Surface plasmon amplification by stimulated emission of radiation: quantum generation of coherent surface plasmons in nanosystems

We make a step towards quantum nanoplasmonics: surface plasmon fields of a nanosystem are quantized and their stimulated emission is considered. We introduce a quantum generator for surface plasmon quanta and consider the phenomenon of surface plasmon amplification by stimulated emission of radiation (spaser). Spaser generates temporally coherent high-intensity fields of selected surface plasmon modes that can be strongly localized on the nanoscale, including dark modes that do not couple to far-zone electromagnetic fields. Applications and related phenomena are discussed.     

One-pot synthesis of chiral nonracemic amines

One-pot five-component reactions of oxathiazolidine-S-oxides with mesitylmagnesium bromide, lithium bis(trimethylsilyl)amide, aldehydes and Grignard reagents afford chiral nonracemic amines or sulfinamides in good yields and high stereoselectivities.