全文获取类型
收费全文 | 2870篇 |
免费 | 104篇 |
国内免费 | 7篇 |
专业分类
化学 | 2213篇 |
晶体学 | 46篇 |
力学 | 21篇 |
数学 | 145篇 |
物理学 | 556篇 |
出版年
2023年 | 17篇 |
2022年 | 14篇 |
2021年 | 35篇 |
2020年 | 65篇 |
2019年 | 45篇 |
2018年 | 45篇 |
2017年 | 30篇 |
2016年 | 78篇 |
2015年 | 58篇 |
2014年 | 93篇 |
2013年 | 137篇 |
2012年 | 198篇 |
2011年 | 254篇 |
2010年 | 123篇 |
2009年 | 118篇 |
2008年 | 208篇 |
2007年 | 199篇 |
2006年 | 202篇 |
2005年 | 192篇 |
2004年 | 165篇 |
2003年 | 138篇 |
2002年 | 137篇 |
2001年 | 43篇 |
2000年 | 34篇 |
1999年 | 22篇 |
1998年 | 29篇 |
1997年 | 24篇 |
1996年 | 31篇 |
1995年 | 19篇 |
1994年 | 17篇 |
1993年 | 12篇 |
1992年 | 17篇 |
1991年 | 10篇 |
1990年 | 12篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1985年 | 10篇 |
1984年 | 13篇 |
1983年 | 13篇 |
1982年 | 18篇 |
1981年 | 9篇 |
1980年 | 16篇 |
1979年 | 11篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1975年 | 8篇 |
1974年 | 4篇 |
1973年 | 4篇 |
排序方式: 共有2981条查询结果,搜索用时 93 毫秒
131.
132.
Yasuhiro Igarashi Daisuke Asano Kazuo Furihata Naoya Oku Satoshi Miyanaga Hiroaki Sakurai Ikuo Saiki 《Tetrahedron letters》2012,53(6):654-656
During the course of screening natural products for the inhibitors of tumor cell invasion, pterocidin, a linear polyketide with a δ-lactone terminus, was rediscovered from a Streptomyces strain of a marine sediment-origin. A series of J-based configuration analyses and NOESY analysis, coupled with chemical derivatization and chiral anisotropy analysis, established the absolute stereochemistry of five asymmetric centers in this compound. 相似文献
133.
134.
Satoshi Someya Satoshi Yoshida Koji Okamoto Yan Rong Li Manabu Tange Mohammad Mezbah Uddin 《显形杂志》2010,13(1):41-47
Abstract
Droplets impinging on a hot surface that is near the Leidenfrost temperature were experimentally investigated. Ejection of jets from the top of the droplet was observed during the transient interaction between the droplet and a hot wall. We term this phenomenon jet ejection from droplets. When the bottom of the droplet initially impacts the hot surface, a jet is to be ejected from the top of the droplet. The jet ejection occurred only at low impact velocities and around the wetting limit temperature. It was not observed when droplets were dropped from large heights or when the surface was at a high temperature. 相似文献135.
In this paper, we give a polytopal estimate of Mirkovi?–Vilonen polytopes lying in a Demazure crystal in terms of Minkowski sums of extremal Mirkovi?–Vilonen polytopes. As an immediate consequence of this result, we provide a necessary (but not sufficient) polytopal condition for a Mirkovi?–Vilonen polytope to lie in a Demazure crystal. 相似文献
136.
137.
138.
Fujiko Iwasaki Seui Kakuma Satoshi Yoshida Shin Murata Masanori Yasui 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):515-516
Abstract The deformation electron-density distributions of 6a-thia-1,3,4,6-tetraazapentalene derivatives (I, II) and bis(phenylthio)dibenzothiophene (III) were investigated by the X-ray diffraction method. For I and II, a structure around the hypervalent S-N bonds is a trigonal bipyramid with equatorial sp2 hybrid of S-C bond and lone-pair electrons and apical polarized S-N bonds. In 111 lone-pair electron densities are observed perpendicular to the thiophene ring and the C-S-C sulfide planes. 相似文献
139.
Polymerization of acrolein(AL) in the presence of imidazole(Im) has been investigated in tetrahydrofuran or methanol below room temperature. The polymers obtained, white or pale yellow powders, were found to be composed of vinyl polymer with one Im group attached and having an aldehyde side chain, of which 70–80 mole % of the aldehyde revealed bridge structure. The number-average molecular weight (M n) of these polymers was determined to be in the range of 317 to 691. The rate of polmerization Rp was expressed by the equation, R + k[Im] [AL]2. The addition of water or dimethyl sulfoxide accelerated the polymerization reaction, while the presence of benzaldehyde or N,N'-dimethylformamide decreased Rp. The structure of addition products in the initial polymerization step was confirmed by IR and NMR spectra, and the observations of polymerization system was carried out by UV and NMR spectra. The polymerization mechanisms were discussed on the basis of these results. 相似文献
140.
Toyoji Kakuchi Toshifumi Satoh Junji Mata Satoshi Umeda Hisaho Hashimoto Kazuaki Yokota 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(3):325-336
Abstract The cyclopolymerizations of 1,2:5,6-dianhydro-3,4-di-O-pentyl-D-mannitol (1b) and 1,2:5,6-dianhydro-3,4-di-O-decyl-D-mannitol (1c) were carried out using BF3OEt2 and t-BuOK. All the resulting polymers consisted of cyclic constitutional units, i.e., the extent of cyclization was 100%. The polymer structures for the polymerization with t-BuOK were (1→6)-2,5-anhydro-3,4-di-O-pentyl-D-glucitol (2b) and (1→6)-2,5-anhydro-3,4-di-O-decyl-D-glucitol (2c), whereas those with BF3O-decyl2 comprised 2,5-anhydro-D-glucitols as major units along with other cyclic ones. These polymers were soluble in n-hexane, CHCl3, and THF, but insoluble in water, which differs from the amphiphilic solubility of (1→6)-2,5-anhydro-3,4-di-O-methyl-D-glucitol (2a). The cation-binding properties of 2b and 2c were examined using alkali-metal picrates in order to compare them with those of 2a. The extraction yields for each cation decreased in the order of 2c < 2b < 2a. Every polymer exhibited a similar cation-binding selectivity in the order Cs+ > Rb+ > K+ ? Na+ > Li+. The ratio of K+ and Na+, K+/Na+, was 4.6 for 2a, 5.1 for 2b, and 7.1 for 2c in the increasing order 2a < 2b > 2c. 相似文献