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This paper proves a strong convergence theorem for sequences of pseudo-holomorphic maps from a Riemann surface to a symplectic
manifoldN with tamed almost complex structure. (These are the objects used by Gromov to define his symplectic invariants.) The paper
begins by developing some analytic facts about such maps, including a simple new isoperimetric inequality and a new removable
singularity theorem.
The main technique is a general procedure for renormalizing sequences of maps to obtain “bubbles on bubbles.” This is a significant
step beyond the standard renormalization procedure of Sacks and Uhlenbeck. The renormalized maps give rise to a sequence of
maps from a “bubble tree”—a map from a wedge Σ V S2 V S2 V ... →N. The main result is that the images of these renormalized maps converge in L1,2 ∪C° to the image of a limiting pseudo-holomorphic map from the bubble tree. This implies several important properties of the
bubble tree. In particular, the images of consecutive bubbles in the bubble tree intersect, and if a sequence of maps represents
a homology class then the limiting map represents this class. 相似文献
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Non-steady-state kinetic studies reveal that the elimination of HBr from 2-(p-nitrophenyl)ethyl bromide in alcohol/alkoxide media, the classical concerted E2 reaction, actually takes place by a two-step mechanism involving the intermediate formation of the carbanion. 相似文献
78.
Tellurium and selenium can be sorbed from hydrochloric acid and hydrobromic acid solution by both polyether and polyester-based polyurethane foam. Although some acid is needed, the substitution of sodium chloride or sodium bromide increases the extraction significantly. Tellurium is extracted rapidly with > 99% sorbed in 2 min from 1.0/5.0M and 2.0/4.0M hydrochloric acid/sodium bromide. Selenium can also be sorbed quantitatively but much more slowly so that a separation is possible based on the relative rates of extraction. The capacity of polyether foam is 3% by weight of tellurium. 相似文献
79.
Naphthoquinone , a fully functionalized model for intermediates in ansamycin synthesis, was prepared by the intramolecular Claisen condensation of benzofuran followed by oxidation of the novel tricyclic compound . 相似文献
80.
Chatterjee B Noveron JC Resendiz MJ Liu J Yamamoto T Parker D Cinke M Nguyen CV Arif AM Stang PJ 《Journal of the American Chemical Society》2004,126(34):10645-10656
The syntheses, structures, and N2 adsorption properties of six new supramolecular metallacycles are reported. Flexible ditopic linkers, 1-4, with systematically varied lengths and conformational degrees of freedom were synthesized utilizing ester linkages. They were used in combination with (dppp)M(OTf)2, where M = Pt(II) and Pd(II), and cis-(Me3P)2Pt(OTf)2 to form flexible supramolecular metallacycles 5-10 in 88-98% isolated yields. Their structures were characterized via multinuclear NMR and X-ray crystallography. The metallacycles stack to form porous structures in the crystalline state. The pore dimensions depend on both the phosphorus ligands attached to the metals and the flexible linkers. Adsorption studies on the porous materials show that 5a, 6, 8, and 9 held 11.7, 16.5, 5.7, and 6.8 cm3/g STP of N2 at 77 K, respectively. A guest-exchange study with nitromethane and toluene reveals that the nanopore in 5 is flexible, a property which was transferred from the linker to the supramolecular structure in the solid state. 相似文献