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91.
This paper describes the preparation and conductivity studies of polyindole–ZnO composite polymer electrolyte (CPE) with LiClO4. Polyindole–ZnO-based polymer nanocomposites were prepared by chemical method and characterized by XRD, infrared (IR), scanning
electron microscope (SEM), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). The IR spectrum confirms
the intermolecular interaction between polyindole and ZnO. The significant spectral changes of polyindole and ZnO nancomposites
reveal the strong interaction between polyindole and ZnO nanoparticles. The structural morphologies of the ZnO, polyindole,
and polyindole–ZnO are obtained from SEM. The TEM image of polyindole nanocomposite shows that ZnO is embedded in polyindole
matrix. An enhanced conductivity of 4.405 × 10−7 S cm−1 at 50 °C for the CPE was determined from impedance studies. 相似文献
92.
A conic integer program is an integer programming problem with conic constraints. Many problems in finance, engineering, statistical
learning, and probabilistic optimization are modeled using conic constraints. Here we study mixed-integer sets defined by
second-order conic constraints. We introduce general-purpose cuts for conic mixed-integer programming based on polyhedral
conic substructures of second-order conic sets. These cuts can be readily incorporated in branch-and-bound algorithms that
solve either second-order conic programming or linear programming relaxations of conic integer programs at the nodes of the
branch-and-bound tree. Central to our approach is a reformulation of the second-order conic constraints with polyhedral second-order
conic constraints in a higher dimensional space. In this representation the cuts we develop are linear, even though they are
nonlinear in the original space of variables. This feature leads to a computationally efficient implementation of nonlinear
cuts for conic mixed-integer programming. The reformulation also allows the use of polyhedral methods for conic integer programming.
We report computational results on solving unstructured second-order conic mixed-integer problems as well as mean–variance
capital budgeting problems and least-squares estimation problems with binary inputs. Our computational experiments show that
conic mixed-integer rounding cuts are very effective in reducing the integrality gap of continuous relaxations of conic mixed-integer
programs and, hence, improving their solvability.
This research has been supported, in part, by Grant # DMI0700203 from the National Science Foundation. 相似文献
93.
Mikhail Belkin Hariharan Narayanan Partha Niyogi 《Random Structures and Algorithms》2013,43(4):407-428
We draw on the observation that the amount of heat diffusing outside of a heated body in a short period of time is proportional to its surface area, to design a simple algorithm for approximating the surface area of a convex body given by a membership oracle. Our method has a complexity of O*(n4), where n is the dimension, compared to O*(n8) for the previous best algorithm. We show that our complexity cannot be improved given the current state‐of‐the‐art in volume estimation. © 2013 Wiley Periodicals, Inc. Random Struct. Alg., 43, 407–428, 2013 相似文献
94.
An analysis of phase-modulated heteronuclear dipolar decoupling sequences in solid-state nuclear magnetic resonance 总被引:1,自引:1,他引:0
Thakur RS Kurur ND Madhu PK 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,193(1):77-88
The design of variants of the swept-frequency two-pulse phase modulation sequence for heteronuclear dipolar decoupling in solid-state NMR is reported, their performance evaluated, and compared with other established sequences like TPPM and SPINAL. Simulations performed to probe the role of the homonuclear (1)H-(1)H bath show that the robustness of the decoupling schemes improves with the size of the bath. In addition, these simulations reveal that the homonuclear (1)H-(1)H bath also leads to broad baselines at high MAS rates. Results from a study of the SPINAL decoupling scheme indicate that optimisation of the starting phase and phase increment improves its performance and efficiency at high MAS rates. Additionally, experiments performed on a liquid crystal display the role of the initial phase in SPINAL-64 and sequences in the SW(f)-TPPM family. 相似文献
95.
