全文获取类型
收费全文 | 555篇 |
免费 | 26篇 |
国内免费 | 1篇 |
专业分类
化学 | 390篇 |
晶体学 | 9篇 |
力学 | 8篇 |
数学 | 15篇 |
物理学 | 160篇 |
出版年
2021年 | 4篇 |
2019年 | 3篇 |
2018年 | 10篇 |
2017年 | 7篇 |
2016年 | 9篇 |
2015年 | 22篇 |
2014年 | 12篇 |
2013年 | 29篇 |
2012年 | 23篇 |
2011年 | 21篇 |
2010年 | 18篇 |
2009年 | 10篇 |
2008年 | 25篇 |
2007年 | 18篇 |
2006年 | 32篇 |
2005年 | 28篇 |
2004年 | 17篇 |
2003年 | 18篇 |
2002年 | 18篇 |
2001年 | 12篇 |
2000年 | 5篇 |
1999年 | 15篇 |
1998年 | 8篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 12篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1990年 | 19篇 |
1989年 | 10篇 |
1988年 | 15篇 |
1987年 | 7篇 |
1986年 | 11篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 11篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 11篇 |
1977年 | 5篇 |
1976年 | 8篇 |
1975年 | 4篇 |
1974年 | 9篇 |
1973年 | 3篇 |
1971年 | 3篇 |
1968年 | 2篇 |
1967年 | 2篇 |
排序方式: 共有582条查询结果,搜索用时 31 毫秒
61.
Bailly J. L. Caso C. Chiba Y. Dibon H. Epp B. Ferrando A. Fontanelli F. Ganguli S. N. Gémesy T. Gurtu A. Hamatsu R. Hidas P. Hirose T. Hrubec J. Ivanyshenkov Yu. Kageya T. Khalatyan N. Kistenev E. Kita I. Kitamura S. Kubik V. MacNaughton J. Malhotra P. K. Matsumoto S. Mittra I. S. Montanet L. Neuhofer G. Pinter G. Porth P. Raghavan R. Rodrigo T. Singh J. Squarcia S. Takahashi K. Tanaka R. Tikhonova L. A. Trevisan U. Yamagata T. Zholobov G. Zotkin S. A. 《Zeitschrift fur Physik C Particles and Fields》1989,43(3):341-348
Zeitschrift für Physik C Particles and Fields - Correlations among identically charged pions were measured for pions produced inp p collisions at 360 GeV/c using the EHS spectrometer. The... 相似文献
62.
Yoshinori Kamiya Keishin Mizoguchi Yasutoshi Naito Takuji Hirose 《Journal of Polymer Science.Polymer Physics》1986,24(3):535-547
High-pressure sorption (up to 50 atm) for CO2, N2, and Ar in poly(vinyl benzoate) (PVB) was studied at temperatures from 25 to 70°C by a gravimetric method utilizing an electromicrobalance. The results are described by Henry's law above the glass transition temperature Tg for all gases. The dual-mode sorption model, Henry's law plus a Langmuir isotherm, applies to the sorption isotherms of N2 and Ar in the glassy state, and the dual-mode parameters are given. For CO2, a new type of sorption isotherm is observed below Tg. The isotherm is concave to the pressure axis in the low-pressure region and turns into a straight line with increasing CO2 pressure which can be extrapolated back to the coordinate origin. The linear part of the isotherm is characteristic of the rubbery state, while the nonlinear part stems from glassystate behavior. The “glass transition solubility” of CO2, at which PVB film changes from the glassy to the rubbery state, decrease as the temperature increases. The disappearance of microvoids, that is, the decrease of the Langmuir capacity, may be due to a large plasticizing effect of sorbed CO2. The difference between the N2 and Ar isotherms and the CO2 isotherm is discussed from this standpoint. 相似文献
63.
A series of novel optically active 1,3‐aminoalcohols based on cis‐(1R,2S)‐2‐benzamidocyclohexanecarboxylic acid and trans‐(1R,2R)‐2‐benzamidocyclohexanecarboxylic acid were synthesized and used in the asymmetric diethylzinc addition to aromatic aldehydes. Not only the enantioselectivity but also the stereochemistry of the product were controlled by the N‐substituents and the substituents on the vicinity carbon to hydroxyl group of the cis‐derivatives. 相似文献
64.
Kenshu Fujiwara Yuta Hirose Hidetoshi Kawai Takanori Suzuki 《Tetrahedron letters》2010,51(32):4263-4546
Armatol F, isolated from the red alga Chondria armata as a polyether triterpene, has a solitary oxepane (A-ring) and a fused tricyclic ether moiety (BCD-ring). The A-ring features a rare cis-relationship between the hydroxy group at the quaternary carbon C6 and the carbon chain at C7. As part of our program toward the total synthesis of armatol F, a new stereoselective method for the construction of the C6 and C7 stereocenters has been developed based on chirality-transferring Ireland-Claisen rearrangement. The A-ring skeleton has also been synthesized from the rearrangement product by a process including ring-closing olefin metathesis. 相似文献
65.
