全文获取类型
收费全文 | 290篇 |
免费 | 18篇 |
专业分类
化学 | 173篇 |
晶体学 | 3篇 |
力学 | 3篇 |
数学 | 70篇 |
物理学 | 59篇 |
出版年
2024年 | 2篇 |
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 11篇 |
2020年 | 6篇 |
2019年 | 13篇 |
2018年 | 7篇 |
2017年 | 20篇 |
2016年 | 19篇 |
2015年 | 13篇 |
2014年 | 12篇 |
2013年 | 28篇 |
2012年 | 20篇 |
2011年 | 17篇 |
2010年 | 14篇 |
2009年 | 13篇 |
2008年 | 13篇 |
2007年 | 14篇 |
2006年 | 20篇 |
2005年 | 2篇 |
2004年 | 3篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 1篇 |
排序方式: 共有308条查询结果,搜索用时 15 毫秒
131.
Diazotized anthranilic acid has been found to be a possible reagent for the spectrophotometric microdetermination of acetone in aqueous solution. The determination range is 10–130 μg/ml. The coefficient of variation does not usually exceed 12% for 60–130 μg of acetone but increases to 2.8% at the 10-μg level. The average relative error for five determinations ranges from ?1.5 to 2%. The molar absorptivity is 9.28 × 103 liter · mol?1 · cm?1 in the presence of starch as a surfactant. Possible reaction path mechanism has been suggested for the colored body formation. 相似文献
132.
A simple and very fast photometric method for the determination of trace levels of cerium(IV) has been developed. Use has been made of the reaction in which iron (II), on oxidation with cerium(IV), gives iron(III) which is complexed with tiron, in acidic medium, to form a stable blue color, the intensity of which is in direct proportion to the amount of cerium(IV) originally present in the sample solution. In addition, the method has a wide range of determination and reasonable sensitivity, and it avoids both temperature control and the tedious extraction step. 相似文献
133.
A simple and sensitive photometric method for the trace determination of 1-naphthylamine has been worked out. The method is based on the coupling reaction of the determinand in acidic medium with diazotized sulfisomidine, to form a purplish violet water-soluble mono azo dye that shows maximum absorption at 540 nm with a molar absorptivity of 4.47 x 10(4) l mol(-1) cm(-1). Beer's law is obeyed over the concentration range 5-70 mug of 1-naphthylamine in a final volume of 25 ml, i.e. 0.2-2.8 p.p.m. with a relative error of -0.7 to +1.7% and a relative standard deviation of 0.35-4.2%, depending on the concentration level. Moreover, the method does not require either temperature control or solvent extraction. Interferences due to foreign species have been examined. The developed method has been applied to the determination of 1-naphthylamine in river water and sea water. 相似文献
134.
Nakane T Maeda Y Ebihara H Arai Y Masuda K Takano A Ageta H Shiojima K Cai SQ Abdel-Halim OB 《Chemical & pharmaceutical bulletin》2002,50(9):1273-1275
Two new migrated hopane triterpenoids, viz. 4alpha-hydroxyfilican-3-one and fern-9(11)-en-12beta-ol, and olean-18-en-3-one and olean-12-en-3-one as the first example of oleanane compounds from Adiantum ferns were isolated along with many other known triterpenoids from Adiantum capillus-veneris of China and Egypt. Their structures were elucidated by spectroscopic analyses. 相似文献
135.
Bashir S Giannakopulos AE Derrick PJ Critchley P Bottrill A Padley HJ 《European journal of mass spectrometry (Chichester, England)》2004,10(1):109-120
In the first part of this study fragmentation patterns from a range of dextran oligomers (containing 4-20 anhydroglucose units) were compared in three different methods of analysis coupled with matrix-assisted laser desorption/ionisation (MALDI) mass spectrometry. Collision-induced-dissociation (CID), prompt in-source decay (ISD) and post-source decay (PSD) all caused cleavage of the glycosidic bonds. Both CID and to a lesser extent ISD caused further cleavage of pyranose rings of the individual sugar residues. There was very little cleavage of pyranose rings detected in the PSD spectrum. Derivatisation of the reducing end-groups of the oligodextrans with 1-phenyl-3-methyl-5-pyrazolone (PMP) restricted cleavage in the MALDI mass spectrometer to the non-reducing end, and further it enabled the saccharides to be separated by HPLC so that a single chain length could be examined as a standard. Maltoheptaose was also used as a standard. In the second part of the study prompt ISD-MALDI mass spectrometry was used to compare the fragmentation of three oligoglucans, dextran, maltodextrin and gamma cyclodextrin, that have different linkages and different secondary structure. The results showed that the degree of fragmentation correlated with the degree of freedom in the saccharide chains in solution determined by NMR. Dextran the most random conformation was fragmented most whereas there was little evidence of any fragments, not even glycosidic bond breakage from cyclodextrin, even when the laser power was increased considerably. The fragmentation pattern of maltodextrin was intermediate. The patterns of fragmentation produced by MALDI mass spectrometry, particularly where standards are available to calibrate the spectrum and the energy of the laser is controlled, can be used to predict the type of linkage present. 相似文献
136.
