Ionic liquids with fluorine-containing anions as a new class of functional materials: features of the synthesis,physicochemical properties,and use

Russian Chemical Bulletin - The results obtained by the authors and literature data on the methods of preparation, properties, and the use of ionic liquids with fluorine-containing anions are...     

Hilbert Boundary-Value Problem With Two-Side Curling at Infinity Point of Different Orders

Russian Mathematics - We study a boundary-value problem for a generalized biaxisymmetric Helmholtz equation. Boundary conditions in this problem depend on equation parameters. By the method of...     

Application of a cryogenic moderator in the REMUR neutron reflectometer

Examples of the application of a cryogenic moderator in the REMUR time-of-flight neutron reflectometer of the IBR-2 pulsed reactor (Dubna) are given. The results of two experiments are presented: spatial beam splitting upon reflection from a magnetically noncollinear film and the recording of a microbeam formed by a layered waveguide. A conclusion concerning the efficiency of the cryogenic moderator for experiments of this type is made.     

More efficient Brownian dynamics algorithms

We examine the relative efficiencies of three- algorithms for performing Brownian Dynamics simulations without many-body hydrodynamics. We compare the conventional Brownian Dynamics algorithm of Ermak (CBD), Smart Monte Carlo (SMC) which incorporates Boltzmann sampling into essentially a CBD procedure, and the Stochastic Runge Kutta (SRK) method. We show, using the repulsive potential φ(r) = ε(σ/r) ⁿ , where n = 36 and 72, that the SRK algorithm gives the most accurate short-time dynamics for the mean-square displacements. The SRK algorithm static and dynamical properties converge better with a reducing time step to the exact values, than those generated by the CBD algorithm; giving efficiency gains typically of a factor of 3–4. Both CBD and SMC have the incorrect sign for the first correction term to the mean square displacement in a time step, whereas the SRK algorithm gives essentially the exact solution to order Δt ², where Δt is the simulation time step. In fact, these correction terms are almost equal and opposite in sign. Expressions for these terms were derived in terms of the average interaction energy per particle. The force, shear and bulk stress autocorrelation functions were calculated. The average energy per particle and time correlation functions at short time have values in excess of the exact values, while the corresponding quantities for SRK are below this. This difference in behaviour can be traced back to the extent of compliance of the particle trajectories with the exact expansion of the Smoluchowski equation. The accuracy, at a given value of the time step, of the stochastic algorithms can significantly depend on the form of the interaction potential between particles. It is also demonstrated that the long time limits of various correlation functions are fairly insensitive to a particular scheme (SRK or CBD) used in the simulations. All the correlation functions have a stretched exponential region at intermediate to long times, and the values of the exponents on density and force law steepness have been determined.     

Characterization of partially transesterified poly(beta-hydroxyalkanoate)s using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry

Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) was used for the characterization of a partially transesterified poly(beta-hydroxyalkanoate), PHA, polymer produced by the bacterial strain Alcaligenes eutrophus using saponified vegetable oils as the sole carbon sources. The transesterification was carried out separately under acidic and basic conditions to obtain PHA oligomers weighing less than 10 kDa. The intact oligomers were detected in their cationized [M + Na](+) and [M + K](+) forms by MALDI-TOFMS. A composition analysis, using the MALDI-TOF spectra, indicate that the oligomers obtained via acid catalysis were terminated with a methyl 3-hydroxybutyrate end group, and those obtained by base catalysis had a methyl crotonate (olefinic) termination. In addition to HB (hydroxy butyrate), the oligomers were found to contain a small percentage of HV (hydroxy valerate). This was independently confirmed using gas chromatography/mass spectrometry (GC/MS). In comparison, the analysis of a commercial PHA polymer, transesterified under identical conditions, only showed the presence of HB, i.e. a pure PHB homopolymer. Copyright 1999 John Wiley & Sons, Ltd.     

Application of optoelectronic negative feedback to ordering of the temporal structure of the diode-pumped Nd:YLF laser radiation

The conditions of the generation of radiation with ordered temporal structure are determined for a solid-state laser with external negative feedback. Experiments are performed based on the Nd:YLF laser longitudinally pumped by a high-power diode array. Lasing was controlled using an intracavity electro-optic modulator based on a lithium tantalate crystal. Intensity smoothing and self-mode-locking regimes with generation of several short pulses in the axial interval are implemented by varying the delay in the feedback circuit. Under conditions of amplification above the stability boundary, the secondary electro-optic effect manifestation was detected in the lithium tantalate crystal.