Mukhopadhyay MK Jiao X Lurio LB Jiang Z Stark J Sprung M Narayanan S Sandy AR Sinha SK 《Physical review letters》2008,101(11):115501
Changes to the structure of polystyrene melt films as measured through the spectrum of density fluctuations have been observed as a function of film thickness down to the polymer radius of gyration (Rg). Films thicker than 4Rg show bulklike density fluctuations. Thinner films exhibit a peak in S(q) near q=0 which grows with decreasing thickness. This peak is attributed to a decreased interpenetration of chains resulting in an enhanced compressibility. Measurements were made using small angle x-ray scattering in a standing wave geometry designed to enhance scattering from the interior of the film compared to interface scattering. 相似文献
96.
Vinay Kiran Narayanan Balaji Bhavesh Babulal Gabani Manjuanth Bajantri Rajesh Chandran Abhishek Dixit Nuggehally R. Srinivas Ramesh Mullangi 《Biomedical chromatography : BMC》2020,34(9):e4879
We developed and validated a simple, sensitive, selective, and reliable LC–MS/MS–ESI method for the direct quantitation of lumefantrine (LFN) enantiomers [(−)-LFN and (+)-LFN] in mice plasma as per regulatory guideline. LFN enantiomers and carbamazepine (internal standard) were extracted from mice plasma using Strata X SPE (solid-phase extraction) cartridges. Good resolution between enantiomers was achieved on a Chiralpak IA-3 column using an isocratic mobile phase (0.1% of diethyl amine in methanol), which was delivered at a flow rate of 0.8 mL/min. Detection and quantitation were performed using multiple reaction monitoring mode following the transitions m/z 530.27 → 512.30 and 237.00 → 194.00 for LFN enantiomers and the internal standard, respectively, in the positive-ionization mode. The proposed method provided accurate and reproducible results over the linearity range of 2.39–895 ng/mL for each enantiomer. The intra- and inter-day precisions were in the range of 1.03–6.14 and 6.36–8.70 and 2.03–4.88 and 5.82–11.5 for (−)-LFN and (+)-LFN, respectively. Both (−)-LFN and (+)-LFN were found to be stable under different stability conditions. The method was successfully used to delineate stereoselective pharmacokinetics of LFN enantiomers in mice after an oral administration of rac-LFN (20 mg/kg). The pharmacokinetic results indicated that the disposition of LFN enantiomers was stereoselective in mice. 相似文献
97.
Premchand V. P. Balaram Bipin Mani Ajith K. Narayanan M. D. Sajith A. S. 《Nonlinear dynamics》2022,110(1):573-588
Nonlinear Dynamics - Optimisation procedures for nonlinear vibrating systems are made cumbersome due to the fact that the regimes of periodic response are not known beforehand. Moreover, such... 相似文献
98.
Analytical and numerical solution of an $$\varvec{n}$$n-term fractional nonlinear dynamic oscillator
Nonlinear Dynamics - This work presents a novel method for the analytical and numerical solution of an n-term fractional nonlinear dynamical system. Two simple methods, commonly known to vibration... 相似文献
99.
Mithilesh Kumar Nayak Jessica Stubbe Dr. Nicolás I. Neuman Dr. Ramakirushnan Suriya Narayanan Sandipan Maji Prof. Dr. Carola Schulzke Prof. Vadapalli Chandrasekhar Prof. Dr. Biprajit Sarkar Dr. Anukul Jana 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(19):4425-4431
This work presents a stepwise reversible two-electron transfer induced hydrogen shift leading to the conversion of a bis-pyrrolinium cation to an E-diaminoalkene and vice versa. Remarkably, the forward and the reverse reaction, which are both reversible, follow two completely different reaction pathways. Establishing such unprecedented property in this type of processes was possible by developing a novel synthetic route towards the starting dication. All intermediates involved in both the forward and the backward reactions were comprehensively characterized by a combination of spectroscopic, crystallographic, electrochemical, spectroelectrochemical, and theoretical methods. The presented synthetic route opens up new possibilities for the generation of multi-pyrrolinium cation scaffold-based organic redox systems, which constitute decidedly sought-after molecules in contemporary chemistry. 相似文献