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741.
742.
743.
A novel and one-pot synthesis of 2-aryl/alkyl-4(3H)-quinazolinones is described. The in situ prepared amidoximes from the reaction between nitriles and hydroxylamine are condensed with anthranilic acids under solvent- and catalyst-free conditions to produce the title compounds in excellent yields. 相似文献
744.
The purpose of this paper is to study and analyze three different kinds of Mann type iterative methods for finding a common element of the solution set ?? of the split feasibility problem and the set Fix(S) of fixed points of a nonexpansive mapping S in the setting of infinite-dimensional Hilbert spaces. By combining Mann??s iterative method and the extragradient method, we first propose Mann type extragradient-like algorithm for finding an element of the set ${{{\rm Fix}}(S) \cap \Gamma}$ ; moreover, we derive the weak convergence of the proposed algorithm under appropriate conditions. Second, we combine Mann??s iterative method and the viscosity approximation method to introduce Mann type viscosity algorithm for finding an element of the ${{{\rm Fix}}(S)\cap \Gamma}$ ; moreover, we derive the strong convergence of the sequences generated by the proposed algorithm to an element of set ${{{\rm Fix}}(S) \cap \Gamma}$ under mild conditions. Finally, by combining Mann??s iterative method and the relaxed CQ method, we introduce Mann type relaxed CQ algorithm for finding an element of the set ${{{\rm Fix}}(S)\cap \Gamma}$ . We also establish a weak convergence result for the sequences generated by the proposed Mann type relaxed CQ algorithm under appropriate assumptions. 相似文献
745.
Explicit expressions are given to study the biaxial buckling of monolayer graphene sheets. Based upon the continuum mechanics, a plate model is adopted in which the small length scale effect is incorporated into the governing equation through the nonlocal elasticity theory of Eringen. By employing the Galerkin method, analytical expressions are derived which allow quick and accurate calculation of the critical buckling loads of monolayer graphene sheets with various boundary conditions from the static deflection under a uniformly distributed load. The effectiveness of the present study is assessed by molecular dynamics simulations as a benchmark of good accuracy. 相似文献
746.
Al Ansari S. V. Aksenova N. V. Popova T. V. 《Russian Journal of Coordination Chemistry》2001,27(3):172-174
Complexation in the Co(II)–H6X–H2O, Ni(II)–H6X–H2O, and Co(II)–Ni(II)–H6X–H2O systems (H6X is nitrilotrimethylenephosphonic acid) was studied by spectrophotometry. The formation of binuclear complexonates Ni2H2X · 7H2O, Co2H2X · 5H2O, and NiCoH2X · 6H2O was demonstrated. These compounds were isolated from the solution, their composition was determined, the thermal stability was studied, and the kinetic parameters of dehydration were calculated. 相似文献
747.
748.
749.
Mary Jo Turk Asif S. Ansari William B. Alston Gloria S. Gahn Aryeh A. Frimer Daniel A. Scheiman 《Journal of polymer science. Part A, Polymer chemistry》1999,37(21):3943-3956
Thermogravimetric analysis (TGA) has been used for many years to evaluate polymer thermal stability. The objective of this study is to determine if weight-loss curves from TGA and isothermal TGA (IGA) can be used to determine degradation activation energies and thus rank the thermal stability (TS) and thermooxidative stability (TOS) for selected polyimides. Two high-temperature stable addition-cured polyimides and two aromatic condensation polyimides, all four containing fluorinated connecting linkages in the dianhydride monomers, were compared. Three TGA kinetic methods (Coats/Redfern, Ingraham/Marier, Horowitz/Metzger) were used to determine the activation energy for decomposition in air. The results were then used to rank polyimide stability compared to more traditional rankings based on long-term isothermal air aging weight-loss (IWL) studies and thermal decomposition temperatures (Td) from TGA data. Use of TGA coupled to a Fourier transform infrared (TGA–FTIR) spectrophotometer allowed for the simultaneous identification and relative quantification of evolved decomposition products (CO2, CO, ArNCO, and CHF3) of the four polyimides degraded in air or nitrogen. Isothermal TGA–FTIR (IGA–FTIR) was also done in air to determine the relative rate of product evolution at a constant temperature. Activation energies using TGA and IGA data were determined and then compared with IWL values for the degradation of the polyimide to examine for correlations of real-life thermal oxidative aging to accelerated aging techniques. The Coats/Redfern method and Td were found to best reproduce stability rankings of those from long-term, high-temperature IWL studies. Together, they may provide a time-saving technique to evaluate polyimide thermal oxidative stability. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3943–3956, 1999 相似文献
750.
Photolysis of [Mo(CN)8]4− in the presence of diethylenetriamine (dien) leads to the complexation of ligand via hydrogen in the stoichiometry 2:1. The mechanism of the complexation was investigated by spectroscopy absorption and the rate constants and the quantum yield determined. Rate constants and quantum yields for the formation of the final products were found to depend on pH, ligand, and metal cyanide concentration. The values are a maximum at pH 7.4. At pH >7.4 the reverse reaction, generating octacyanomolybdate complex from the heptacyano species, is faster. At low pH, the ligand is protonated and less reactive; hence, the rate of reaction and quantum yield values decrease. The ionic strength does not affect the reaction rate, implying an associative mechanism for the photochemical reaction with dien, supported by the rate law. The observed rate law is: © 1999 John Wiley & Sons, Inc. J Chem Kinet 31: 89–93, 1999 相似文献