The effect of NaCl and Na2SO4 concentration in aqueous phase on the phase inversion temperature O/W nanoemulsions

The effect of NaCl and Na₂SO₄ concentrations in aqueous phase on the phase inversion temperature (PIT) in nanoemulsions of water/Brij30/n-hexadecane system has been studied separately, and then compared. The variation of conductivity with temperature was measured by Cyber Scan PC510 conductivity meter for emulsions with 20 wt% hexadecane and 8 wt% Brij30 concentration and different concentrations of NaCl and Na₂SO₄ in aqueous phase. The results showed that with increasing concentrations of NaCl and Na₂SO₄ in aqueous phase, the PIT of nanoemulsions decreases. The effect of the elevation of concentration on the decrease of PIT was more for Na₂SO₄ in aqueous phase than NaCl with equal concentrations.     

ORGANOSOLUBLE,THERMALLY STABLE POLYAMIDES CONTAINING SULFONE AND SULFIDE UNITS

A new diamine containing sulfone,sulfide and amide groups was synthesized via a three-step reaction process. The nucleophilic substitution reaction of 4-aminothiophenol with 4-nitrobenzoyl chloride in the presence of propylene oxide (PO) afforded N-(4-mercaptophenyl)-4-nitrobenzamide(MPNB).The catalytic reduction of the nitro group in MPNB to amino group was accomplished by using Pd/C and hydrazine monohydrate to produce 4-amino-N-(4-mercapto phenyl)benzamide(AMPB).Reaction of two moles of AMPB with bis(...     

Developing electrodeposition techniques for preconcentration of ultra-traces of Ni, Cr and Pb prior to arc-atomic emission spectrometry determination

Electrodeposition is known to be proper for separation and preconcentration of extremely low concentrations of analytes from the bulk sample which is instrumentally very simple. In the present research, a combination of electrodeposition with arc atomic emission spectrometry (ED-AAES) method has been developed in order to improve the analytical performance of this spectrometry technique. The results show that sensitivity and detection limits by using ED-AAES were improved 1000–2000 folds over those of normal arc atomic emission spectrometry in determination of the selected elements. The detection limits for measurement of Ni, Cr and Pb were 2.56, 3.05 and 2.11 µg L^{− 1} for monodeposition and 3.31, 3.72 and 3.25 µg L^{− 1} for simultaneously deposition, respectively. The precision of determination was in the range of 2–4% RSD. Typical calibration graphs for these elements were linear up to 100 µg L^{− 1}, depending on the element and matrix.Application of this technique was also tested on determination of the studied elements in an electroplating plant's waste water. The accuracy of technique was verified by comparing the results of the waste water analysis with those of electrothermal atomic absorption spectroscopy as a reference standard method.The obtained results show that the combined technique (ED-AAES) has been progressed substantially toward the ultimate goal of direct interference-free determination of trace analysis in complex samples by AAES.     

A RANS simulation toward the effect of turbulence and cavitation on spray propagation and combustion characteristics

A multidimensional computational fluid dynamic code was developed and integrated with probability density function combustion model to give the detailed account of multiphase fluid flow. The vapor phase within injector domain is treated with Reynolds-averaged Navier–Stokes technique. A new parameter is proposed which is an index of plane-cut spray propagation and takes into account two parameters of spray penetration length and cone angle at the same time. It was found that spray propagation factor (SPI) tends to increase at lower r/d ratios, although the spray penetration tends to decrease. The results of SPI obtained by empirical correlation of Hay and Jones were compared with the simulation computation as a function of respective r/d ratio. Based on the results of this study, the spray distribution on plane area has proportional correlation with heat release amount, NO _x emission mass fraction, and soot concentration reduction. Higher cavitation is attributed to the sharp edge of nozzle entrance, yielding better liquid jet disintegration and smaller spray droplet that reduces soot mass fraction of late combustion process. In order to have better insight of cavitation phenomenon, turbulence magnitude in nozzle and combustion chamber was acquired and depicted along with spray velocity.     

