Enhancing effects of π-hole tetrel bonds on the σ-hole interactions in complexes involving F2TO (T = Si,Ge, Sn)

Structural Chemistry - The bimolecular and termolecular complexes involving F2TO (T = Si, Ge, Sn) and XCN/BrY (X = H, Br, CH3, and PH2; Y = F, CN, OH, and H)...     

A mussel‐inspired method to fabricate a novel reduced graphene oxide/Bi12O17Cl2 composites membrane for catalytic degradation and oil/water separation

In this study, a novel dopamine modified graphene‐based photocatalytic membrane with Bi₁₂O₁₇Cl₂ inserted was fabricated to modify the commercial cellulose acetate membrane via vacuum filtration method. Results showed the reduced graphene oxide (RGO)/poly(dopamine) (PDA)/Bi₁₂O₁₇Cl₂‐CA photocatalytic composite membrane exhibited 98% removal efficiency for methylene blue (MB) within 100 minutes and 96% removal efficiency for 4‐CP within 160 minutes. Importantly, the photocatalytic composite membrane can simultaneously achieve dye degradation and oil‐water separation in only one device within a short time. And the as‐prepared membrane displayed great antifouling performance and recyclability after 10 cycles. Meanwhile, the membrane showed excellent stability in the agitated water bath or different pH conditions. In summary, the photocatalytic membrane investigated in this study opens new avenue for treatment of wastewater.     

Ion‐imprinted poly(methyl methacrylate‐vinyl pyrrolidone)/poly(vinylidene fluoride) blending membranes for selective removal of ruthenium(III) from acidic water solutions

While conventional approaches have been studied for removal of ruthenium(III) ions (Ru(III)), this work focuses on the applicability of ion‐imprinted poly(methyl methacrylate‐vinyl pyrrolidone)/poly(vinylidene fluoride) blending membranes (Ru(III)–ion‐imprinted membrane[IIM]) for selective removal of Ru(III) from acidic water solutions. In order to measure the effectiveness of these imprinted membranes, after fabrication, binding experiments were done with aqueous Ru(III) solutions. The results showed that Ru(III)‐IIMs were fabricated successfully at various blending ratios, and their chemical components, microstructures, hydrophilicity, and water fluxes were measured. In pH range 0.5 to 5.0, binding capacity (Q_e) of Ru(III) onto Ru(III)‐IIM increases remarkably with pH and then reaches to a maximum value (53.52 mg/g) at pH 1.5. After that, Q_e gradually decreases. Compared with a nonimprinted membrane, Ru(III)‐IIM demonstrates higher selectivity for Ru(III) at pH 1.5 in the presence of Ni(II) and Cu(II) ions, and its selectivity coefficients for Ru(III)/Ni(II) and Ru(III)/Cu(II) are 3.70 and 3.32, respectively. Also, Ru(III)‐IIM shows a good chemical stability and reusability. C─N and C═O bonds within poly(vinyl pyrrolidone) segments of poly(methyl methacrylate‐vinyl pyrrolidone) (P(MMA‐VP)) participate the uptake of Ru(III). Ru(III)‐IIM exhibited excellent hydrophilicity and Ru(III) selective adsorption ability and reusability and has potential to be used for Ru(III) removal from acidic water solutions.     

Hybrid Organic–Inorganic Thermoelectric Materials and Devices

Hybrid organic–inorganic materials have been considered as a new candidate in the field of thermoelectric materials since the last decade owing to their great potential to enhance the thermoelectric performance by utilizing the low thermal conductivity of organic materials and the high Seebeck coefficient, and high electrical conductivity of inorganic materials. Herein, we provide an overview of interfacial engineering in the synthesis of various organic–inorganic thermoelectric hybrid materials, along with the dimensional design for tuning their thermoelectric properties. Interfacial effects are examined in terms of nanostructures, physical properties, and chemical doping between the inorganic and organic components. Several key factors which dictate the thermoelectric efficiency and performance of various electronic devices are also discussed, such as the thermal conductivity, electric transportation, electronic band structures, and band convergence of the hybrid materials.     

