全文获取类型
收费全文 | 341篇 |
免费 | 17篇 |
国内免费 | 1篇 |
专业分类
化学 | 229篇 |
晶体学 | 3篇 |
力学 | 2篇 |
数学 | 18篇 |
物理学 | 107篇 |
出版年
2021年 | 6篇 |
2020年 | 3篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 8篇 |
2012年 | 7篇 |
2011年 | 22篇 |
2010年 | 9篇 |
2009年 | 17篇 |
2008年 | 18篇 |
2007年 | 16篇 |
2006年 | 17篇 |
2005年 | 18篇 |
2004年 | 14篇 |
2003年 | 11篇 |
2002年 | 10篇 |
2001年 | 9篇 |
2000年 | 15篇 |
1999年 | 8篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 10篇 |
1994年 | 5篇 |
1993年 | 7篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1976年 | 4篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1964年 | 1篇 |
1961年 | 1篇 |
1960年 | 1篇 |
1959年 | 1篇 |
1932年 | 1篇 |
1927年 | 1篇 |
排序方式: 共有359条查询结果,搜索用时 281 毫秒
41.
meso‐Dibenzoporphycene has a Large Bathochromic Shift and a Porphycene Framework with an Unusual cis Tautomeric Form 下载免费PDF全文
Dr. Koji Oohora Ayumu Ogawa Tamaki Fukuda Dr. Akira Onoda Prof. Dr. Jun‐ya Hasegawa Prof. Dr. Takashi Hayashi 《Angewandte Chemie (International ed. in English)》2015,54(21):6227-6230
meso‐Monobenzoporphycene (mMBPc) and meso‐dibenzoporphycene (mDBPc), in which one or two benzene moieties are fused at ethylene‐bridged positions (meso‐positions) of porphycene, were prepared in an effort to further delocalize the π‐electrons within the porphycene molecule. mMBPc and mDBPc were fully characterized by mass spectrometry, 1H and 13C NMR spectroscopy, and X‐ray crystallography. The longest‐wavelength Q‐bands of mMBPc and mDBPc are red‐shifted by 92 nm and 418 nm, respectively, compared to that of the unsubstituted porphycene (Pc). Electrochemical measurements indicate that the HOMO is destabilized and the LUMO is stabilized by the fused benzene moieties at the meso positions. Furthermore, both XPS and theoretical studies support the presence of a cis tautomeric form in the ground state of mDBPc, despite the fact that essentially all known porphycene derivatives adopt the trans tautomeric form. 相似文献
42.
43.
Imoto M Matsui Y Takeda M Tamaki A Taniguchi H Mizuno K Ikeda H 《The Journal of organic chemistry》2011,76(15):6356-6361
Observations show that nitroanilines exhibit an unusually high S(N)Ar reactivity with OH(-) in aqueous media in reactions that produce nitrophenols. S(N)Ar reaction of 4-nitroaniline (2a) in aqueous NaOH for 16 h yields 4-nitrophenol (4a) quantitatively, whereas a similar reaction of 4-nitrochlorobenzene (1a) gave 4a in 2% yield together with recovered 1a in 97%, suggesting that the leaving ability of the NH(2) group far surpasses that of Cl under these conditions. An essential feature of S(N)Ar reactions of nitroanilines is probably that the NH(2) leaving group participates in a hydrogen-bonding interaction with H(2)O. Density functional theory (DFT) calculations for a set of 4-nitroaniline, OH(-), and H(2)O suggest a possible formation of a Meisenheimer complex stabilized by hydrogen-bonding interactions and a six-membered ring structure. The results obtained here contrast with conventional S(N)Ar reactivity profiles in which nitroanilines are nearly unreactive with nucleophiles in organic solvents. 相似文献
44.
45.
46.
Kouichi Tsuji Tetsuya Emoto Yosuke Nishida Eiichiro Tamaki Yoshikuni Kikutani Akihide Hibara Takehiko Kitamori 《Analytical sciences》2005,21(7):799-803
Grazing-exit x-ray fluorescence (GE-XRF) and micro x-ray fluorescence (micro-XRF) methods were applied to chemical microchips as a detection method. Since an energy-dispersive x-ray detector was used, the simultaneous detection of multiple elements was possible. An analyzing region was especially designed on the microchip so that a sample solution could be dried and concentrated in a suitable area corresponding to the size of the primary x-ray beam. Finally, it was confirmed that both analytical methods could be combined well for use with a microchip. In GE-XRF, the background intensity in the XRF spectrum was reduced at grazing-exit angles. In addition, a good relationship between the x-ray fluorescence intensities and the concentrations of standard solutions that were introduced into the microchip was obtained. This indicates that the GE-XRF method is feasible for trace elemental analysis in chemical microchip systems. In micro-XRF, an attempt was made to concentrate and dry the analyte within a small analyzing region. The preliminary results indicated that the micro-XRF method could be applied for the analysis of microchips. 相似文献
47.
Thermoelectric powers of Fe, Ni and Co dissolved in liquid Sn are measured and discussed in relation to resistivity and susceptibility by reference to the concept of virtual bound state. 相似文献
48.
Neutron scattering measurements have been made of phonons in a Fe65Ni35 crystal at several temperatures. Marked softening of the [110] acoustic shear modes and a dip in the dispersion relation are found at low temperatures. Above the magnetic ordering temperature Tc, the frequency shift is removed completely, which suggests phonon perturbation by magnetoelastic coupling. 相似文献
49.
50.
The phase diagram and the heat of transition of AgI-AgBr system have been determined by using the differential scanning calorimetry (DSC) with the help of X-ray diffraction patterns. It has been verified that the miscibility gap between β-AgI-type solid solution and AgBr-type one depends on the thermal history of the sample. From the thermodynamic point of view, it is likely that the variation of transition temperature with composition suggests the change of correlation among silver ions in superionic conducting phase. 相似文献