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851.
Qmd-plot is a utility to obtain rapid information about past or on-going simulations, or real-time data collections, in the form of graphs of recorded variables (x, y, ...), as x-y plots or as a function of simulated or real time. Time series records in the data file must be named. Variable names and their locations in the data file are initially unknown to the program, but are identified in a first scan, in which header records are located on the basis of a predefined key (that can be changed interactively). The names of the time series are then presented in an interactive menu, from which the user can repeatedly specify a graph to be viewed. Qmd-plot has been developed in the context of molecular dynamics simulations. We give examples of time series and x-y plots made from output of the sigma program. Qmd-plot code is a Java application; source and class files can be obtained free from the authors. 相似文献
852.
Xu YN Kim JS Kang SS Son KH Kim HP Chang HW Bae K 《Chemical & pharmaceutical bulletin》2002,50(8):1124-1125
A new acylated triterpene together with prunasin, (-)-epicatechin, daucosterol, and three triterpenes, ursolic, oleanolic, and pomolic acids was isolated from the root of Chaenomeles japonica (THUNB.) LINDL. (Rosaceae) and determined to be 3-O-(E)-3, 5-dihydroxycinnamoylursolic acid on the basis of NMR and FAB-MS experiments. 相似文献
853.
854.
The Heisenberg paramagnet in one, two, and three dimensions is analyzed by a second-order Green's function theory similar to that used by Knapp and ter Haar. This theory, which incorporates the exact values for the zero, first, and second moments of the relaxation function as boundary conditions, yields results satisfying the rotational symmetry of the paramagnetic region as well as the principle of detailed balance. We find that our predictions for equal time properties in the classical limit are identical with the RPA Green's function theory of Liu as well as the spherical model results of Lax. The quantum limit is analyzed, and our predictions for the 1/T series coefficients for both internal energy and susceptibility are compared with exact results.Supported by National Science Foundation. 相似文献
855.
Determinations of neutral nonchromophoric organic compounds by dye-assisted chromatography are extended to the determination of aliphatic ketones and esters by using reversed-phase conditions and a mobile phase containing Brilliant Green. Detection limits of 6–20 μg were obtained when a mobile phase containing 50% (v/v) methanol/water and 0.00010 M Brilliant Green was used with detection at 575 nm, and 0.5–2 μg with detection in the ultraviolet region. In the absence of dye the detection limits for several solutes were about four times higher than the corresponding values obtained with the dye. The dye was shown to form a dimer having a molar absorptivity two orders of magnitude smaller than that of the monomeric dye. Detection of non-chromophoric compounds is concluded to be due to the desorption of adsorbed dye by the analytes and the shift of the aggregation and hydration equilibria of the dye promoted by the organic solutes. The lowering of the capacity factors is interpreted in terms of the adsorption of dye by the column which reduces the hydrophobicity of the stationary phase. 相似文献
856.
Summary Given a collection of nested closed, convex symmetric sets and a linear functional, we find estimates which are within a logarithm term of being simultaneously asymptotically minimax. Moreover, these estimates can be constructed so that the loss of this logarithm term only occurs on a small subset of functions. These estimates are quasi-optimal since there do not exist estimators which do not lose a logarithm term on some part of the parameter spaces.This author was partially supported by an NSF Grant DMS-9123956This author was supported by an NSF Postdoctoral Research Fellowship 相似文献
857.
1,3-dialkylimidazolium-based room-temperature ionic liquids as background electrolyte and coating material in aqueous capillary electrophoresis 总被引:3,自引:0,他引:3
The 1-ethyl-3-methylimidazolium (EMIM) cation was found to have constant mobility of 4.5 x 10(-4) cm2 V(-1) s(-1) over the pH range of 3 to 11. The electroosmotic flow of bare silica capillary was reversed by the covalently bonded room-temperature ionic liquid (RTIL) coating. With run buffer of 5 mM EMIM (pH 8.5), NH4+ in human urine was separated from the K+ matrix and was detected to be 0.37 +/- 0.012%. K+, Na+, Li+, Ca2+, Mg2+ and Ba2+ were baseline separated in RTIL-coated capillary with run buffer of 10 mM EMIMOH-acetic acid at pH 5, and the concentration of the above ions in a red wine were detected to be 907, 27.9, 0, 71.0, 83.4 and 31.1 microg/ml, respectively. The RTIL-coated capillary showed stable electroosmotic flow for at least 80 h in the run buffer. 相似文献
858.
Shiio Y Eisenman RN Yi EC Donohoe S Goodlett DR Aebersold R 《Journal of the American Society for Mass Spectrometry》2003,14(7):696-703
A method to identify and quantify chromatin-associated proteins has been developed and applied to the analysis of changes in chromatin-associated proteins induced by Myc oncoprotein expression in human B lymphocytes. Chromatin-enriched fractions were isolated by differential detergent/salt extraction and analyzed by ICAT reagent labeling, multi-dimensional chromatography and tandem mass spectrometry. Many known chromatin-associated regulatory factors were identified and quantified. The method will be widely applicable to various biological systems and reveal changes in chromatin-associated regulatory factors that underlie biological phenomena. 相似文献
859.
An ionic liquid (IL) coated capillary was prepared and investigated for DNA separation. The electroosmotic flow of the capillary was reversed between pH 4.5 and 9. Below 900 base pairs the larger DNA fragment suffered more retardation in the IL coated capillary due to the increasing charge density of the fragment with size. In the presence of 4% hydroxyethylcellulose, the phiX174 DNA-Hae III digest fragments were baseline separated in both IL- and polyacrylamide-coated capillary except for the fragments of 271 and 281 base pairs; while the analysis time was shorter in the IL-coated capillary. Our experiments indicated that the IL-coated capillary could work stably in the run buffer for at least 96 h with no notable deterioration in performance. 相似文献
860.
This paper proposes a new volume function for calculation of the entropy of planar granular assemblies. This function is extracted from the antisymmetric part of a new geometric tensor and is rigorously additive when summed over grains. It leads to the identification of a conveniently small phase space. The utility of the volume function is demonstrated on several case studies, for which we calculate explicitly the mean volume and the volume fluctuations. 相似文献