A new indole-type alkaloid from the roots of Clematis florida var. plena

One new indole-type alkaloid, α-L-rhamnopyranosyl-(1→6)-β-D- glucopyranosyl 6-methoxy-3-indolecarbonate (1), together with three known alkaloids (2–4), one aromatic acid (5) and five known saponins (6–10), was isolated from the roots of Clematis florida var. plena. Their structures were established by NMR spectroscopic analysis and acid hydrolysis. In in vivo anti-inflammatory activity, n-butanol extract was found to be potent against ear edema in mice, with inhibition rate of 48.7% at a dose of 800?mg/kg. Furthermore, compounds 8 and 9 obtained from the n-butanol extract exhibited significant anti-inflammatory activities with inhibition rates of 50.9% and 54.7% at a dose of 200?mg/kg.     

Quantum anomaly at horizon and Hawking radiation from higher dimensional Reissner–Nordström–de Sitter black hole

Based on the anomaly cancellation method, initiated by Robinson and Wilczek, we investigate Hawking radiation from the event horizon and cosmological horizon of the higher dimensional Reissner–Nordström–de Sitter black hole via covariant gauge and gravitational anomalies. Unlike in black hole space-time, to describe the observable physics, the effective field theory here is constructed between the event horizon and cosmological horizon. Our result shows that to restore the underlying gauge covariance and diffeomorphism covariance at the quantum level, the covariant compensating fluxes of gauge and energy–momentum tensor, which are shown to equal to those of Hawking radiation, should be radiated from the event horizon and absorbed from the cosmological horizon, respectively.     

Quantum Anomaly and Hawking Radiation of Charged and Magnetized Reissner-Nordström de Sitter Black Hole

The recent work of Robinson and Wilczek that Hawking radiation can be determined by the compensating fluxes is extended to the charged and magnetized Reissner-Nordström de Sitter black hole. We reconstruct the electromagnetic field tensor and the Lagrangian of the field corresponding to the source with electric and magnetic charges to redefine an equivalent charge and gauge potential. We construct the effect field theory between the event horizon and cosmological horizon to respectively determine the compensating fluxes from them, which are shown to exactly equal to those of Hawking radiation, by the covariant anomaly cancellation conditions.     

A photonic wire-based directional coupler based on SOI

A photonic wire-based directional coupler based on SOI was fabricated by e-beam lithography (EBL) and the inductively coupled plasma (ICP) etching method. The size of the sub-micron waveguide is 0.34 μm × 0.34 μm, and the length in the coupling region and the separation between the two parallel waveguides are 410 and 0.8 μm, respectively. The measurement results are in good agreement with the results simulated by 3D finite-difference time-domain method. The transmission power from two output ports changed reciprocally with about 23 nm wavelength spacing between the coupled and direct ports. The extinction ratio of the device was between 5 and 10 dB, and the insertion loss of the device in the wavelength range 1520-1610 nm was between 22 and 24 dB, which included an about 18.4 ± 0.4 dB coupling loss between the taper fibers and the polished sides of the device.     

Numerical study of the effects of scatterer sizes and distributions on multiple backscattered intensity patterns of polarized light

We investigate numerically the effects of scatterer sizes on backscattered polarization patterns using the third-order scattering model developed. The calculated results show that both parallel and cross polarization patterns from water suspensions of polystyrene spheres have four-lobe structures of the azimuth dependence of intensities. Particularly, the parallel polarization pattern is sensitive to scatterer sizes, exhibiting good agreement with prior experimental measurements. Furthermore, the polarization patterns from the dysplastic and normal cells with different size distribution widths are calculated and analyzed. The results show that the polarization patterns of dysplastic and normal cells have distinct differences, which might be used for identification of the morphological structure changes of cancer, dysplasia, and regeneration cells.