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21.
A new method is presented for the analysis of 17[small beta]-estradiol in bovine urine. After deconjugation, the sample is cleaned up using an OASIS[trade mark sign] HLB disposable cartridge and extracted into 1-chlorobutane. The hormone is derivatized using pentafluorobenzoyl chloride. The derivatized estradiol is quantitated using gas-chromatography negative-ion chemical ionization mass spectrometry. Calibrations, obtained using spiked blank urine, are linear in the range of 100-1000 pg mL(-1) with CC[small alpha] approximately 170 pg mL(-1) and CC[small beta] of 287 pg mL(-1). Recoveries are in the range of 80 to 130%. The method is rugged, rapid and sensitive when compared to other hormone methods. 相似文献
22.
Natalie R. Altvater Rick W. Dorn Melissa C. Cendejas William P. McDermott Brijith Thomas Aaron J. Rossini Ive Hermans 《Angewandte Chemie (International ed. in English)》2020,59(16):6546-6550
Boron‐containing materials have recently been identified as highly selective catalysts for the oxidative dehydrogenation (ODH) of alkanes to olefins. It has previously been demonstrated by several spectroscopic characterization techniques that the surface of these boron‐containing ODH catalysts oxidize and hydrolyze under reaction conditions, forming an amorphous B2(OH)xO(3?x/2) (x=0–6) layer. Yet, the precise nature of the active site(s) remains elusive. In this Communication, we provide a detailed characterization of zeolite MCM‐22 isomorphously substituted with boron (B‐MWW). Using 11B solid‐state NMR spectroscopy, we show that the majority of boron species in B‐MWW exist as isolated BO3 units, fully incorporated into the zeolite framework. However, this material shows no catalytic activity for ODH of propane to propene. The catalytic inactivity of B‐MWW for ODH of propane falsifies the hypothesis that site‐isolated BO3 units are the active site in boron‐based catalysts. This observation is at odds with other traditionally studied catalysts like vanadium‐based catalysts and provides an important piece of the mechanistic puzzle. 相似文献
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24.
Barlow RD 《OR manager》2002,18(6):1, 9-10, 13
25.
Degradates of acetochlor and alachlor (ethanesulfonic acids, ESAs) were analyzed in both standards and in a groundwater sample using high-performance liquid chromatography-time-of-flight mass spectrometry with electrospray ionization. The negative pseudomolecular ion of the secondary amide of acetochlor ESA and alachlor ESA gave average masses of 256.0750+/-0.0049 amu and 270.0786+/-0.0064 amu respectively. Acetochlor and alachlor ESA gave similar masses of 314.1098+/-0.0061 amu and 314.1153+/-0.0048 amu; however, they could not be distinguished by accurate mass because they have the same empirical formula. On the other hand, they may be distinguished using positive-ion electrospray because of different fragmentation spectra, which did not occur using negative-ion electrospray. 相似文献
26.
Xun?Gu Selcuk?Akturk Aparna?Shreenath Qiang?Cao Rick?TrebinoEmail author 《Optical Review》2004,11(3):141-152
We review the state of the art of ultrashort-light-pulse measurement using frequency-resolved-optical-gating (FROG). Recent developments have extended the state of the art considerably. FROG devices for measuring the intensity and phase of ultrashort laser pulses have become so simple that almost no alignment is required. In addition, such devices not only operate single shot, but they also yield the two most important spatio-temporal distortions, spatial chirp and pulse-front tilt. With other FROG variations, it is now possible to measure more general ultrashort light pulses (i.e., pulses much more complex than common laser pulses), with time-bandwidth products as large as several thousand and as weak as a few hundred photons, and despite other difficulties such as random absolute phase and poor spatial coherence. 相似文献
27.
