Acoustic diagnosis for porous medium with circular cylindrical pores

Acoustic transmission coefficient and phase velocity of a Lucite slab with circular cylindrical pores with a nonrigid pore frame were experimentally and theoretically investigated. For theoretical investigation a new phenomenological model, the modified Biot-Attenborough (MBA) model, was proposed. The MBA model takes into account both the first kind and the second kind of waves introduced by Biot. It also separately considers viscous and thermal effects with three new phenomenological parameters: boundary, phase velocity, and impedance parameters. The theoretical estimation with three phenomenological parameters shows reasonably good agreement with the experimental data. The physical characteristics of porous medium such as porosity and pore size can be inversely analyzed in terms of the acoustic data such as the transmission coefficient and phase velocity as the functions of porosity and frequency. This makes acoustic diagnosis possible for noninvasively investigating physical characteristics of porous media such as bones and ocean sediments.     

Protein and solvent dynamics: how strongly are they coupled?

Analysis of Raman and neutron scattering spectra of lysozyme demonstrates that the protein dynamics follow the dynamics of the solvents glycerol and trehalose over the entire temperature range measured 100-350 K. The protein's fast conformational fluctuations and low-frequency vibrations and their temperature variations are very sensitive to behavior of the solvents. Our results give insight into previous counterintuitive observations that protein relaxation is stronger in solid trehalose than in liquid glycerol. They also provide insight into the effectiveness of glycerol as a biological cryopreservant.     

Magnetic response of microbially synthesized transition metal- and lanthanide-substituted nano-sized magnetites

The magnetic susceptibility (κ_RT) and saturation magnetization (M_S) of microbially synthesized magnetites were systematically examined. Transition metal (Cr, Mn, Co, Ni and Zn)- and lanthanide (Nd, Gd, Tb, Ho and Er)-substituted magnetites were microbially synthesized by the incubation of transition metal (TM)- and lanthanide (L)-mixed magnetite precursors with either thermophilic (TOR-39) or psychrotolerant (PV-4) metal-reducing bacteria (MRB). Zinc incorporated congruently into both the precursor and substituted magnetite, while Ni and Er predominantly did not. Microbially synthesized Mn- and Zn-substituted magnetites had higher κ_RT than pure biomagnetite depending on bacterial species and they exhibited a maximum κ_RT at 0.2 cationic mole fraction (CMF). Other TMs’ substitution linearly decreased the κ_RT with increasing substitution amount. Based on the M_S values of TM- and L-substituted magnetite at 0.1 and 0.02 CMF, respectively, Zn (90.7 emu/g for TOR-39 and 93.2 emu/g for PV-4)- and Mn (88.3 emu/g by PV-4)-substituted magnetite exhibited higher M_S than standard chemical magnetite (84.7 emu/g) or pure biomagnetite without metal substitution (76.6 emu/g for TOR-39 and 80.3 emu/g for PV-4). Lanthanides tended to decrease M_S, with Gd- and Ho-substituted magnetites having the highest magnetization. The higher magnetization of microbially synthesized TM-substituted magnetites by the psychrotroph, PV-4 may be explained by the magnetite formation taking place at low temperatures slowing mechanics, which may alter the magnetic properties compared to the thermophile, through suppression of the random distribution of substituted cations.     

Optical detection of Cu ion using a SQ-dye containing polymeric thin-film on Au surface

In this study, we have fabricated Cu²⁺ ion sensor using a squarylium dye (SQ-dye) containing polymeric thin-film. Surface Plasmon Resonance (SPR) was used as a signal amplifier to achieve high sensitivity and large linear dynamic range for detection of Cu²⁺ ion. High selectivity to Cu²⁺ ion was obtained by the effective electro-static interaction between SQ-dye and Cu²⁺ ion in the polymeric film. The optimal analytical condition of high selectivity and sensitivity in the wider linear dynamic range obtained in this study may be a result of the cooperative ‘hard-soft’ metal ion-ligand interaction and effective detection of refractive index changes by the complexation of Cu²⁺ ion and SQ-dye in SPR measurement. Among 10 different alkali metal, alkaline earth metal, and transition metal ions, SQ-dye in poly(vinylchloride)–poly(vinyl acetate)–poly(vinyl alcohol) (PVC–PVAc–PVA) copolymer film showed the highest selectivity to Cu²⁺ ion. Although the interaction between SQ-dye and metal ions has not been well understood, both cooperative ‘hard-soft’ metal ion-ligand interaction and size-selective recognition of Cu²⁺ ion to SQ-dye may contribute to high selectivity. Furthermore, additional sensitivity in the detection of Cu²⁺ ion by SPR was obtained by matching the wavelength of probing radiation of SPR and absorption maximum of SQ-dye at 675 nm, which allow to detect small changes in the refractive index by complex formation on the sensing surface. This result may apply in development of the Cu²⁺ ion selective sensor for medical, biochemical, and environmental applications.     

Gamma-ray spectroscopy with relativistic exotic heavy-ions

Feasibility of gamma-ray spectroscopy at relativistic energies with exotic heavy-ions and new generation of germanium detectors (segmented Clover) is discussed. An experiment with such detector array and radioactive is discussed.     

Zur Theorie der Gammafunction

Ohne Zusammenfassung Vergl. meine Abhandlung:Om en ny klass af transcendenta functioner, hvilka ?ro n?ra besl?gtade med gammafunktionen, Acta soc. scient. Fennic?, Tom. XIV, XV; 1885, 1886.     

Simple expressions of the reflection and transmission coefficients of fundamental Lamb waves by a rectangular notch

The scattering of Lamb waves by a two-dimensional rectangular notch is investigated for rapid inspection of defects in a structure. To derive the reflection and transmission coefficients of the scattered waves in a simple way, the scattering caused by the notch is analyzed through the composition of individual scattering processes. Linear equations corresponding to the reflection and transmission coefficients are constructed along with scattering graphs. For an illustration of the efficacy of the presented method, the scattering of fundamental symmetric and anti-symmetric modes are inspected according to the depth and width of a notch in a plate. Validity of these expressions is demonstrated by the comparison of the theoretical analysis results with those from the finite element analysis.     

Tetrazoles: LI. Synthesis of 5-substituted tetrazoles under microwave activation

Reaction of nitriles with sodium azide in the presence of ZnCl₂ under microwave activation (MWA) leads to the formation of 5-tetrazoles in high yields; therewith the process is 2–3 times shorter than the inactivated reaction.     

Passive combination of multiple beams in an optical fiber via stimulated Brillouin scattering

We demonstrate passive combination of multiple beams in an optical fiber via stimulated Brillouin scattering (SBS). Four off-axis beams are combined in a long multimode optical fiber using a novel all-optical mount. The combined beam has the high spatial coherence properties of the LP(01) mode owing to the beam cleanup properties of SBS. The threshold for SBS when off-axis pumps are used is shown to be a factor of 13 times higher than for on-axis pump beams. We propose this method would improve the brightness of an array of fiber amplifiers.