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81.
Jian‐Guo Zhang Dr. Jing‐Yu Li Yan Zang Yuan‐Jie Shu Tong‐Lai Zhang Li Yang Philip P. Power 《无机化学与普通化学杂志》2010,636(6):1147-1151
The novel high nitrogen‐containing energetic complex [Cd(DAT)6](NO3)2 was synthesized by reaction of Cd(NO3)2·6H2O with 1,5‐diamino‐tetrazole (DAT). It was characterized by elemental analysis, FT‐IR spectroscopy and single‐crystal X‐ray diffraction analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three‐dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3)2 was investigated by DSC and TG/DTG analyses and FT‐IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger’s and Ozawa–Doyle’s methods. 相似文献
82.
Hiromasa Aono Dingy Wen Li Zang Damian Houde R. Blake Pepinsky David R.H. Evans 《Journal of chromatography. A》2010,1217(32):5225-5232
Protein trisulfide linkages are generated by the post-translational insertion of a sulfur atom into a disulfide bond. Molecular heterogeneity was detected in a recombinant IgG1 monoclonal antibody (mAb) and attributed to the presence of a protein trisulfide moiety. The predominant site of trisulfide modification was the bond between the heavy and light chains. The trisulfide was eliminated during purification of the IgG1 mAb via a cysteine wash step incorporated into Protein A affinity column chromatography. Analysis of the cysteine-treated mAb by electrophoresis and peptide mapping indicated that the trisulfide linkages were efficiently converted to intact disulfide bonds (13% trisulfide decreased consistently to 1% or less) without disulfide scrambling or an increase in free sulfhydryls. The on-column trisulfide conversion caused no change in protein folding detectable by hydrogen/deuterium exchange or differential scanning calorimetry. Consistent with this, binding of the mAb to its antigen in vitro was insensitive to the presence of the trisulfide modification and to its removal by the on-column cysteine treatment. Similar, high efficiency trisulfide conversion was achieved for a second IgG1 mAb using the column wash strategy (at least 7% trisulfide decreased to 1% or less). Therefore, trisulfide/disulfide heterogeneity can be eliminated from IgG1 molecules via a convenient and inexpensive procedure compatible with routine Protein A affinity capture. 相似文献
83.
B. Z. Li C. G. Sun A. F. Zang X. H. Zhang M. Zhao J. B. Wang G. Y. Jin 《Laser Physics》2011,21(6):988-990
We describe the output performances of the 1048 nm transition in Yb:YAG under in-band pumping with diode laser at the 968 nm wavelength. An end-pumped Yb:YAG crystal yielded 787 mW of continuous-wave (CW) output power for 9.1 W of absorbed pump power. Furthermore, 104 mW 524 nm green light was acquired by frequency doubling. Comparative results obtained for the pump with diode laser at 940 nm are given in order to prove the advantages of the in-band pumping. 相似文献
84.
Tu XL Xu HS Wang M Zhang YH Litvinov YA Sun Y Schatz H Zhou XH Yuan YJ Xia JW Audi G Blaum K Du CM Geng P Hu ZG Huang WX Jin SL Liu LX Liu Y Ma X Mao RS Mei B Shuai P Sun ZY Suzuki H Tang SW Wang JS Wang ST Xiao GQ Xu X Yamaguchi T Yamaguchi Y Yan XL Yang JC Ye RP Zang YD Zhao HW Zhao TC Zhang XY Zhan WL 《Physical review letters》2011,106(11):112501
Mass excesses of short-lived A=2Z-1 nuclei (63)Ge, (65)As, (67)Se, and (71)Kr have been directly measured to be -46,921(37), -46,937(85), -46,580(67), and -46,320(141) keV, respectively. The deduced proton separation energy of -90(85) keV for (65)As shows that this nucleus is only slightly proton unbound. X-ray burst model calculations with the new mass excess of (65)As suggest that the majority of the reaction flow passes through (64)Ge via proton capture, indicating that (64)Ge is not a significant rp-process waiting point. 相似文献
85.
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87.
Forsythia suspensa (Thunb.) Vahl is one of the most widely used traditional Chinese medicines, and possesses important biological activities, such as antibacterial, antiviral, anti-inflammatory and antioxidant activities. Phillyrin is the main bioactive component of Forsythia suspensa. In this paper, ultrasound-assisted extraction of phillyrin from Forsythia suspensa was studied with HPLC-photodiode array detection. Effects of several experimental parameters, such as type and concentration of extracting solvent, ratio of liquid to material, extraction temperature, and time of sonication on extraction efficiencies of phillyrin from Forsythia suspensa were evaluated. The optimal extraction conditions were 1g plant sample with 10 ml of 20% methanol and the extraction for 60 min at 60°C under ultrasonic irradiation. Under the optimum conditions, the yield of phillyrin was 0.713±0.009 mg/g. The results indicated that the ultrasound-assisted extraction is a very useful method for the extraction of important phytochemicals from plant materials. 相似文献
88.
(Na0.5K0.5)0.975Li0.025Nb0.82−xSbxTa0.18O3 lead-free piezoceramics were prepared by the conventional solid-state sintering method. All samples possess a pure perovskite phase, and no secondary phase could be certified. The crystal structure changes from tetragonal to pseudo-cubic with increasing amount of Sb. The ferroelectric Curie temperature (Tc) shifts to lower temperature while the tetragonal to orthorhombic phase transition temperature (To-t) shows no obvious change with increasing Sb5+. Enhanced piezoelectric and electromechanical properties are obtained with x=0.06: d33=352 pC/N, kp=47% and kt=38%, showing that they could be promising candidates as lead-free piezoelectric materials. 相似文献
89.
Qinqin Liu Juan YangXiaonong Cheng Xiujuan SunChuanliang Zang 《Physica B: Condensed Matter》2011,406(18):3458-3464
ZrW2O8 displays the unusual property of an isotropic bulk contraction in volume as a function of temperature. We report here on the positive thermal expansion (PTE) property caused by substituting Mo for W sites in ZrW2O8 at room temperature. The room temperature crystal structure of ZrW2−xMoxO8 compounds, which were synthesized using a low temperature route, could be divided into ordered phase with α-ZrW2O8 structure (0≤x≤0.5) and disordered phase with β-ZrW2O8 (0.5<x≤1.5) and c-ZrMo2O8 structure (1.5<x≤2). ZrW2−xMoxO8 adopting β-ZrW2O8 structure shows abnormal PTE property at room temperature due to the existence of water molecules, while ZrW2−xMoxO8 adopting the other two structures (α-ZrW2O8 and c-ZrMo2O8) shows negative thermal expansion (NTE) property from room temperature until decomposition for α-ZrW2O8 structure or trigonal phase transition for c-ZrMo2O8 structure. The reason lies in the fact that the oxygen migration caused by the Mo substitution leads to the re-arrangement of W(Mo)O4 tetrahedra lying along the 3-fold axis, only particular W/Mo ratio (0.5<x≤1.5) produces a special crystal structure, which allows the entrance of water molecules. 相似文献
90.
以超混沌Chen系统和超混沌Lorenz系统为例,研究了慢时变参数超混沌系统的反同步问题.首先利用主动控制的思想,消去超混沌系统中的非线性部分,然后基于Lyapunov稳定性理论,合理地选取参数自适应控制律,很好的解决了时变参数的参数摄动问题,从而实现了两个超混沌系统的反同步.在此基础之上,又进一步研究了分数阶超混沌系统,使用滑模控制方法对其进行控制,理论上分析了该方法的可行性.数值模拟实验进一步验证了所提出方法的有效性.
关键词:
超混沌
分数阶
自适应
滑模 相似文献