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991.
992.
Y. Ono M.A.H. Khalafalla K. Takashina S. Horiguchi Y. Takahashi 《Applied Surface Science》2008,254(19):6252-6256
We investigate the hole transport in p-channel field-effect transistors doped with boron, at low temperatures (6-28 K). In transistors with a relatively large dimension, we observe the acceptor-mediated hopping and carrier freezeout, both of which are strongly influenced by the gate bias. In nanoscale transistors, these features turn into single-charge tunneling, i.e., the trapping/detrapping of single holes by/from individual acceptors. The statistics of the appearance of the modulation in a few ten samples indicates that the number of acceptors is small, or even just one, indicating that what we have observed is single-charge-transistor operation by a single-acceptor quantum dot. 相似文献
993.
Aldehydes reacted with zirconacyclopentane derivatives via insertion into the Zr‐sp3C bond to afford the corresponding 7‐membered zirconacycles. 相似文献
994.
Reductive energy from visible light-responsive Au–TiO2 photocatalyst, which is based on plasmon resonance absorption of Au nanoparticles, can be stored in WO3 as a reductive energy storage material. About 60% of the charge stored in WO3 is consumed on the WO3 and the other 40% is on the Au–TiO2 by reduction of ambient O2. Electrochemically pretreated MoO3 can also be used as an energy storage material. 相似文献
995.
V.F. Tarasov I.S.M. Saiful Y. Ohba K. Takahashi S. Yamauchi 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(5):1327
EPR spectra of the excited quartet and doublet molecular states of (tetraphenylporphinato)zinc(II)covalently bounded to 3-(N-nitronyl-notroxide) pyridine stable radical are modeled in terms of the spin-Hamiltonian given by the sum of the contributions from the radical and triplet moieties, and the interaction between them. The later is represented by anisotropic point dipolar and isotropic exchange electron spin–spin interactions. It is shown that the high field (W-band) EPR spectra depend on energy separation between the electronic doublet (D) and quartet (Q) states. This dependence was utilized to estimate the upper limit of the intensity of exchange interaction between the radical and porphyrin moieties. 相似文献
996.
Fresnel zone plates (FZPs) were fabricated in order to evaluate the performance of nonadiabatic photolithography by exploiting
the localized nature of optical near fields. This novel photolithography scheme could realize FZPs with structures smaller
than the wavelength of the light source used for exposure. The FZP for 325-nm-wavelength UV light could focus the incident
light to a spot size of 590 nm. An FZP for focusing soft X-rays was also fabricated and, compared to conventional adiabatic
photolithography, showed higher-contrast zones over the whole area of the FZP. This method exhibits a high dynamic range and
good spatial resolution, and it was free from artifacts due to the interference of the residual propagating exposure light
transmitted through the aperture of the photomask. 相似文献
997.
We study the first positive eigenvalue (p)
1(g) of the Laplacian on p-forms for a connected oriented closed Riemannianmanifold (M, g) of dimension m. We show that for 2 p m – 2 a connected oriented closed manifold M admits three metrics g
i
(i = 1, 2, 3) such that (p)
1(g
1)> (0)
1(g
1),(p)
1(g
2) < (0)
1(g
2) and(p)
1(g
3)= (0)
1(g
3).Furthermore, if (M, g) admits a nontrivial parallel p-form,then (p)
1 (0)
1 always holds. 相似文献
998.
K. Suzuki M. Takahashi M. Takeda T. Kitazawa 《Journal of Radioanalytical and Nuclear Chemistry》2003,255(2):305-309
Four kinds of Dy(III) hexacyanometalates (II or III), DyFe(CN)6·4H2O (1), KDyFe(CN)6·4H2O (2), DyCo(CN)6·4H2O (3), and KDyRu(CN)6·4H2O (4) have been investigated by 161Dy Mössbauer spectroscopy. 161Dy isomer shifts of four compounds fall in the range of +3 ionic compounds. Although all spectra 1-4 show an almost symmetric line, the broadening of the line-width is observed on lowering the temperature due to the paramagnetic relaxation. As a parameter of intermolecular force constant, the M2 value obtained for 161Dy of 1 is slightly larger than that of 2. 相似文献
999.
1000.
Takayuki Ban Yutaka Ohya Yasutaka Takahashi 《Journal of Sol-Gel Science and Technology》2003,27(3):363-372
A clear alcoholic solution of titanium alkoxide with an addition of various alkanolamines is suitable for a sol-gel coating of titania films. The reaction of titanium isopropoxide, Ti(OPr
i
)4 (TIP), with alkanolamines, such as triethanolamine (TEAH3), diethanolamine (DEAH2), and N-ethyldiethanolamine (EDEAH2), and an association of the Ti species in the resultant mixtures were examined via liquid-state nuclear magnetic resonance (NMR), infrared spectroscopy (IR), and cryoscopy measurements. Regardless of the kinds of the alkanolamines used, the IR and NMR spectra showed that alcohol exchange reactions occurred between the alcoholic moieties in alkanolamines and the isopropoxy groups in TIP, and that the N atom in the alkanolamines might be datively bonded to Ti. In the DEAH2 and EDEAH2 systems with the molar ratio of amine/TIP = 1, the results of the NMR and cryoscopy measurements showed that an association degree of the formed Ti species increased with an increase in the concentration of TIP, according to the thermodynamical equilibriums of associations between various oligomers. The increase was larger in the DEAH2 system than in the EDEAH2 one, because of the larger equilibrium constants due to the smaller size of the DEA group. In the system of EDEAH2/TIP = 2, the NMR spectra showed that only one kind of oligomer was formed as a Ti species, independent of the concentration of TIP. The oligomer may be a much more stable species than other species. The cryoscopy results showed that the oligomer had a tetrameric structure. 相似文献