全文获取类型
收费全文 | 1062篇 |
免费 | 50篇 |
国内免费 | 6篇 |
专业分类
化学 | 686篇 |
晶体学 | 2篇 |
力学 | 40篇 |
数学 | 194篇 |
物理学 | 196篇 |
出版年
2023年 | 11篇 |
2022年 | 8篇 |
2021年 | 39篇 |
2020年 | 28篇 |
2019年 | 20篇 |
2018年 | 18篇 |
2017年 | 25篇 |
2016年 | 49篇 |
2015年 | 40篇 |
2014年 | 47篇 |
2013年 | 56篇 |
2012年 | 58篇 |
2011年 | 78篇 |
2010年 | 32篇 |
2009年 | 36篇 |
2008年 | 65篇 |
2007年 | 67篇 |
2006年 | 76篇 |
2005年 | 56篇 |
2004年 | 43篇 |
2003年 | 31篇 |
2002年 | 35篇 |
2001年 | 14篇 |
2000年 | 14篇 |
1999年 | 13篇 |
1998年 | 12篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 12篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1980年 | 11篇 |
1979年 | 10篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1975年 | 4篇 |
1974年 | 4篇 |
1972年 | 3篇 |
排序方式: 共有1118条查询结果,搜索用时 31 毫秒
991.
Riccardo Falciai Francesco Baldini Franco Cosi Paolo Bechi Filippo Pucciani 《Fiber and Integrated Optics》1993,12(2):215-222
A portable optical-fiber sensor for ambulatory assessment of the enterogastric reflux, based on the optical properties of the bile, was developed. It makes use of two light-emitting diodes and of an appropriate electronic circuit that processes the signals and provides the readout on a display. A suitable probe for in vivo measurements was designed. Plastic fiber bundles are used in order to obtain probe flexibility and low price. In vivo measurements performed on different patients show the superiority of this technique over existing methods. 相似文献
992.
993.
Riccardo Benedetti Francois Loeser Jean Jacques Risler 《Discrete and Computational Geometry》1991,6(1):191-209
For every polynomial mapf=(f
1,…,f
k): ℝ
n
→ℝ
k
, we consider the number of connected components of its zero set,B(Z
f) and two natural “measures of the complexity off,” that is the triple(n, k, d), d being equal to max(degree off
i), and thek-tuple (Δ1,...,Δ4), Δ
k
being the Newton polyhedron off
i respectively. Our aim is to boundB(Z
f) by recursive functions of these measures of complexity. In particular, with respect to (n, k, d) we shall improve the well-known Milnor-Thom’s bound μ
d
(n)=d(2d−1)
n−1. Considered as a polynomial ind, μ
d
(n) has leading coefficient equal to 2
n−1. We obtain a bound depending onn, d, andk such that ifn is sufficiently larger thank, then it improves μ
d
(n) for everyd. In particular, it is asymptotically equal to 1/2(k+1)n
k−1
dn, ifk is fixed andn tends to infinity. The two bounds are obtained by a similar technique involving a slight modification of Milnor-Thom's argument,
Smith's theory, and information about the sum of Betti numbers of complex complete intersections. 相似文献
994.
Riccardo Stradi Donato Pocar Giuseppe Bianchetti 《Magnetic resonance in chemistry : MRC》1972,4(2):247-251
A series of 1-aryl-5-amino-4,5-dihydro-v-triazoles bearing at least one hydrogen atom at the C-4 position has been prepared. The NMR features of the above compounds have been studied with the purpose of differentiating the triazolines with a trans configuration from those with a cis configuration. It has been shown that the hydrogen atom at C-4 lying on the same side of the amine group at C-5 always resonates at lower field than the hydrogen atom on the opposite side. This rule can be applied for identifying the configuration of the 5-amino-v-triazolines. 相似文献
995.
Flamini R Vedova AD Panighel A Perchiazzi N Ongarato S 《Journal of mass spectrometry : JMS》2005,40(12):1558-1564
A new method has been developed to determine acetaldehyde, 2,3-butanedione (diacetyl) and 3-hydroxy-2-butanone (acetoin) in wine by solid-phase microextraction (SPME) and positive ion chemical ionization GC/MS analysis of O-(2,3,4,5,6-pentafluorobenzyl)-hydroxylamine (PFBOA) derivatives. For SPME, a 65-microm PEG/DVB fibre was used; chemical ionization was performed with methane as reagent gas. The best analysis-time/sensitivity compromise was to perform the PFBOA reaction at 50 degrees C for 20 min, followed by 5-min SPME at the same temperature. Quantitative analysis was performed in SCAN mode using o-chlorobenzaldehyde as internal standard (IS), on the signal of the [M + H](+) ion at m/z 240 for acetaldehyde, 266 for acetoin (corresponding to the [M + H - 18](+) ion), 282 for diacetyl (protonated mono-derivatized compound), and 336 for IS. The accuracy and repeatability of the method were suitable for the study aims, and linearity was good in the range of concentration studied, with correlation coefficients of calibration curves 0.997, 0.998 and 0.988 for acetaldehyde, diacetyl and acetoin respectively. Due to the higher polarity of acetoin with respect to other two compounds, lower sensitivity in the detection of this compound was observed. By following the variation of the three carbonyl compounds, malolactic fermentations (MLF) were monitored in Merlot wines and this was carried out in the laboratory by two different bacteria strains. 相似文献
996.
