Two novel heterogeneous nickel ?-diimine based polymerization catalysts, containing MWCNT as the main ligand, were synthesized by novel in situ catalyst preparation technique. The in situ synthesis was performed by covalent attachment of the acenaphthenic ligand core to amine functionalized MWCNT ligand arms through diimine bonding and further nickel dibromide chelation. The prepared catalysts were fully characterized and their structures and supporting efficiencies were determined. Single or double introduction of the MWCNTs through their ends or sidewall(s) in the catalytic system, as a ligand, influenced the catalytic performance, microstructure and morphology of obtained polyethylenes. MWCNT sidewall bonding to para-aryl position of the tetramethylphenyl moiety performed as more electron-donating ligand than MWCNT ends linked to the imine bond and protected the catalytic system to retain its activity. This character resulted in the maintenance of the resulting polymer topology at elevated temperatures so that the catalytic activity and the obtained polymer melting points remained around 110 g PE?mmol?1 Ni?h?1 and 123 ℃ in all polymerization temperatures respectively. In polymerization trials, molecular weight fall against temperature was not as sharp as what had been observed in sequentially prepared catalysts insofar as the molecular weight of resultant polymer at 60 ℃ reached to 310000 g?mol?1 which was close to the highest value had been reported at 30 ℃ for sequentially prepared catalysts. TEM observations showed the presence of the stopped-growth polymer chains due to geometrical constrains or ligand debonding for both catalytic systems. 相似文献
Quantitative HPLC and colorimetry are used to study color variations in dyeings with indigo, 6-bromoindigo, and 6,6′-dibromoindigo, the main components of the historic dye Tyrian purple. For the first time, visible light is identified conclusively as a cause of debromination of the leuco form of 6-bromoindigo. A dyeing run using 6-bromoindigo alone is found to yield a dyed fabric containing large amounts of indigo, when the vat is exposed to visible light. The extent of debromination is dependent upon the pH of the dye bath and also the source of the visible light. This information allowed development of a dyeing procedure which is demonstrated to give consistent colors through two passes. Quantitative HPLC analysis of extracts from the dyed fabrics indicates that the leuco form of 6-bromoindigo vs. the leuco forms of indigo and 6,6′-dibromoindigo has the strongest affinity for wool fabric. This is postulated to be due to attractive electrostatic interactions between the leuco form of 6-bromoindigo and wool.
Cyclofusene is a corona-condensed benzenoid whose graph-theoretic representation consists of hexacycles with exactly two non-adjacent shared II-bonds. We showed that the number of linear chains, k, is an upper bound for m, the number of shared II-bonds. Furthermore, this upper bound is achievable. In this paper, we show that given a positive even integer m < k, there exists m shared II-bonds. In other words, the number of shared II-bonds in cyclofusene has the even interpolation property. 相似文献
N-(2-Pyridylmethyl)-2-pyrazinecarboxamide was prepared and its crystal structure was investigated by X-ray analysis. The compound
crystallizes in the triclinic space group
P[`1]P{\bar 1}
with a = 4.262(3), b = 12.117(9), c = 20.840(18) ?, α = 91.802(6), β = 89.834(7), γ = 91.845(6)°, V = 1075.2(16) ?3, Z = 4, and D = 1.323 Mg/m3. The structure was solved by direct method and refined to R = 0.0699 and wR2 = 0.1268 by full matrix anisotropic least-squares method. Using the Hartree-Fock and density functional method (B3LYP) with 6-31G(d) basis set, the molecular geometry and vibrational frequencies of the title compound has been investigated
and compared with experimental ones from experimental studies. The optimized bond lengths obtained by RHF method and bond angles obtained by B3LYP method show better agreement with the experimental values. The vibrations computed of the title compound by the RHF and DFT methods are in good agreement with the observed IR spectra data. 相似文献
N-(2-Pyridylmethyl)-2-pyrazinecarboxamide was prepared and its crystal structure was investigated by X-ray analysis. The compound crystallizes in the triclinic space group \(P{\bar 1}\) with a = 4.262(3), b = 12.117(9), c = 20.840(18) Å, α = 91.802(6), β = 89.834(7), γ = 91.845(6)°, V = 1075.2(16) Å3, Z = 4, and D = 1.323?Mg/m3. The structure was solved by direct method and refined to R = 0.0699 and wR2 = 0.1268 by full matrix anisotropic least-squares method. Using the Hartree-Fock and density functional method (B3LYP) with 6-31G(d) basis set, the molecular geometry and vibrational frequencies of the title compound has been investigated and compared with experimental ones from experimental studies. The optimized bond lengths obtained by RHF method and bond angles obtained by B3LYP method show better agreement with the experimental values. The vibrations computed of the title compound by the RHF and DFT methods are in good agreement with the observed IR spectra data. 相似文献
If a hexacyclic graph G represents a benzenoid, a perfect matching corresponds to a configuration of π-bonds. We present an algorithm for counting the number of configurations of π-bonds for parallelogram-like benzenoids with parallelogram-like holes by counting descending paths in a corresponding rectangular
mesh with rectangular holes. 相似文献
We recently reported an algorithm to count Kekulé (resonance) structures for convex cyclofusenes using a combinatorial/geometric
approach. Previously, we presented an algorithm for counting resonance structures for parallelogram-like benzenoids with holes
by counting descending paths using rectangular meshes with holes. In this article, we employ a similar combinatorial/geometric
approach to determine algorithms that will facilitate counting of the resonance structures in parallelogram-like benzenoids
with no holes. 相似文献