全文获取类型
收费全文 | 930篇 |
免费 | 4篇 |
专业分类
化学 | 449篇 |
晶体学 | 2篇 |
力学 | 136篇 |
数学 | 63篇 |
物理学 | 284篇 |
出版年
2021年 | 16篇 |
2019年 | 19篇 |
2018年 | 28篇 |
2017年 | 36篇 |
2016年 | 27篇 |
2015年 | 18篇 |
2014年 | 29篇 |
2013年 | 44篇 |
2012年 | 32篇 |
2011年 | 48篇 |
2010年 | 34篇 |
2009年 | 21篇 |
2008年 | 36篇 |
2007年 | 30篇 |
2006年 | 39篇 |
2005年 | 26篇 |
2004年 | 24篇 |
2003年 | 26篇 |
2002年 | 27篇 |
2001年 | 18篇 |
2000年 | 14篇 |
1999年 | 13篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1995年 | 12篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1992年 | 8篇 |
1991年 | 18篇 |
1990年 | 10篇 |
1989年 | 14篇 |
1988年 | 10篇 |
1987年 | 11篇 |
1986年 | 9篇 |
1985年 | 16篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1979年 | 8篇 |
1978年 | 15篇 |
1977年 | 10篇 |
1976年 | 10篇 |
1975年 | 12篇 |
1974年 | 7篇 |
1973年 | 11篇 |
1972年 | 6篇 |
1971年 | 10篇 |
1969年 | 10篇 |
1967年 | 7篇 |
排序方式: 共有934条查询结果,搜索用时 15 毫秒
931.
Several series of polyphosphonium salts have been prepared. These include those in which the cationic sites are located at regular intervals along a linear chain of defined length (“strings”) and those in which the cationic sites are in linkages arrayed in branching arms about a central focus unit (“balloons”). Similarly, polyphosphonium balloon arrays have been attached to a polystyrene backbone providing a material that can serve as an anionic exchange resin. Several of the resultant materials have demonstrated antibacterial activity, in systems analogous to those previously reported for simple functionalized polystyrene species, and continue to be investigated. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9:495–502, 1998 相似文献
932.
J. Krill I. V. Shevchenko A. Fischer P. G. Jones R. Schmutzler 《Heteroatom Chemistry》1997,8(2):165-175
The title compound 1 was allowed to react with catechol, 2,3-dihydroxynaphthalene, tetrabromocatechol, resorcinol, saligenin, and 3,5-di-tert-butylcatechol in the presence of triethylamine to form compounds 4a–4d and 4f. Whereas the catechol derivative 4a, the naphthol derivative 4b, and the tetrabromocatechol derivative 4c could be readily obtained, the saligenin derivative 4d and the 3,5-di-tert-butylcatechol derivative 4f were found to be stable only in solution. Contrary to expectation, compound 4e was not formed in the reaction of 1 with resorcinol. The reaction of 1 with 1,2,4,5-tetrahydroxybenzene led to the pentacyclic derivative 4g. Reaction of hydroquinone with 1 led to the formation of the dimeric structure 4h. Crystal structure analyses of 4a and 4b show that the nine-membered rings adopt essentially identical “tub” conformations in which the P and O atoms are coplanar. The P-C-P angles (across the CCl2 bridge) are wide (ca. 119°). © 1997 John Wiley & Sons, Inc. 相似文献
933.
V.A. Alexandrova D.V. Ryzhkov G.V. Obukhova N.S. Domnina D.A. Topchiev E.B. K
tlyarova V.A. Shevchenko 《Macromolecular Symposia》1998,130(1):1-17
A new approach to the problem of construction of efficient antimutagenic (at γ-irradiation) systems has been developed on the basis of the models- synthetic cationic polyelectrolytes- polyquaternary salts of diallyldimethyl-ammonium type. 相似文献
934.
Dr. Sebastian Armin Schwengers Dr. Gabriela Guillermina Gerosa Dr. Tynchtyk Amatov Dr. Naoki Yasukawa Sebastian Brunen Dr. Markus Leutzsch Benjamin Mitschke Dr. Grigory André Shevchenko Prof. Dr. Dr. h.c. Benjamin List 《Angewandte Chemie (International ed. in English)》2023,62(35):e202307081
We disclose a highly regioselective, catalytic one-step dehydrogenation of α-substituted cyclic ketones in the presence of 2,3-dichlorobenzo-5,6-dicyano-1,4-benzoquinone (DDQ). The high regioselectivity originates from a phosphoric acid-catalyzed enolization, selectively affording the thermodynamically preferred enol, followed by the subsequent oxidation event. Our method provides reliable access to several α-aryl and α-alkyl substituted α,β-unsaturated ketones. 相似文献