhance the heat transfer.

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Experimentelle Untersuchung des Wärmeübergangs bei natürlicher Konvektion zwischen einer horizontalen zylindrischen Außenhülle und einem konzentrischen, beheizten, quadratischen Prisma mit zwei Schlitzen

Zusammenfassung In der Arbeit werden die Ergebnisse einer experimentellen Untersuchung des Wärmeübergangs bei natürlicher Konvektion zwischen einer horizontalen zylindrischen Außenhülle und einem beheizten quadratischen Prisma mit zwei Schlitzen vorgestellt. Das Prisma selbst ist hohl und weist in der oberen und unteren Begrenzungsfläche je einen horizontalen Längsschlitz auf. Das Verhältnis von SchlitzweiteS zu SeitenhöheH beträgt 0,0612 und 0,3878, das des HülleninnendurchmessersD _o zur SeitenhöheH beträgt 2,653. Als Arbeitsmedium diente Luft. Die Rayleigh-Zahlen variierten zwischen 1,7·10² und 8,72·10⁶ fürS/H=0,0612 und zwischen 1,32·10² und 6,25·10⁶ fürS/H=0,3878. Die Ergebnisse belegen die Existenz dreier unterschiedlicher Wärmeübergangsregime in den verschiedenen Rayleigh-Zahl-Bereichen, und zwar reiner Leitungsbereich, Übergangsgebiet und Konvektionsbereich. Die Ergebnisse für den Wärmeübergang werden im Vergleich mit jenen für ein Prisma ohne Schlitze durch zwei Korrelationbeziehungen dargestellt. Es zeigt sich, daß durch Anbringung von Schlitzen am Innenprisma der Wärmeübergang wesentlich verstärkt werden kann.

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Nomenclature C _p specific heat at constant pressure, J/(kg·K) - D _i diameter of the related circular cylinder whose circumferential area is equal to that of the unslotted square cylinder, m - D _o internal diameter of the outer circular envelope, m - F _i surface area of the inner two slot cylinder, m - g gravitational acceleration, m/s² - H distance between the opposite sides of the square cylinder with two slots, m - K _eq dimensionless equivalent thermal conductivity - L axial length of the test section, m - m ratio of the area of the unslotted square cylinder surface to that of the slotted square cylinder - P pressure in the enclosure, Pa - Q total power input to the enclosure, W - Q _cond radial heat conduction, W - Q _conv convective heat transfer, W - Q _r radiation heat transfer, W - Q _los end heat dissipation, W - R air gas constant, J/(kg·K) - Ra Rayleigh number - S slot width, m - T _i wall temperature of the inner cylinder, K - T _o wall temperature of the outer envelope, K - T _m mean temperature, K - T temperature difference=T _i –T _o , K - W maximum gap width of the test annuli=(D _o –H)/2 for the square case, m Greek symbols ₀ black body radiation constant, W/(m²·K⁴) - _s equation system emissivity - air thermal conductivity, W/(m·K) - _eq equivalent thermal conductivity, W/(m·K) - air dynamic viscosity, kg/(m·s) This work was supported by the National Natural Science Foundation of China.     

Efficient degradation of organic pollutants mediated by immobilized iron tetrasulfophthalocyanine under visible light irradiation

Supported iron tetrasulfophthalocyanine can efficiently catalyze the degradation of organic pollutants by H2O2 under visible light irradiation in an aqueous solution, and the catalyst can be easily recycled without apparent loss of activity.     

Two New Pyrrolizidines from Ligularia lankongensis

Two new pyrrolizidines named lankongensisine A (1), B (2) were isolated from the roots of Ligularia lankongensis collected in Lijiang, Yunnan, and their structures were established by spectroscopic analysis.