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51.
Fluorescence spectra of PrI3 molecules isolated in Ar and Xe matrices have been measured for the first time. More than 40 transitions have been measured using Hg excitation and have been assigned to transitions within the 4f2 configuration. 相似文献
52.
[reaction: see text] Cyclic hydrazides function as asymmetric organocatalysts in aqueous Diels-Alder reactions. The hydrazide is employed as the catalytic machinery in a compact camphor-derived framework that imparts facial selectivity to the cycloadditions. Kinetic evidence suggests the reaction involves rapid iminium formation. 相似文献
53.
We report a novel Fourier transform method for measuring two-photon excitation spectra. We demonstrate this method using simple dye molecules and discuss its applications in two-photon fluorescence microscopy and optimal control. This method facilitates an intuitive interpretation of recent control experiments in terms of tuning the nonlinear spectrum of the exciting laser source. 相似文献
54.
Doezé RH Maltman BA Egan CL Ulijn RV Flitsch SL 《Angewandte Chemie (International ed. in English)》2004,43(24):3138-3141
55.
The German bakery waste incident; use of a combined approach of screening and confirmation for dioxins in feed and food 总被引:1,自引:0,他引:1
During the last six years several incidents have occurred with dioxins in feed, stressing the need for rapid screening methods for these compounds. The most recent incident was the contamination of bakery waste used for animal feed due to the use of waste wood for drying of the material. In addition to Germany, the material was also shipped to the Netherlands. Levels up to 12 ng TEQ/kg have been detected, being about 15 times over the current limit of 0.75 ng TEQ/kg. In the Netherlands a combined strategy of screening with the CALUX-bioassay and the HRGC/HRMS confirmatory method was used to rapidly control the incident. Pigs were contaminated by the incident but only to a very limited extent. Despite the rather low limits for pig meat, the CALUX bioassay showed excellent performance, once again confirming the value of this assay. 相似文献
56.
Recently, unusual giant magnetic properties were found experimentally in some organized organic monolayers adsorbed on solid substrates. A model is presented which explains the observed phenomenon. The model is based on the special properties of electrons transferred from the substrate to the layer as a result of the adsorption process. Triplet pairing of those electrons is forced by the special 2D properties of the organic layer. Such pairs are confined within domains in the organic layer and their quantum statistics provide a model that explains the unique magnetization as well as all other features of the experimental observations. The model suggests the possible existence of Bose-Einstein condensation at room temperature on the scale of the domains. 相似文献
57.
The goal of this paper is to study some Poincaré series associated to the invariants of the symplectic and odd orthogonal
groups. These series turn out to be rational functions and our main results will describe the denominators. This work will
generalize some known results on the invariants of the general linear groups. In addition to whatever intrinsic interest we
hope our results may have, the subject involves an interesting interplay of invariant theory and complex variables.
The first author gratefully acknowledges Support from DePaul University Research Council.
The second author was supported in part by the Israel Science Foundation, founded by the Israel Academy of Sciences and Humanities,
and by an Internal Research Grant from Bar-Ilan University. 相似文献
58.
To evaluate individual expansion coefficients composing fitting parameters of the Born-Oppenheimer corrections to Dunham's coefficients Y(ij) that have been given analytically with the Delta(B) and Delta(omega) formalism, we examined the consistency of analytic expressions for those corrections with Watson's assertion of the experimental inseparability of nonadiabatic corrections Q(a, b)(r) for a molecule AB. Derived analytic expressions in terms of optimal fitting parameters for the corrections are essential to evaluate individual expansion coefficients. These expressions also reveal redundancies between empirical correction parameters Delta(ij). A method of evaluating nonadiabatic vibrational corrections Q(a, b)(r) and adiabatic corrections S(a, b)(r) separately consistent with Watson's assertion of inseparability is presented and is applied to an analysis of spectral data of LiH. Functions Q(a, b) and S(a, b) for LiH are thus successfully evaluated; S(H, Li)(r) values agree well with those predicted simply by wobble-stretch theory. Experimental values for optimal fitting parameters r(H)(1q) and r(H)(2q) are nearly equal to those of r(Li)(1q) and r(Li)(2q), respectively, in agreement with a theoretical relation r(a)(iq)=r(b)(iq). Copyright 2001 Academic Press. 相似文献
59.
Baryon rapidity loss in relativistic Au + Au collisions 总被引:4,自引:0,他引:4
Back BB Betts RR Chang J Chang WC Chi CY Chu YY Cumming JB Dunlop JC Eldredge W Fung SY Ganz R Garcia E Gillitzer A Heintzelman G Henning WF Hofman DJ Holzman B Kang JH Kim EJ Kim SY Kwon Y McLeod D Mignerey AC Moulson M Nanal V Ogilvie CA Pak R Ruangma A Russ DE Seto RK Stanskas PJ Stephans GS Wang HQ Wolfs FL Wuosmaa AH Xiang H Xu GH Yao HB Zou CM 《Physical review letters》2001,86(10):1970-1973
An excitation function of proton rapidity distributions for different centralities is reported from AGS Experiment E917 for Au+Au collisions at 6, 8, and 10.8 GeV/nucleon. The rapidity distributions from peripheral collisions have a valley at midrapidity which smoothly change to distributions that display a broad peak at midrapidity for central collisions. The mean rapidity loss increases with increasing beam energy, whereas the fraction of protons consistent with isotropic emission from a stationary source at midrapidity decreases with increasing beam energy. The data suggest that the stopping is substantially less than complete at these energies. 相似文献
60.
Gareth AD Hardy Nesrina Imami Mark R Nelson Ann K Sullivan Ron Moss Marlén MI Aasa-Chapman Brian Gazzard Frances M Gotch 《Journal of immune based therapies and vaccines》2007,5(1):6-12