The path-integral renormalization group and direct energy minimization method of practical first-principles electronic structure calculations for multi-body systems within the framework of the real-space finite-difference scheme are introduced. These two methods can handle higher dimensional systems with consideration of the correlation effect. Furthermore, they can be easily extended to the multicomponent quantum systems which contain more than two kinds of quantum particles. The key to the present methods is employing linear combinations of nonorthogonal Slater determinants (SDs) as multi-body wavefunctions. As one of the noticeable results, the same accuracy as the variational Monte Carlo method is achieved with a few SDs. This enables us to study the entire ground state consisting of electrons and nuclei without the need to use the Born-Oppenheimer approximation. Recent activities on methodological developments aiming towards practical calculations such as the implementation of auxiliary field for Coulombic interaction, the treatment of the kinetic operator in imaginary-time evolutions, the time-saving double-grid technique for bare-Coulomb atomic potentials and the optimization scheme for minimizing the total-energy functional are also introduced. As test examples, the total energy of the hydrogen molecule, the atomic configuration of the methylene and the electronic structures of two-dimensional quantum dots are calculated, and the accuracy, availability and possibility of the present methods are demonstrated. 相似文献
66.
Pure hydrogenated amorphous carbon (α-C:H) and nitrogen doped hydrogenated amorphous carbon (α-C:H:N) thin films were prepared using end-Hall (EH) ion beam deposition with a beam energy ranging from 24 eV to 48 eV. The composition, microstructure and mechanical properties of the films were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, scanning probe microscopy (SPM), and nano-scratch tests. The films are uniform and smooth with root mean square roughness values of 0.5-0.8 nm for α-C:H and 0.35 nm for α-C:H:N films. When the ion energy was increased from 24 eV to 48 eV, the fraction of sp3 bonding in the α-C:H films increased from 36% to 55%, the hardness increased from 8 GPa to 12.5 GPa, and the Young's modulus increased from 100 GPa to 130 GPa. In the α-C:H:N films, N/C atomic ratio, the hardness and Young's modulus of the α-C:H:N films are, 0.087, 15 and 145 GPa, respectively. The results indicate that both higher ion energy and a small amount of N doping improve the mechanical properties of the films. The results have demonstrated that smooth and uniform α-C:H and α-C:H:N films with large area and reasonably high hardness and Young's modulus can be synthesized by EH ion source. 相似文献
67.
The steady-shear viscosity, dynamic viscoelasticity, and sedimentation behavior were measured for silica suspensions dispersed
in aqueous solutions of poly(ethylene oxide) (PEO). For suspensions prepared with polymer solutions in which the transient
network is developed by entanglements, the viscosity at a given shear rate decreases, shows a minimum, and then increases
with increasing particle concentration. Because the suspensions are sterically stabilized under the conditions where the particle
surfaces are fully covered with by a thick layer of adsorbed polymer, the viscosity decrease can be attributed to the reduction
of network density in solution. But under the low coverage conditions, the particles are flocculated by bridging and this
leads to a viscosity increase with shear-thinning profiles. The polymer chains with high molecular weights form flexible bridges
between particles. The stress-dependent curve of storage modulus measured by a stress amplitude sweep shows an increase prior
to a drastic drop due to structural breakdown. The increase in elastic responses may arise from the restoring forces of extended
bridges with high deformability. The effect of PEO on the rheological behavior of silica suspensions can be explained by a
combination of concentration reduction of polymer in solution and flocculation by bridging. 相似文献
68.
Keitaro Tanoi Natsuko I. Kobayashi Takayuki Saito Naoko Iwata Atsushi Hirose Yoshimi Ohmae Ren Iwata Hisashi Suzuki Tomoko M. Nakanishi 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(2):749-751
The time course of Mg uptake and release using intact rice plants and 28Mg as a tracer is presented. Since there is no conventional Mg tracer available, 28Mg was produced via 27Al(α, 3p)28Mg reaction using a cyclotron. Using the purified 28Mg tracer, it was found that the uptake amount of 28Mg by the rice plants increased linearly during 30 min of application. After 28Mg treatment for 90 min, the roots were sequentially washed with iced solution for 120 min. Within about 10 min, almost all of the 28Mg, that was thought to be weakly bound to the apoplast, was washed away. 相似文献
69.
Hidekazu Kumano Satoshi Kimura Michiaki Endo Ikuo Suemune Hirotaka Sasakura Satoru Adachi Shunichi Muto Hai Zhi Song Shinichi Hirose Tatsuya Usuki 《Physica E: Low-dimensional Systems and Nanostructures》2006,32(1-2):144
Triggered single-photon generation from InAlAs quantum dot (QD) was demonstrated for the first time. Emitted photon energy coincides with high detection efficiency range of Si single-photon detectors, which is highly suitable for free-space communication. Single-QD spectroscopy and crossed photon correlation measurements unambiguously revealed that several emitting lines observed in a single mesa structure originated from the identical QD, and two temporary competing decay processes associated with neutral states and charged states were identified. Presence of the competing process is also inferred from an analysis of steady-state photoluminescence intensities. Formation process of charged exciton in QD is also discussed. 相似文献
70.
Kenji Hirose Nobuhiko Kobayashi 《Physica E: Low-dimensional Systems and Nanostructures》2005,29(3-4):515
Using the recursion-transfer-matrix (RTM) method combined with nonequilibrium Green's function (NEGF) method, we study the electronic states and current–voltage (I–V) characteristics of junction systems with atomic-scale nanocontacts as a function of the distance between electrodes. We observe a strong nonlinear behavior in the I–V characteristics and correspondingly a gap structure appears in conductance. We find that such a nonlinear behavior emerges when the transport properties change from tunneling to ballistic regimes. 相似文献