Rick Kreminski. 《Mathematics of Computation》2003,72(243):1379-1397
In the Laurent expansion
of the Riemann-Hurwitz zeta function, the coefficients are known as Stieltjes, or generalized Euler, constants. [When , (the Riemann zeta function), and .] We present a new approach to high-precision approximation of . Plots of our results reveal much structure in the growth of the generalized Euler constants. Our results when for , and when for (for such as 53/100, 1/2, etc.) suggest that published bounds on the growth of the Stieltjes constants can be much improved, and lead to several conjectures. Defining , we conjecture that is attained: for any given , for some (and similarly that, given and , is within of for infinitely many ). In addition we conjecture that satisfies for 1$">. We also conjecture that , a special case of a more general conjecture relating the values of and for . Finally, it is known that for . Using this to define for all real 0$">, we conjecture that for nonintegral , is precisely times the -th (Weyl) fractional derivative at of the entire function . We also conjecture that , now defined for all real arguments 0$">, is smooth. Our numerical method uses Newton-Cotes integration formulae for very high-degree interpolating polynomials; it differs in implementation from, but compares in error bounding to, Euler-Maclaurin summation based methods.
of the Riemann-Hurwitz zeta function, the coefficients are known as Stieltjes, or generalized Euler, constants. [When , (the Riemann zeta function), and .] We present a new approach to high-precision approximation of . Plots of our results reveal much structure in the growth of the generalized Euler constants. Our results when for , and when for (for such as 53/100, 1/2, etc.) suggest that published bounds on the growth of the Stieltjes constants can be much improved, and lead to several conjectures. Defining , we conjecture that is attained: for any given , for some (and similarly that, given and , is within of for infinitely many ). In addition we conjecture that satisfies for 1$">. We also conjecture that , a special case of a more general conjecture relating the values of and for . Finally, it is known that for . Using this to define for all real 0$">, we conjecture that for nonintegral , is precisely times the -th (Weyl) fractional derivative at of the entire function . We also conjecture that , now defined for all real arguments 0$">, is smooth. Our numerical method uses Newton-Cotes integration formulae for very high-degree interpolating polynomials; it differs in implementation from, but compares in error bounding to, Euler-Maclaurin summation based methods.
28.
Micro-contact imprinting has been used to form thin-film molecular imprints of ovalbumin (OVA) in polymers supported on glass slides. Thermocalorimetric data was used to optimise the choice of functional monomer and cross-linker to maximise selectivity and minimise non-specific recognition.A polymer comprising polyethyleneglycol 400 dimethacrylate (95 vol.%) and methacrylic acid (5 vol.%) showed both maximum recognition for OVA when made as a molecularly imprinted polymer (MIP), and minimal recognition when made as a non-imprinted, i.e. control polymer. OVA rebinding to the molecularly imprinted polymer, from a buffered 2 µM OVA solution, was 1.55 × 10− 11 mol cm− 2, while the control polymer showed 10-fold less re-binding, i.e. 0.154 × 10− 11 mol cm− 2.Experiments in which human serum albumin (HSA), conalbumin, ovomucoid or lysozyme, were re-bound to the polymers, either as single proteins or in competition with OVA, showed them to have low affinity for the polymer formulation used. Of the competing proteins examined, in non-competitive binding experiments, HSA showed the greatest affinity 0.45 × 10− 11 mol cm− 2 for the OVA imprinted polymer. In two protein competition experiments, i.e. with OVA and a competing protein present at equal concentrations (2 µM), OVA binding to the OVA imprinted polymer was in all cases significantly greater than that of the competitor. 相似文献
29.
Natalie R. Altvater Rick W. Dorn Melissa C. Cendejas William P. McDermott Dr. Brijith Thomas Prof. Dr. Aaron J. Rossini Prof. Dr. Ive Hermans 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6608-6612
Boron-containing materials have recently been identified as highly selective catalysts for the oxidative dehydrogenation (ODH) of alkanes to olefins. It has previously been demonstrated by several spectroscopic characterization techniques that the surface of these boron-containing ODH catalysts oxidize and hydrolyze under reaction conditions, forming an amorphous B2(OH)xO(3−x/2) (x=0–6) layer. Yet, the precise nature of the active site(s) remains elusive. In this Communication, we provide a detailed characterization of zeolite MCM-22 isomorphously substituted with boron (B-MWW). Using 11B solid-state NMR spectroscopy, we show that the majority of boron species in B-MWW exist as isolated BO3 units, fully incorporated into the zeolite framework. However, this material shows no catalytic activity for ODH of propane to propene. The catalytic inactivity of B-MWW for ODH of propane falsifies the hypothesis that site-isolated BO3 units are the active site in boron-based catalysts. This observation is at odds with other traditionally studied catalysts like vanadium-based catalysts and provides an important piece of the mechanistic puzzle. 相似文献
30.