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51.
Gesquiere A Abdel-Mottaleb MM De Feyter S De Schryver FC Sieffert M Mullen K Calderone A Lazzaroni R Bredas JL 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(20):3739-3746
Monolayers of isophthalic acid derivatives at the liquid/solid interface have been studied with scanning tunneling microscopy (STM). We have investigated the dynamics related to the phenomenon of solvent co-deposition, which was previously observed by our research group when using octan-1-ol or undecan-1-ol as solvents for 5-alkoxy-isophthalic acid derivatives. This solvent co-deposition has now been visualized in real-time (two frames per second) for the first time. Dynamics of individual molecules were investigated in mixtures of semi-fluorinated molecules with video-STM. The specific contrast arising from fluorine atoms in STM images allows us to use this functionality as a probe to analyze the data obtained for the mixtures under investigation. Upon imaging the same region of a monolayer for a period of time we observed that non-fluorinated molecules progressively substitute the fluorinated molecules. These findings illustrate the metastable equilibrium that exists at the liquid/solid interface, between the physisorbed molecules and the supernatant solution. 相似文献
52.
Latterini L Pourtois G Moucheron C Lazzaroni R Bredas JL Kirsch-De Mesmaeker A De Schryver FC 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(8):1331-1336
Scanning tunneling microscopy (STM) and molecular mechanics calculations were used to investigate the long-range packing and the structure of an heptanuclear ruthenium (II) dendritic species, as a PF6- salt. STM imaging was carried out on a mono-add layer of the ruthenium dendrimer formed by physisorption from a 1,2,4-trichlorobenzene solution at the liquid-graphite interface. The packing of the molecules on the surface was visualised by the formation of ordered patterns and a distance of 27 +/- 2 A was measured between two adjacent lamellae. The comparison of this dimension with the molecular-modelling data indicates that the lamellae were formed by rows of dendrimer molecules in which the counterions (PF6-) were strongly associated with the Ru atoms. The images acquired with higher spatial resolution revealed the presence of repeating units within the lamellae. The comparison of the STM images with the modelling results allowed the attribution of the repeating units observed in the imaged pattern to the STM signature of single dendrimer molecules. 相似文献
53.
Crystal field parameter have been determined from EPR spectra (77K) of LiNbO3Fe(III). Anomalous line shapes are described phenomenologically and saturation studies are compared with calculations using a second order dynamic spin-hamiltonian H. Mössbauer spectra of LiNbO3Fe(III) have been interpreted by means of simulations using Liouville superoperators including a static fine-and a hyperfine spin-hamiltonian and H. Calculations have been performed using an effective spin of 1/2, the supermatrix with dimension 288 and a reduced formalism (supermatrix with dimension 96). 相似文献
54.
O. R. Santos W. S. Braga D. D. Luders A. R. Sampaio N. M. Kimura M. Simões 《Molecular Crystals and Liquid Crystals》2016,632(1):57-63
ABSTRACTThe nematic phases of a lyotropic system NadS/ decanol/ heavy water are investigated using optical conoscopy and image processing. The phase diagram obtained from these lyotropic materials predicts the occurrence of a direct phase transition, which does not present the biaxial nematic phase, between the discotic (ND) and calamitic (NC) nematic phases. A biaxial nematic (NB) phase is optically characterized and confirmed through conoscopic image, inside the biaxial range, between the two uniaxial nematic phases. Also, their respective transition points are determined by means of image processing. The NB phase observed here is discussed as part of the nature of the micellar configuration of lyotropic materials which exhibit uniaxial nematic phases. 相似文献
55.
Differentiation of Human Mesenchymal Stem Cells Toward Quality Cartilage Using Fibrinogen‐Based Nanofibers 下载免费PDF全文
56.
57.
Adriano Costa de Camargo Anna Paula de Souza Silva Jackeline Cintra Soares Severino Matias de Alencar Cíntia Ladeira Handa Karina Silva Cordeiro Marcela Souza Figueira Geni R. Sampaio Elizabeth A. F. S. Torres Fereidoon Shahidi Andrs R. Schwember 《Molecules (Basel, Switzerland)》2021,26(2)
A clear gap with respect to the potential biological properties of wheat flavonoids exists in the available literature. This information is crucial for breeding programs aiming to produce new varieties presenting improved health benefits. Accordingly, advanced breeding lines of whole durum wheat were evaluated in this contribution. The highest recovery of phenolics was achieved using aqueous acetone (50:50, v/v), as verified by multi-response optimization, thus showing that phenolics could be largely underestimated by employing an inappropriate extraction. The concentration of derivatives of apigenin, the main phenolics present, ranged from 63.5 to 80.7%, as evaluated by LC–ESI-QTOF-MS. Phenolics from the breeding line 98 exhibited the highest ability in scavenging peroxyl radicals, reducing power as well as in terms of inhibition of pancreatic lipase activity, a key enzyme regulating the absorption of triacylglycerols. In contrast, none of the samples exhibited a significant anti-diabetic potential. Despite their high concentration compared to that of phenolic acids, results of this work do not support a significant antioxidant and pancreatic lipase inhibitory effect of durum wheat flavonoids. Therefore, breeding programs and animal and/or human trials related to the effect of durum wheat flavonoids on oxidative stress and absorption of triacylglycerols are discouraged at this point. 相似文献
58.
We show that single and multislit experiments involving matter waves may be constructed to assess dispersively generated correlations between the position and momentum of a single free particle. These correlations give rise to position dependent phases which develop dynamically as a result of dispersion and may play an important role in the interference patterns. To the extent that initial transverse coherence is preserved throughout the proposed diffraction setup, such interference patterns are noticeably different from those of a classical dispersion free wave. 相似文献
59.
In many researches and applications in applied mathematics and engineering, we need to generalize the existing results, algorithms or methods in order to apply them to different situations or considerations. Generalization will allow certain particular problems to be solved more efficiently. Here we use some examples in scientific computing to demonstrate the importance of generalization technique for some researches, and how to generalize results or to improve conditions. 相似文献
60.
Luiz G. Guimarães Edson E.S. Sampaio 《Journal of Quantitative Spectroscopy & Radiative Transfer》2008,109(11):2124-2140
Based on Maxwell's equations and Ohm's law, we rederived the Snell laws for reflection and transmission of harmonic inhomogeneous plane electromagnetic (EM) waves propagating through planar lossy interfaces. The present results are new, simple and exact and they recover the ordinary Snell laws in the case of lossless media. Besides, these results show that the wave propagation direction strongly depends on the polarization state of the EM wave and the lossy media can behave as a polarizing device. Moreover, we verify that in low frequency regime these traveling waves do not exhibit total internal reflection at interfaces between two adjacent lossy media. 相似文献