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671.
672.
This is the second part of a quantum chemical investigation on the reaction between boron trichloride and ammonia. In part I [9] we focused on the energetic course of successive chlorine substitutions which are relevant for the chemical vapor deposition of BN. In this work we analyze in detail the vibrational spectra of reaction products accessible at room temperature. Regarding an experimental IR spectrum of the condensation product of the reaction between BCl3 and NH3 [10], there are more signals than expected for monomeric aminodichloroborane. Since this molecule shows the tendency to oligomerize, we have studied whether the presence of aminodichloroborane dimers or trimers or an impurity of the ammonia boron trichloride complex – an intermediate from which aminodichloroborane is formed – can explain the shape of the measured spectrum. To this end we have calculated the vibrational frequencies of monomeric, dimeric, and trimeric BCl2NH2, H3N · BCl3, and several van der Waals complexes at the level of a Møller‐Plesset second order perturbation theory. For the verification of the methodology, the vibrational frequencies of the dimethylaminodichloroborane molecule have been determined, in good accord with experimental gas phase spectra. Also the solid state spectrum of H3N · BCl3 is well reproduced by the computed vibrational spectrum of the monomeric adduct and a hydrogen‐bonded aggregate. Our studies concerning the spectrum of the condensation product of the reaction of boron trichloride with ammonia indicate that the substance investigated by Kwon and McGee had contained, besides monomeric aminodichloroborane, also its trimer and ammonia boron trichloride. 相似文献
673.
Noemí Andrade-Lpez Armando Ariza-Castolo Rosalinda Contreras Amrica Vzquez-Olmos Norh Barba Behrens Hugo Tlahuext 《Heteroatom Chemistry》1997,8(5):397-410
The structure, dynamic behavior, protonation, methylation, and coordination sites of 2-guanidinobenzimidazole 1a were investigated. Structures of compounds [2-guanidinium-1,3,10-trihydrobenzimidazole]sulfate 1b , [2-guanidinium-1,3-dihydro-benzimidazole]sulfate 1c–1d , [2-guanidinium-1,3-dihydro-benzimidazole]tetrafluoroborate 1e , [2-guanidinium-1,3-dihydro-benzimidazole]chloride 1f , [2-guanidinium-1,3-dihydro-benzimidazole] perchlorate 1g , 2-guanidino-1-methyl-benzimidazole 2a , [2-guanidinium-1,3-dimethyl-benzimidazole]iodide 2b , [2-guanidinium-1-methyl-3-hydro-benzimidazole]chloride 2c , [2-guanidinium-1,10-dihydro-benzimidazole]acetate 3 , 2-guanidino-1-hydro-3-borane-benzimidazole 4a , 2-guanidino-1-methyl-3-borane-benzimidazole 4b , (2-guanidino-benzimidazole)dimethyltin 5 , [bis(2-guanidino-10-hydro-benzimidazole)nickel(II)] 6 , and [bis(2-guanidino-1,10-dihydro-benzimidazole)zinc(II)]nitrate 7 were determined based on 1H, 13C, and 15N NMR spectroscopy. The X-ray diffraction structures of 2a, 2b, 3, 6 , and 7 were obtained. The results show that 1a has an open structure without an intramolecular hydrogen bond in DMSO or DMF. The imidazolic N-3 is the preferred basic site in solution for protonation, methylation, and coordination and not N-10 as was suggested from semiempirical calculations. Under strong acidic conditions, diprotonation occurs at N-3 and N-10. In the solid state, 3 and 6 were protonated preferently at N10 rather than at N-1. © 1997 John Wiley & Sons, Inc. Heteroatom Chem 8: 397–410, 1997 相似文献
674.
675.
Lisa Krapf Manuela Dezi Werner Reichstein Jürgen Köhler Silke Oellerich 《Colloids and surfaces. B, Biointerfaces》2011,82(1):25-32
We present a detailed AFM study on multilayered dry lipid films prepared from aqueous vesicle suspensions. Different preparation techniques were applied in order to optimize the preparation of homogeneous lipid films of various film thicknesses. Suspensions of preformed DOPC/DPPC vesicles were adsorbed onto indium tin oxide-coated glass coverslips, a substrate also commonly employed for the formation of giant liposomes. We found that the homogeneity of the lipid films could substantially be improved when applying a spin-coating step during the film preparation. These films were much more homogeneous than those prepared by conventional drop-casting and in addition the film thickness could be controlled. When using a combination of vesicle adsorption and spin-coating the quality and thickness of the films depended crucially on the lipid concentration of the vesicle suspension, the adsorption temperature and the adsorption time. For lipid films prepared by direct spin-coating the lipid concentration and the applied spin-coating sequence were critical parameters for the quality and thickness of the deposited lipid films. 相似文献