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41.
Sankar C Bhunia Sutanuka Pal Gopal C Patra Sudhir C Pal 《Journal of heterocyclic chemistry》2014,51(6):1679-1688
Some 6‐disubstituted, 8‐disubstituted, and/6,8‐disubstituted compounds have been prepared from coumarin, 7‐methylcoumarin, and 3,4‐benzocoumarin. The Reimer–Tiemann reaction, Lederer–Manasse reaction, bromination using molecular bromine as well as 2,4,4,6‐tetrabromocyclohex‐2,5‐dien‐1‐one, Elbs reaction, and diazocoupling have been carried under controlled conditions to obtain various derivatives. Further, several reactions of aldehyde derivatives of these coumarins have been carried on to prepare important functional compounds including some heterocycles. It is noteworthy that these aldehydes behave as phenolic aldehydes under alkaline conditions to undergo the Dakin reaction. The reactions are mostly carried in aqueous media involving a dianionic intermediate and hence fulfill one important criterion of green chemistry. 相似文献
42.
Sudhir K. SharmaSahaj Gupta Mohammad SaifuddinAnil K. Mandadapu Piyush K. AgarwalHarsh M. Gauniyal Bijoy Kundu 《Tetrahedron letters》2011,52(1):65-68
Two simple, highly efficient three component tandem reactions for the synthesis of diversified NaNb di-carbamate-4,9-dihydro-3-iodo-α-carbolines and Na-carbamate-3-iodo-α-carbolines have been described. The strategy involves one-pot condensation of bis-carbamate protected 2-amino indoles with disubstituted propargyl alcohols and I2/ICl. The salient feature of the reaction involves iodocyclo-elimination of Nb-linked carbamate under mild condition in the final step. 相似文献
43.
Sudhir Kumar PandeyKi-Hyun Kim 《Trends in analytical chemistry : TRAC》2011,30(6):899-917
This review critically evaluates the measurement methodologies most commonly employed for the analysis of the various forms of mercury (Hg) in air. Emphasis is given to the three most common forms of mercury in air [i.e. gaseous elemental mercury (GEM, Hg0), reactive gaseous mercury (RGM), and particle-bound mercury (Hgp)]. Moreover, we also briefly describe methods dealing with gas-phase analysis of organic mercury species (e.g., mostly methyl mercury), as they are also reported to be present in air on rare occasions. To begin with, we describe the approaches to sampling airborne mercury species and associated sample-treatment strategies. We evaluate both conventional and emerging alternative detection techniques for different mercury forms with respect to their applicability in airborne mercury analysis. We also discuss the artifacts and the biases associated with analysis of different mercury species. Finally, the review summarizes current methodological developments for the determination of mercury in air and highlights future prospects for improvements. 相似文献
44.
The synthesis and characterization of water-soluble dispersions of Ag nanoparticles by the reduction of AgNO(3) using tryptophan under alkaline synthesis conditions are reported. The Ag nanoparticle formation was very slow at low concentration and rapid at extremes. For surface modification and redox reactions, manipulating the interparticles interaction controlled the size of Ag nanoparticles aggregates. Our results suggest that the replacement of the BH(4)(-) ions adsorbed on the nanoparticle surface by tryptophan destabilizes the particles and further caused aggregation. A mechanism is proposed for the formation of silver nanoparticles by tryptophan. The experimental results are supported by theoretical calculations. The Ag nanoparticles were characterized by UV-vis absorption, dynamic light scattering and transmission electron microscopy techniques. 相似文献
45.
We have studied the valence and electronic properties of Mn doped SrRuO3 using electrical transport measurement, X-ray photoelectron spectroscopy (XPS) and local (spin) density approximation plus Coulomb interaction strength calculation (LSDA+U). The resistivity data revealed that the system undergoes transition from metal to insulator at the critical Mn doping level, x∼0.2, which is accompanied by the structural transition from orthorhombic to tetragonal crystal symmetry. Besides, the significant reduction of the spectral weight at the coherent zone (0.8 eV) of the valence band is observed for x>0.2. The core XPS spectra suggest that both the transition elements exist in the mixed ionic pair, Ru+4/Ru+5↔Mn+3/Mn+4. The detail analysis of the results suggests that the Coulomb correlation effect in conjugation with localization of the charge carriers predominate over the mixed ionic pair effect and responsible for the metal-insulator transition in the series. 相似文献
46.
Wacker SA Kashyap S Li X Kapoor TM 《Journal of the American Chemical Society》2011,133(32):12386-12389
It is difficult to determine a chemical inhibitor's binding site in multiprotein mixtures, particularly when high-resolution structural studies are not straightforward. Building upon previous research involving photo-cross-linking and the use of mixtures of stable isotopes, we report a method, Stable Isotope Labeled Inhibitors for Cross-linking (SILIC), for mapping a small molecule inhibitor's binding site in its target protein. In SILIC, structure-activity relationship data is used to design inhibitor analogues that incorporate a photo-cross-linking group along with either natural or 'heavy' stable isotopes. An equimolar mixture of these inhibitor analogues is cross-linked to the target protein to yield a robust signature for identifying inhibitor-modified peptide fragments in complex mass spectrometry data. As a proof of concept, we applied this approach to an ATP-competitive inhibitor of kinesin-5, a widely conserved motor protein required for cell division and an anticancer drug target. This analysis, along with mutagenesis studies, suggests that the inhibitor binds at an allosteric site in the motor protein. 相似文献
47.
48.
A perturbation theory of polar hard Gaussian overlap fluid mixture is discussed. Explicit analytic expressions for the second
and third varial coefficients are given. Numerical results are estimated for the thermodynamic properties of quadrupolar hard
Gaussian overlap fluid and fluid mixture. It is found that the excess free energy and internal energy depend on concentrationsc
1,c
2, molecular diameter ratioR, shape parameterK and the quadrupole momentsQ*1,Q*2. 相似文献
49.
Kirti Patel Sudhir Kapoor D. P. Dave Tulsi Mukherjee 《Journal of Chemical Sciences》2005,117(1):53-60
Silver nanosized crystallites have been synthesized in aqueous and polyols viz., ethylene glycol and glycerol, using a microwave
technique. Dispersions of colloidal silver have been prepared by the reduction of silver nitrate both in the presence and
absence of stabilizer poly(vinylpyrolidone) (PVP). It was observed that PVP is capable of complexing and stabilizing Ag nanoparticles
formed through the reduction of Ag+ ions in water and ethylene glycol. In the case of ethylene glycol, it has been shown that the use of PVP leads to particles
with a high degree of stability. The colloids are stable in glycerol for months even in the absence of stabilizer. 相似文献
50.
H. S. Dang D. D. Jaiswal K. B. S. Murthy R. C. Sharma P. P. V. J. Nambiar C. M. Sunta 《Journal of Radioanalytical and Nuclear Chemistry》1992,156(1):55-64
This paper compares the urinary excretion levels of Th obtained in bio-assay monitoring using the neutron activation technique with those predicted by applying the ICRP metabolic model to the measured Th activity in chest and total body of a group of Thorium plant workers. The results indicated much lower urinary Th excretion as compared to what was expected on the basis of the ICRP model. Lower urinary excretion in occupational subjects is explained in terms of negligible contribution of skeleton and soft tissue to the activity excreted in urine. It is suggested that the existing model should be modified to enable it to be applicable to the bio-assay monitoring of occupational workers. 相似文献