Hexamethildisiloxane-oxygen fed radiofrequency discharges have been studied under high power density and 0.05÷0.1 torr pressure,
i.e., experimental conditions of high monomer fragmentation. Actinometric Optical Emission Spectroscopy of plasma phase, X-Ray
Photoelectron Spectroscopy and Infrared Spectroscopy analyses of the deposited films allowed to set the basis of the first
“semi-quantitative” mechanism of deposition of siloxane films which can reasonably account for both deposition rates and film
compositions. A by-product of the research is the use of CH-to-Ar emission ratio as a probe of carbon content in the film,
an important practical parameter for process control. 相似文献
997.
Rossi G Ferrando R Rapallo A Fortunelli A Curley BC Lloyd LD Johnston RL 《The Journal of chemical physics》2005,122(19):194309
Genetic algorithm global optimization of Ag-Pd, Ag-Au, and Pd-Pt clusters is performed. The 34- and 38-atom clusters are optimized for all compositions. The atom-atom interactions are modeled by a semiempirical potential. All three systems are characterized by a small size mismatch and a weak tendency of the larger atoms to segregate at the surface of the smaller ones. As a result, the global minimum structures exhibit a larger mixing than in Ag-Cu and Ag-Ni clusters. Polyicosahedral structures present generally favorable energetic configurations, even though they are less favorable than in the case of the size-mismatched systems. A comparison between all the systems studied here and in the previous paper (on size-mismatched systems) is presented. 相似文献
998.
A heterostructure formed by a conjugated polymer and semiconducting nanoparticles was produced. The conjugated polymer was synthesized by oxidative copolymerization of 3-thiopheneacetic acid and 3-hexylthiophene, thus obtaining an amphiphilic polythiophene that allows the formation of a stable polymer layer at the air-water interface. Different numbers of monolayers were deposited on solid substrates. CuS nanoparticles were grown directly in the polymeric matrix using the carboxylic groups as nucleation centers. The reactions were monitored by quartz crystal microbalance, Brewster angle, and fluorescence microscopy. The heterostructure showed increased conductivity as compared to the pristine polymer. 相似文献
999.
Antony F. McDonagh † Giovanni Agati Franco Fusi Riccardo Pratesi † 《Photochemistry and photobiology》1989,50(3):305-319
The quantum yield for laser photocyclization of bilirubin to lumirubin in the presence of human serum albumin (phi LR) was measured at five monochromatic excitation wavelengths in the range 450-530 nm. Solutions used were optically thin throughout the wavelength range and precautions were taken to exclude contributions from photocyclization of bilirubin XIII alpha impurities. The values obtained (7.2-18 x 10(-4] were lower than those previously reported and showed the following wavelength dependence: 457.9 less than 488.0 less than 501.7 less than 514.5 approximately equal to 528.7. However, the rate of lumirubin formation, normalized to constant fluence, decreased with wavelength over the same wavelength range and no evidence was found that photoisomerization of bilirubin to lumirubin is faster with green (514.5 or 528.7 nm) than with blue (457.9 or 488.0 nm) light. The stereoselectivity of the configurational isomerization of bilirubin to 4Z,15E and 4E,15Z isomers also was studied. This reaction became less regioselective for the 4Z,15E isomer with increasing wavelength. The observed wavelength dependence of phi LR and of the [4E,15Z]: [4Z,15E] ratio at photoequilibrium are consistent with an exciton coupling model in which intramolecular energy transfer can occur between the two pyrromethenone chromophores of the bilirubin molecule in the excited state. Relative rates of lumirubin formation in vivo at different excitation wavelengths and constant fluence were estimated for different optical thicknesses and for different skin thicknesses. These estimates suggest that the recently reported clinical equivalence of blue and green phototherapy lights probably reflects the marked variation of skin transmittance with wavelength more than wavelength-dependent photochemistry. The calculations also indicated that the optimal wavelength for phototherapy is probably on the long wavelength side of the bilirubin absorption maximum. 相似文献
1000.
Nicola Raffone Brieuc Le Fèvre Luisa Ottolini Riccardo Vannucci Alberto Zanetti 《Mikrochimica acta》2006,155(1-2):251-255
The high sensitivity of Secondary-Ion Mass Spectrometry (SIMS) in determining very low trace-element concentrations (down
to few ppb wt) has been used to address the important issue of the Light-Lithophile Element (LLE) signatures of mantle peridotites
and their potential utility as tracers of transfer of subducted material into the overlying mantle wedge operated either by
slab-related fluids or melts. The effects of such metasomatic agents have been described and interpreted on the basis of geochemical
and isotopic characteristics of peridotites. However, direct observation of metasomatic processes occurring in the mantle
is limited because the most highly metasomatised peridotites are usually found as xenoliths which do not allow large-scale
chemical information. In this context, the Finero phlogopite-peridotite massif (Ivrea-Verbano Zone, western Italian Alps)
offers a unique opportunity because it contains hydrous mineral assemblages (amphibole + phlogopite ± apatite) and trace element
enrichments, supposed to be related to the pervasive migration of slab-derived melts. In this study we report the results
of texture-related SIMS investigations performed on a wide range of trace elements such as Li, B, Large-Ion Lithophile Elements
(LILE), Rare Earth Elements (REE), Nb, Zr, Ti on clinopyroxenes from the Finero peridotite. SIMS analyses revealed unusual
LLE signatures that highlight the role of crust-derived components and open new perspectives on the timing of metasomatic
processes. 相似文献