M. Ashraf Chaudry S. Nasir Ahmad M. Z. Iqbal Bashir Ahmad H. M. A. Karim 《Journal of Radioanalytical and Nuclear Chemistry》1993,172(2):371-385
Transport of99mTc across tri-n-butylphosphate (TBP) kerosene oil supported liquid membranes (SLM) has been studied under various conditions. Presence of dichromate ions helps avoid activity scavenging effects. Concentration increase of TBP, the complexing carrier used in the present study has a positive effect on flux (J) and permeability (P) of these ions, as up to 2.87M there is an increase in J and P values. HCl concentration in the feed solution increases J and P with their maximum values at 2.5–3.0M HCl in the feed. Above this concentration there is a decrease in flux and permeability of99mTc(VII) ions. The given ions are stripped with LiCl or NaCl solutions but more with NaOH. The optimum conditions of transport of the given ions are 2.5M HCl concentration in the feed, 2.87M TBP concentration in the membrane and 1M NaOH concentration in the strip solution. Equations have been developed to indicate the relation between flux, J, viscosity, of TBP in organic membrane phase, temperature, T, [H+], in the aqueous feed solutions and Tc ion concentration in the feed solution. Based on P, the values determined from liquid membrane experiments, the quantitative flux values of Tc(VII) ions were also determined as a function of TBP concentration in the membranes, and HCl and Tc concentration in the feed solution using the given equations. This experimental technique provides quantitative results from trace level activity transfer experiments. 相似文献
137.
A cluster of many small holes with negative imaginary surface impedances may generate a negative refraction index
下载免费PDF全文
![点击此处可从《Mathematical Methods in the Applied Sciences》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ahmed Alsaedi Bashir Ahmad Durga Prasad Challa Mokhtar Kirane Mourad Sini 《Mathematical Methods in the Applied Sciences》2016,39(13):3607-3622
We deal with the scattering of an acoustic medium modeled by an index of refraction n varying in a bounded region Ω of and equal to unity outside Ω. This region is perforated with an extremely large number of small holes Dm's of maximum radius a, a << 1, modeled by surface impedance functions. Precisely, we are in the regime described by the number of holes of the order M:=O(aβ ? 2), the minimum distance between the holes is d ~ at, and the surface impedance functions of the form λm~λm,0a?β with β > 0 and λm,0 being constants and eventually complex numbers. Under some natural conditions on the parameters β,t, and λm,0, we characterize the equivalent medium generating approximately the same scattered waves as the original perforated acoustic medium. We give an explicit error estimate between the scattered waves generated by the perforated medium and the equivalent one, respectively, as a→0. As applications of these results, we discuss the following findings:
138.
Bashir Ahmad Ahmed Alsaedi Mokhtar Kirane 《Mathematical Methods in the Applied Sciences》2016,39(2):236-244
In this article, we prove the local existence of a unique solution to a nonlocal in time and space evolution equation with a time nonlocal nonlinearity of exponential growth. Moreover, under some suitable conditions on the initial data, it is shown that local solutions experience blow‐up. The time profile of the blowing‐up solutions is also presented. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
139.
Saidkhodzha Nematulloev Dr. Arunachalam Sagadevan Badriah Alamer Dr. Aleksander Shkurenko Dr. Renwu Huang Dr. Jun Yin Dr. Chunwei Dong Dr. Peng Yuan Dr. Khursand E. Yorov Azimet A. Karluk Dr. Wasim J. Mir Bashir E. Hasanov Dr. Mohamed Nejib Hedhili Dr. Naveen M. Halappa Prof. Dr. Mohamed Eddaoudi Prof. Dr. Omar F. Mohammed Prof. Dr. Magnus Rueping Prof. Dr. Osman M. Bakr 《Angewandte Chemie (International ed. in English)》2023,62(26):e202303572
Point defects in nanoparticles have long been hypothesized to play an important role in governing the particle's electronic structure and physicochemical properties. However, single point defects in material systems usually exist with other heterogeneities, obscuring the chemical role of the effects. Herein, we report the synthesis of novel atomically precise, copper hydride nanoclusters (NCs), [Cu28H10(C7H7S)18(TPP)3] ( Cu28 ; TPP: triphenylphosphine; C7H7S: o-thiocresol) with a defined defect in the gram scale via a one-pot reduction method. The Cu28 acts as a highly selective catalyst for C−C cross-couplings. The work highlights the potential of defective NCs as model systems for investigating individual defects, correlating defects with physiochemical properties, and rationally designing new nanoparticle catalysts. 相似文献
140.
Park K Jang J Irimia D Sturgis J Lee J Robinson JP Toner M Bashir R 《Lab on a chip》2008,8(7):1034-1041
The size of a cell is a fundamental physiological property and is closely regulated by various environmental and genetic factors. Optical or confocal microscopy can be used to measure the dimensions of adherent cells, and Coulter counter or flow cytometry (forward scattering light intensity) can be used to estimate the volume of single cells in a flow. Although these methods could be used to obtain the mass of single live cells, no method suitable for directly measuring the mass of single adherent cells without detaching them from the surface is currently available. We report the design, fabrication, and testing of 'living cantilever arrays', an approach to measure the mass of single adherent live cells in fluid using silicon cantilever mass sensor. HeLa cells were injected into microfluidic channels with a linear array of functionalized silicon cantilevers and the cells were subsequently captured on the cantilevers with positive dielectrophoresis. The captured cells were then cultured on the cantilevers in a microfluidic environment and the resonant frequencies of the cantilevers were measured. The mass of a single HeLa cell was extracted from the resonance frequency shift of the cantilever and was found to be close to the mass value calculated from the cell density from the literature and the cell volume obtained from confocal microscopy. This approach can provide a new method for mass measurement of a single adherent cell in its physiological condition in a non-invasive manner, as well as optical observations of the same cell. We believe this technology would be very valuable for single cell time-course studies of adherent live cells. 相似文献