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41.
L. V. T. Nguyen M. J. L. Cahill A. J. Lowery D. Novak P. C. R. Gurney D. D. Sampson Dong-Sun Seo 《Optical and Quantum Electronics》1996,28(8):1067-1080
The physical mechanism attributed to producing rabbit-ears on the chirped multimode optical spectra of gain-switched Fabry-Pérot semiconductor lasers is investigated thoroughly. It has been observed experimentally that the short-wavelength rabbit-ears are dominant in the short-wavelength longitudinal modes. However, the long-wavelength rabbit-ears are dominant in the modes near the lasing wavelength, while the short-wavelength rabbit-ears are again dominant in the longest-wavelength modes. In this paper, the unequal rabbit-ears of each mode and the asymmetric chirped spectrum are shown to be a result of the dynamic power transfer between the modes during the gain-switched optical pulse due to carrier-induced modal intermodulation. Such an understanding, and the ability to model accurately this characteristic, is also shown to be essential for designing Fabry-Pérot laser systems, for short-haul applications such as fibre-to-the-home. 相似文献
42.
P. J. Kershaw K. E. Sampson W. McCarthy R. D. Scott 《Journal of Radioanalytical and Nuclear Chemistry》1995,198(1):113-124
Samples from sediment cores, collected from a site close to the Sellafield outfall and dated using conventional - and -spectrometry, have been analysed using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Thermal Ionisation Mass Spectrometry (TIMS). This has provided information on the isotopic composition of plutonium in the liquid discharges from Sellafield; such information is not available using conventional -spectrometry alone. There was very good agreement between the240Pu/239Pu ratios obtained by the two MS methods. More recent discharges have been characterised by a progressive decrease in the relative proportion of239Pu. 相似文献
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Sampson JS Hawkridge AM Muddiman DC 《Journal of the American Society for Mass Spectrometry》2006,17(12):1712-1716
We report the coupling of a hybrid ionization source, matrix-assisted laser desorption electrospray ionization (MALDESI), to a Fourier transform-ion cyclotron resonance mass spectrometer (FT-ICR MS). The details of the source design and initial data are presented. Analysis of peptides and proteins ranging from 1 to 8.6 kDa resulted in high resolving power single-acquisition FT-ICR mass spectra with average charge-states highly correlated to those obtained by nanoESI, thus, providing strong evidence that the ESI process dictates the observed charge-state distribution. Importantly, unlike the recently introduced electrospray assisted laser desorption ionization (ELDI) source reported by Shiea and coworkers [1, 2], the data we have obtained to date rely on the use of an organic acid matrix. The results presented herein provide insight into the charging mechanism of this emerging ionization approach, while also expanding the utility of FT-ICR MS for top-down protein and complex mixture analysis. 相似文献
47.
We report a new synthetic aperture optical microscopy in which high-resolution, wide-field amplitude and phase images are synthesized from a set of Fourier holograms. Each hologram records a region of the complex two-dimensional spatial frequency spectrum of an object, determined by the illumination field's spatial and spectral properties and the collection angle and solid angle. We demonstrate synthetic microscopic imaging in which spatial frequencies that are well outside the modulation transfer function of the collection optical system are recorded while maintaining the long working distance and wide field of view. 相似文献
48.
From the known statistics of fiber-fiber contacts in random fiber networks, an analytic estimate is obtained for the variance of local porosity in random fiber suspensions and evolving filtrate networks. The variance of local porosity, and hence the distribution of projected areal density, seem to depend on fiber geometry only through the cube of mean diameter. Also, the coefficient of variation of local flow rate perpendicular to the plane of the pad is, to a first approximation, independent of the mode of flow. Analytic estimates are obtained also for the effect of fiber clumping on the variance of local porosity of pads for small inspection zones. 相似文献
49.
The translational energy release distribution for dissociation of benzene-Ar has been measured and, in combination with the 6(1)(0) rotational contour of the benzene product observed in emission, used to determine the rotational J,K distribution of 0(0) benzene products formed during dissociation from 6(1). Significant angular momentum is transferred to benzene on dissociation. The 0(0) rotational distribution peaks at J=31 and is skewed to low K:Javerage=27, (K)average=10.3. The average angle between the total angular momentum vector and the unique rotational axis is determined to be 68 degrees. This indicates that benzene is formed tumbling about in-plane axes rather than in a frisbeelike motion, consistent with Ar "pushing off" benzene from an off-center position above or below the plane. The J distribution is very well reproduced by angular momentum model calculations based on an equivalent rotor approach [A. J. McCaffery, M. A. Osborne, R. J. Marsh, W. D. Lawrance, and E. R. Waclawik, J. Chem. Phys. 121, 1694 (2004)], indicating that angular momentum constraints control the partitioning of energy between translation and rotation. Calculations for p-difluorobenzene-Ar suggest that the equivalent rotor model can provide a reasonable prediction of both J and K distributions in prolate (or near prolate) tops when dissociation leads to excitation about the unique, in-plane axis. Calculations for s-tetrazine-Ar require a small maximum impact parameter to reproduce the comparatively low J values seen for the s-tetrazine product. The three sets of calculations show that the maximum impact parameter is not necessarily equal to the bond length of the equivalent rotor and must be treated as a variable parameter. The success of the equivalent rotor calculations argues that angular momentum constraints control the partitioning between rotation and translation of the products. 相似文献
50.
Sieber F Daziano JP Günther WH Krieg M Miyagi K Sampson RW Ostrowski MD Anderson GS Tsujino I Bula RJ 《Phosphorus, sulfur, and silicon and the related elements》2005,180(3-4):647-657
Elemental selenium generated by the photobleaching of selenomerocyanine dyes forms conjugates with serum albumin and serum lipoproteins that are toxic to leukemia and selected solid tumor cells but well tolerated by normal CD34-positive hematopoietic stem and progenitor cells. Serum albumin and lipoproteins act as Trojan horses that deliver the cytotoxic entity (elemental selenium) to tumor cells as part of a physiological process. They exploit the fact that many tumors have an increased demand for albumin and/or low-density lipoprotein. Se(0)-protein conjugates are more toxic than selenium dioxide, sodium selenite, selenomethionine, or selenocystine. They are only minimally affected by drug resistance mechanism, and they potentiate the cytotoxic effect of ionizing radiation and several standard chemotherapeutic agents. The cytotoxic mechanism of Se(0)-protein conjugates is not yet fully understood. Currently available data are consistent with the notion that Se(0)-protein conjugates act as air oxidation catalysts that cause a rapid depletion of intracellular glutathione and induce apoptosis. Drugs modeled after our Se(0)-protein conjugates may prove useful for the local and/or systemic therapy of cancer. 相似文献