Efficient electrocatalysis of formic acid oxidation onto Pd-Cu/poly (2-methoxyaniline)-SDS nanocomposite film

In this work, porous poly (2-methoxyaniline) film prepared in the presence of sodium dodecyl sulfate (P2MA-SDS) is used as a potent support for dispersion of bimetallic palladium-copper nanoparticles (Pd-Cu NPs) towards the electrooxidation of formic acid (HCOOH) in sulfuric acid solution. The Pd-Cu NPs are prepared through galvanic replacement reaction between Pd^II ions and Cu particles. The SEM, EDS, and electrochemical methods were used to characterize the prepared Pd-Cu NPs. The obtained results show that the Pd-Cu exhibited significantly high current density of HCOOH oxidation compared to other catalysts and utilization of Cu NPs enhances the electrocatalytic activity towards electrooxidation. The enhanced performance is related to the synergetic effect between Pd-Cu NPs and P2MA-SDS film. The effects of galvanic replacement time, potential sweep rates, and concentration of HCOOH on the catalytic activity of the electrocatalyst as well as long-term stability are investigated by the various electrochemical techniques.     

Chaplygin gas quantum universe in the presence of the cosmological constant

We present a Chaplygin gas Friedmann-Robertson-Walker quantum cosmological model in the presence of the cosmological constant. We apply the Schutz’s variational formalism to recover the notion of time, and this gives rise to Wheeler-DeWitt equation for the scale factor. We study the early and late time universes and show that the presence of the Chaplygin gas leads to an effective positive cosmological constant for the late times. This suggests the possibility of changing the sign of the effective cosmological constant during the transition from the early times to the late times. For the case of an effective negative cosmological constant for both epoches, we solve the resulting Wheeler-DeWitt equation using the Spectral Method and find the eigenvalues and eigenfunctions for positive, zero, and negative constant spatial curvatures. Then, we use the eigenfunctions in order to construct wave packets for each case and obtain the time-dependent expectation value of the scale factors, which are found to oscillate between finite maximum and minimum values. Since the expectation value of the scale factors never tend to the singular point, we have an initial indication that this model may not have singularities at the quantum level.     

Sonocatalytic oxidation of olefins catalyzed by heteropolyanion–montmorillonite nanocomposite

A Keggin-type heteropolyanion compound (HPO) was doped within the montmorillonite (MMT) structure by impregnation method. The synthesized catalyst was characterized by FT-IR, XRD, UV–vis, CV, SEM and elemental analysis. Based on chemical adsorption between HPO, and hydroxyl surface groups, HPOs nanoparticles were successfully located on the MMT. Moreover, the obtained nanocomposite was found as an efficient catalyst for oxidation of hydrocarbons under reflux and ultrasonic irradiation conditions.     

Experimental investigation on the effect of natural gas premixed ratio on combustion and emissions in an IDI engine

Journal of Thermal Analysis and Calorimetry - Usage of natural gas in an internal combustion engine that has different combustion technologies is considered a possible solution to reduce engine...     

Effect of Nickel Distributions Embedded in Amorphous Carbon Films on Transport Properties

Electrical properties of C/Ni films are studied using four mosaic targets made of pure graphite and stripes of nickel with the surface areas of 1.78,3.21,3.92 and 4.64%.The conductivity data in the temperature range of400–500 K shows the extended state conduction.The conductivity data in the temperature range of 150–300 K shows the multi-phonon hopping conduction.The Berthelot-type conduction dominates in the temperature range of 50–150 K.The conductivity of the films in the temperature range about 50 K is described in terms of variable-range hopping conduction.In low temperatures,the localized density of state around Fermi level(F)for the film deposition with 3.92% nickel has a maximum value of about 56.2×10~(17)cm~(-3)eV~(-1) with the minimum average hopping distance of about 3.43 × 10~(-6) cm.     

Gap States of ZnO Thin Films by New Methods:Optical Spectroscopy,Optical Conductivity and Optical Dispersion Energy

The optical reflectance and transmittance spectra in the wavelength range of 300–2500 nm are used to compute the absorption coefficient of zinc oxide films annealed at different post-annealing temperatures 400, 500 and 600°C.The values of the cross point between the curves of the real and imaginary parts of the optical conductivity ɑ_1 and ɑ_1 with energy axis of films exhibit values that correspond to optical gaps and are about 3.25–3.3 eV. The maxima of peaks in plots dR/dλ and dT/dλ versus wavelength of films exhibit optical gaps at about 3.12–3.25 eV.The values of the fundamental indirect band gap obtained from the Tauc model are at about 3.14–3.2 eV. It can be seen that films annealed at 600°C have the minimum indirect optical band gap at about 3.15 eV. The films annealed at 600°C have Urbach's energy minimum of 1.38 eV and hence have minimum disorder. The dispersion energy d of films annealed at 500°C has the minimum value of 43 eV.