全文获取类型
收费全文 | 137394篇 |
免费 | 3837篇 |
国内免费 | 2306篇 |
专业分类
化学 | 78208篇 |
晶体学 | 1707篇 |
力学 | 5730篇 |
综合类 | 143篇 |
数学 | 13913篇 |
物理学 | 43836篇 |
出版年
2020年 | 1219篇 |
2019年 | 1175篇 |
2018年 | 1076篇 |
2016年 | 1907篇 |
2015年 | 1608篇 |
2014年 | 2112篇 |
2013年 | 5791篇 |
2012年 | 4589篇 |
2011年 | 5623篇 |
2010年 | 3635篇 |
2009年 | 3282篇 |
2008年 | 4800篇 |
2007年 | 4810篇 |
2006年 | 4804篇 |
2005年 | 4650篇 |
2004年 | 3957篇 |
2003年 | 3608篇 |
2002年 | 3537篇 |
2001年 | 3985篇 |
2000年 | 2965篇 |
1999年 | 2480篇 |
1998年 | 2141篇 |
1997年 | 2101篇 |
1996年 | 2049篇 |
1995年 | 1979篇 |
1994年 | 1741篇 |
1993年 | 1696篇 |
1992年 | 1887篇 |
1991年 | 1784篇 |
1990年 | 1691篇 |
1989年 | 1708篇 |
1988年 | 1678篇 |
1987年 | 1655篇 |
1986年 | 1554篇 |
1985年 | 2129篇 |
1984年 | 2264篇 |
1983年 | 1862篇 |
1982年 | 2179篇 |
1981年 | 1999篇 |
1980年 | 2036篇 |
1979年 | 2031篇 |
1978年 | 2152篇 |
1977年 | 2046篇 |
1976年 | 2077篇 |
1975年 | 2024篇 |
1974年 | 1859篇 |
1973年 | 2083篇 |
1972年 | 1264篇 |
1968年 | 1048篇 |
1967年 | 1101篇 |
排序方式: 共有10000条查询结果,搜索用时 515 毫秒
161.
162.
D. I. Naiduss W. W. Kiesewetter S. L. Dikanskaja J. Schapiro R. Meurice J. Cartiaux E. F. Posorski G. N. Murthy S. Mihaéloff A. D. Rich J. J. Vollertsen Gh. Ghimicescu G. Kotsis C. T. Townsend J. A. Esty F. C. Baselt R. Dubrisay J. Gascon E. R. Scheggia K. M. Renner E. S. Miller C. A. Mitchell A. G. Sossin und S. E. Spektor 《Fresenius' Journal of Analytical Chemistry》1939,118(1-2):48-51
Ohne Zusammenfassung 相似文献
163.
164.
A rigorous finite element analysis procedure is developed to study the effect of the inner structures on the acoustic absorption of multi-layer absorbers. To do this, four types of basic inner structure compartments adopted in the multi-layer absorbers are selected for analysis. These compartments are composed of porous materials inlaid with perforated plates of various shapes, say, triangle, semicircle, convex rectangle and plate shapes. As it is different from the conventional finite element analysis for the acoustic system in the literature, the perforated plates are simulated by appropriate equivalent boundary conditions, depending on their thickness, hole radius, hole pitch and porosity and the air contained in the holes. A large number of total degrees of freedom generated from meshing the air in the holes of perforated plates are thus avoided. The results reveal that the inner structures of the multi-layer absorbers will influence the acoustic absorption at some frequency bands significantly. Based on those features, the multi-layer absorber with a novel inner structure is then designed and manufactured. Both the finite element and experimental results show that its acoustic absorption would be distinctly promoted. 相似文献
165.
A. Sanusi M. Z. A. Yahya S. Navaratnam W. J. Basirun Y. Alias N. S. Mohamed A. K. Arof 《Ionics》2003,9(3-4):253-257
In this study, lead sulphide (PbS) was prepared by the chemical bath deposition technique. The sample was characterized by
X-ray diffraction (XRD), Energy Dispersive Analysis of X-rays (EDAX) and cyclic voltammetry. EDAX spectrum shows peaks attributable
to lead and sulphur. The EDAX analysis also shows that the prepared sample is stoichiometric. Cyclic voltammetry experiments
were recorded at 100 mV·s−1 and 400 mV·s−1 scan rates. Results show that the rate controlling electrochemical reaction is electron transfer. The presence of redox waves
shows that the lithium intercalation and deintercalation can occur as a result of lattice expansion in PbS. There were no
differences in the PbS XRD data before and after the cyclic voltammetry experiments indicating that the PbS structure is not
modified upon lithium ion intercalation and deintercalation in PbS. The discharge characteristics for 35 cycles of the cell
using the LiCoO2/PbS couple is presented indicating the possible development of such materials as anode in lithium ion cells. 相似文献
166.
学生的学习需求是指学生要达到的目标水平与他现在实际水平之间的差距.本课的教学目标是:了解波的形成条件及过程、波的种类、振动和波的关系;理解波的传播规律和波的图象.学生的实际是只学过振动和振动的图象,会使用《几何画板》软件.此差距很明显.这就要求教师根据建构主义学习理论,通过创设情景、搭脚手架来降低知识的梯度,真正把教学目标转化为学生自己的学习需求. 相似文献
167.
在程序升温条件下 ,用DSC研究了标题化合物的放热分解反应动力学 .用线性最小二乘法、迭代法以及二分法与最小二乘法相结合的方法 ,以积分方程、微分方程和放热速率方程拟合DSC数据 .在逻辑选择建立了微分和积分机理函数的最可几一般表达式后 ,用放热速率方程得到相应的表观活化能 (Ea)、指前因子 (A)和反应级数 (n)的值 .结果表明 :该反应的微分形式的经验动力学模式函数、Ea 和A值分别为 (1-α) 0 .44、2 30 .4kJ/mol和 10 18.16s-1.借助加热速率和所得动力学参数值 ,提出了标题化合物放热分解反应的动力学方程 .该化合物的热爆炸临界温度为 30 2 .6℃ .上述动力学参数对分析、评价标题化合物的稳定性和热变化规律十分有用 . 相似文献
168.
169.
Ohne Zusammenfassung 相似文献
170.
David S. McGuinness Edward L. Marshall Vernon C. Gibson Jonathan W. Steed 《Journal of polymer science. Part A, Polymer chemistry》2003,41(23):3798-3803
Hetero‐bimetallic Fe(II) alkoxide/aryloxides were evaluated as initiators for the ring‐opening polymerization of rac‐lactide. [(THF)NaFe(OtBu)3]2 ( 1 ) and [(THF)4Na2Fe(2,6‐diisopropylphenolate)4] ( 2 ) (THF = tetrahydrofuran) both polymerized lactide efficiently at room temperature, with complex 1 affording better control over the molecular weight parameters of the resultant polymer. At conversions below 70%, a linear increase in molecular weight with conversion was observed, indicative of a well‐controlled polymerization process. Complex 2 is the first example of a dianionic Fe(II) alkoxide and has been structurally characterized to reveal a distorted square planar FeO4 array in which both Na counterions bridge two aryloxide ligands and are further complexed by two THF ligands. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3798–3803, 2003 相似文献